Characterization of olive mill wastewater and gamma irradiation effects on some parameters of its composition

Journal of Radioanalytical and Nuclear Chemistry - Gamma irradiation was applied to olive mill wastewater and synthetic samples prepared from Gallic acid. The effects, generated on the...     

Single photon double ionization of \mbox{\sffamily\bfseries H}_{\hbox{\sffamily\bfseries\fontsize{10}{12}\selectfont 2}} by circularly polarized photons at a photon energy of 160 eV

We report on fully differential cross sections for double ionization of H₂ by a single circularly polarized photon of 160 eV energy. For an unequal sharing of the energy between the two electrons and a particular geometry where the influence of electron/electron interaction is constant, we find a four-lobe structure in the molecular frame angular distribution of the faster electron. This structure is interpreted to be due to a coherent emission of the electron from the two atomic centers of the molecule. This Young-type interference pattern is lost for other geometries, where electron-electron interaction plays a major role. Furthermore, we show that the interference structure depends strongly on the internuclear distance.     

Capacitance Polypyrrole‐based Impedimetric Immunosensor for Interleukin‐10 Cytokine Detection

In the present study, we developed a novel label‐free capacitance impedimetric immunosensor based on the immobilization of the human monoclonal antibody anti‐interleukin‐10 (anti‐IL‐10 mAb) onto polypyrrole (PPy)‐modified silicon nitride (Si₃N₄) substrates. The immunosensor was used for the detection of the recombinant interleukin‐10 antigen (rh IL‐10) that may be secreted in patients at the early stage of inflammation. The immunosensor was created by chemical deposition of PPy conducting layer on pyrrole?silane (SPy)‐treated Si/SiO₂/Si₃N₄ substrates (Si/SiO₂/Si₃N₄?SPy), followed by anti‐IL‐10 mAb immobilization through carboxyl‐functionalized diazonium (CMA) protocol and carbodiimide chemistry. The surface characterization and the biofunctionalization steps were characterized by SEM, FTIR and cyclic voltammetry (CV) while the detection process was carried out by using electrochemical impedance spectroscopy (EIS) analyses. The created immunosensor showed two linear fittings (R²=0.999) for the detection of rh IL‐10 within the concentration range from 1–50 pg/mL. It exhibited high sensitivity (0.1128 (pg/mL)^?1) with a very low limit of detection (LOD)=0.347 pg/mL, more particularly, at the low concentration range (1–10 pg/mL). Thus, this developed polypyrrole‐based immunosensor represents a promising strategy for creation of miniaturized label‐free, fast and highly sensitive biosensors for diagnosis of inflammation biomarkers at very low concentrations with reduced cost.     

Existence and Asymptotic Behavior of the Wave Equation with Dynamic Boundary Conditions

The goal of this work is to study a model of the strongly damped wave equation with dynamic boundary conditions and nonlinear boundary/interior sources and nonlinear boundary/interior damping. First, applying the nonlinear semigroup theory, we show the existence and uniqueness of local in time solutions. In addition, we show that in the strongly damped case solutions gain additional regularity for positive times t>0. Second, we show that under some restrictions on the initial data and if the interior source dominates the interior damping term and if the boundary source dominates the boundary damping, then the solution grows as an exponential function. Moreover, in the absence of the strong damping term, we prove that the solution ceases to exists and blows up in finite time.     

Interference in the collective electron momentum in double photoionization of H2

We investigate single-photon double ionization of H(2) by 130 to 240 eV circularly polarized photons. We find a double slitlike interference pattern in the sum momentum of both electrons in the molecular frame which survives integration over all other degrees of freedom. The difference momentum and the individual electron momentum distributions do not show such a robust interference pattern. We show that this interference results from a non-Heitler-London fraction of the H(2) ground state where both electrons are at the same atomic center.     

Spectral-line asymmetry in double-output-cavity lasers

The aim of this work is to show that the output from a double-output laser cavity exhibits distinctive features, manifesting themselves through typical asymmetry in the corresponding spectral-line shapes. Such asymmetry in an inhomogeneously broadened gas laser usually appears with a clear, but unpredictable shift of the maximum intensity level either towards the high or low frequency sides with respect to line centre. In the case of a double-output laser, the spectral profiles show opposite shifts. This means that when the maximum intensity of one output moves towards the high frequency side of the profile, the maximum intensity of the other moves towards the low frequency side. This gives rise to a frequency shift with respect to the Lamb-dip for a classical laser. On the theoretical side, we apply the standard disturbed Gaussian beam model to provide a quantification of the frequency shifts obtained at both sides of the system.