A systematic study of 3NF effects in p + d break-up with BINA at 190 MeV

A systematic study of three-nucleon force (3NF) effects in break-up reactions has been carried out at KVI at several energies. In this article, the p + d → p + p + n reaction with a polarized-proton beam of 190?MeV will be discussed. The experiment was performed by exploiting a new detector called BINA. Some results for high-precision vector analyzing powers and differential cross sections are presented and compared with state-of-the-art Faddeev calculations with or without 3NF.     

Influence of roughness on attachment line boundary layer transition in hypersonic flow

 Attachment line boundary layer transition on swept cylinders is studied in a low enthalpy hypersonic wind tunnel at M _∞=7.14. Sweep angles of 60° and 70° are used and transition is detected by means of heat flux measurements. The influence on attachment line transition of single 2D-roughness elements, in the form of tripwires or slots, as well as 3D obstacles is determined and the results are analyzed with respect to Poll’s criterion. Received: 16 January 1996 / Accepted: 12 July 1996     

Energy transfer and excimer formation in a flowing afterglow of Mg metastables

Mg atoms were vaporized into a fast flowing Ar carrier stream and then excited by an ac discharge. Downstream of the discharge in the afterglow region metastable Mg (³P) atoms were reacted with vaporized metals. The resultant chemiluminescence consisted of metal atom resonance lines and continuous emission bands of the molecule KMg.     

Formation and decay kinetics of optically pumped LiMg excimers

A mixture of Li and Mg vapors at 900°C was optically pumped at 488 nm by an Ar⁺ ion laser. The resulting Li₂ fluorescence and LiMg* excimer chemiluminescence intensities were analyzed to determine rate constants for the reactions Li₂(B¹π) + Mg → LiMg* + Li and LiMg* + Li → Li₂(a³π) + Mg and the radiative decay rates of Li₂(B¹π) and LiMg*.     

CW chemical laser gain at 10.6 microns

Laser amplification by stimulated emission in the 001-100 vibrational-rotational band of CO₂ has been continuously excited by transfer from the products of the oxidation of alkaline earth metal vapors in N₂O. The sensitive detection of gain transverse to a 1 cm diameter flame was accomplished by intracavity measurements in a conventional CO₂-EDL with the aid of two frequency modulation and synchronous detection.     

Effect of Ligand Polarity on the Internal Dipoles and Ferroelectric Distortion in BaTiO3 Nanocubes

Surface adsorbates and surrounding matrix species have been demonstrated to affect the properties of nanoscale ferroelectrics and nanoscale ferroelectric composites; potentially counteracting performance losses that can occur in small particle sizes. In this work, the effects of nonpolar oleic acid (OA) and polar tetrafluoroborate (BF₄⁻) ligand capping on the surface of various sizes of BaTiO₃ nanocubes have been investigated with combined neutron diffraction and neutron pair distribution function (PDF), density functional theory (DFT), and ab initio molecular dynamics (AIMD) methods. The low real space PDF region provides an unobstructed view of rhombohedral (split short and long) Ti−O distances in BaTiO₃ nanocubes, mimicking the well-established order-disorder local structure found in bulk BaTiO₃. Interestingly, the intermediate-range order in nanocubes is found to be orthorhombic, rather than tetragonal. It is concluded that polar ligands adsorbed at BaTiO₃ surfaces stabilize the correlation length scale of local rhombohedral distortions in ferroelectric nanoparticles relative to nonpolar ligands.     

Solid targets for 99mTc production on medical cyclotrons

Recent disruptions in the molybdenum-technetium generator supply chain prompted a review of non-reactor based production methods for both ⁹⁹Mo and ^99mTc. Small medical cyclotrons (E _p ~ 16–24 MeV) are capable of producing Curie quantities of ^99mTc from isotopically enriched ¹⁰⁰Mo using the ¹⁰⁰Mo(p,2n)^99mTc reaction. Unlike most other metallic target materials for routine production of medical radioisotopes, molybdenum cannot be deposited by reductive electroplating from aqueous salt solutions. To overcome this issue, we developed a new process for solid molybdenum targets based on the electrophoretic deposition of fine ¹⁰⁰Mo powder onto a tantalum plate, followed by high temperature sintering. The targets obtained were mechanically robust and thermally stable when irradiated with protons at high power density.     

Efficient New Synthesis of N‐Arylbenzo[b]furo[3,2‐d]pyrimidin‐4‐amines and Their Benzo[b]thieno[3,2‐d]pyrimidin‐4‐amine Analogues via a Microwave‐Assisted Dimroth Rearrangement

A useful and rapid access to libraries of N‐arylbenzo[b]furo[3,2‐d]pyrimidin‐4‐amines ( 1 ) and their novel benzo[b]thieno[3,2‐d]pyrimidin‐4‐amine analogues ( 2 ) was investigated for the first time. Title compounds were obtained via microwave‐accelerated condensation and Dimroth rearrangement of suitable anilines with N′‐(2‐cyanaryl)‐N,N‐dimethylformimidamides obtained by reaction of benzo[b]furane and benzo[b]thiophene precursors with N,N‐dimethylformamide dimethyl acetal. This work also demonstrates that well‐controlled parameters offer comfortable use of microwave technology and are both safe and beneficial to the environment. Some products obtained in this article exhibit interesting in vitro antiproliferative effects.