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61.
M. Beatrice Margaret R. Sankar S. Kalainathan R. Jayavel T. Irusan 《Crystal Research and Technology》2006,41(7):712-717
Tri Glycinsulphate with partial substitution of phosphoric acid, namely Tri Glycine Sulpho Phosphate (TGSP) has been grown by slow cooling method. Habit modifications have been observed with change in the concentration of ortho phosphoric acid (H3PO4). Monoclinic structure of the grown crystals has been confirmed using X‐ray diffraction analysis. TGSP crystals doped with L – Asparagine were also grown. The doping effect is qualitatively estimated using FTIR analysis. TGA, DTA studies and dielectric measurements were carried out for pure and L‐Asparagine doped TGSP crystals to investigate the thermal and electrical properties of the crystals. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
62.
Kapil Shyam Lokare Beatrice Braun‐Cula Christian Limberg Marcel Jorewitz John T. Kelly Knut R. Asmis Stephen Leach Carsten Baldauf Itziar Goikoetxea Joachim Sauer 《Angewandte Chemie (International ed. in English)》2019,58(3):902-906
Even though aluminas and aluminosilicates have found widespread application, a consistent molecular understanding of their surface heterogeneity and the behavior of defects resulting from hydroxylation/dehydroxylation remains unclear. Here, we study the well‐defined molecular model compound, [Al3(μ2‐OH)3(THF)3(PhSi(OSiPh2O)3)2], 1 , to gain insight into the acid–base reactivity of cyclic trinuclear Al3(μ2‐OH)3 moieties at the atomic level. We find that, like zeolites, they are sufficiently acidic to catalyze the isomerization of olefins. DFT and gas phase vibrational spectroscopy on solvent‐free and deprotonated 1 show that the six‐membered ring structure of its Al3(μ2‐OH)3 core is unstable with respect to deprotonation of one of its hydroxy groups and rearranges into two edge‐sharing four‐membered rings. This renders AlIV?O(H)?AlIV units strong acid sites, and all results together suggest that their acidity is similar to that of zeolitic SiIV?O(H)?AlIV groups. 相似文献
63.
Beatrice Meini 《Numerische Mathematik》1997,78(1):39-58
Summary. By performing an accurate analysis of the convergence, we give a complete theoretical explanation of the experimental behaviour
of functional iteration techniques for the computation of the minimal nonnegative solution of the matrix equation , arising in the numerical solution of M/G/1 type Markov chains (here the 's are nonnegative matrices such that the matrix is column stochastic). Moreover, we introduce a general class of functional iteration methods, which includes the standard
methods, and we give an optimality convergence result in this class.
Received September 1, 1995 / Revised version received September 9, 1996 相似文献
64.
65.
Tsutomu Nakada Ingrid L. Kwee Beatrice V. Griffey Richard H. Griffey 《Magnetic resonance imaging》1988,6(6):633-635
Images of the rat head reflecting glucose utilization were obtained using 2-fluoro-2-deoxy-D-glucose (2-FDG) and 19F nuclear magnetic resonance (NMR) imaging. Spatial heterogeneity of glucose utilization in the rat head was clearly demonstrated showing significantly higher glucose utilization in the brain as compared to the surrounding tissues. Although the potential adverse effects of the high doses of 2-FDG (400 mg/kg) needed to perform the study preclude immediate application of this technique to clinical quantitative glucose utilization studies, the present study shows potential for future development of glucose utilization imaging by NMR. 相似文献
66.
Raffaele D’Ambrosio Martina Moccaldi Beatrice Paternoster Federico Rossi 《Journal of mathematical chemistry》2018,56(10):2876-2897
Adapted numerical schemes for the integration of differential equations generating periodic wavefronts have reported benefits in terms of accuracy and stability. This work is focused on differential equations modelling chemical phenomena which are characterized by an oscillatory dynamics. The adaptation is carried out through the exponential fitting technique, which is specially suitable to follow the apriori known qualitative behavior of the solution. In particular, we have merged this strategy with the information coming from existing theoretical studies and especially the observation of time series. Numerical tests will be provided to show the effectiveness of this problem-oriented approach. 相似文献
67.
A Biomimetic Nickel Complex with a Reduced CO2 Ligand Generated by Formate Deprotonation and Its Behaviour towards CO2
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Philipp Zimmermann Santina Hoof Dr. Beatrice Braun‐Cula Dr. Christian Herwig Prof. Dr. Christian Limberg 《Angewandte Chemie (International ed. in English)》2018,57(24):7230-7233
Reduced CO2 species are key intermediates in a variety of natural and synthetic processes. In the majority of systems, however, they elude isolation or characterisation owing to high reactivity or limited accessibility (heterogeneous systems), and their formulations thus often remain uncertain or are based on calculations only. We herein report on a Ni?CO22? complex that is unique in many ways. While its structural and electronic features help understand the CO2‐bound state in Ni,Fe carbon monoxide dehydrogenases, its reactivity sheds light on how CO2 can be converted into CO/CO32? by nickel complexes. In addition, the complex was generated by a rare example of formate β‐deprotonation, a mechanistic step relevant to the nickel‐catalysed conversion of HxCOyz? at electrodes and formate oxidation in formate dehydrogenases. 相似文献
68.
In order to determine the specific effects of radical-induced reactions in the absence of complicating excited-state pathways, four different thiohydroxamic esters and their parent molecule, N-hydroxypyridine-2(1H)-thione, have been studied in murine L1210 leukemia cells for their ability to produce photobiological damage. Irradiation (Xexc= 355 nm) of cells in the presence of thiopyridone esters, specific photolytic precursors of sulfur-, carbon- and oxygen-centered radicals, caused toxicity that was unambiguously demonstrated to result from radical photosensitization mechanisms. Cellular morphological changes were observed following irradiation but apoptosis was not found to take place. A good correlation was evident between lipid peroxidation, measured by the thiobarbituric acid method, and phototoxicity, assessed by the trypan blue exclusion assay, indicating that the ester derivatives exert their effects mainly in plasma and/ or subcellular membranes. Irradiation performed under deaerated conditions also induced significant phototoxicity but the effects of deaeration were dependent on the ester used and are discussed in terms of the nature of the primary radical species generated in each case. Irradiation of L1210 cells in the presence of N-hydroxypyridine-2(1H)-thione, a nonspecific, photochemical source of hydroxyl radical, was also found to trigger phototoxicity and lipid peroxidation. However in this case, photodamage cannot yet be definitely attributed to a radical or type II mechanism although the apparent oxygen independence of phototoxicity would indicate that type II contribution is not significant. 相似文献
69.
A divalent europium chloride-bromide phase, EuBr1.56(7)Cl0.46(2) has been prepared and identified on the basis of analytical, X-ray powder diffraction and single-crystal data. Although the phase is considered isostructural with EuCl2 (PbCl2 structure type, a = 0.9230 (5), b = 0.7890 (4), c = 0.4613 (3) nm, space group Pbnm), the single-crystal data indicate long-range order in the form of a superstructure which doubles the b parameter. In the pseudocell the square pyramidal anion sites are occupied principally by bromide ions, the tetrahedral sites almost equally by bromide and chlorine ions. Structural details and the long-range order are discussed. Evidence is presented for the existence of another europium(II) mixed halide phase, EuBr1.8(2)Cl0.16(2). 相似文献
70.
Beck B Larbig G Mejat B Magnin-Lachaux M Picard A Herdtweck E Dömling A 《Organic letters》2003,5(7):1047-1050
[reaction: see text] A general strategy toward macrocyclic compounds using multicomponent reaction (MCR) chemistry, e.g., Passerini and Ugi variants, and ring-closing metathesis (RCM) is introduced. The corresponding bifunctional isocyanides carboxylic acids bearing a terminal olefin are easy to prepare from the corresponding commercially available starting materials. Advantageously, this strategy allows fast access to a diverse conformational space of natural product-like macrocycles and could thus be of interest in the discovery of novel bioactive agents. 相似文献