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排序方式: 共有205条查询结果,搜索用时 31 毫秒
21.
Gümüşderelioğlu M Kaya FB Beşkardeş IG 《Journal of colloid and interface science》2011,358(2):444-453
In this study, the relationship between the cellular morphology and the material surface topography was investigated. Poly(ε-caprolactone) (PCL) membranes were prepared in a wide range of surface wettabilities by means of crystallinity-controlled solvent casting process. Membrane surfaces were characterized by atomic force microscope (AFM), scanning electron microscope (SEM), and static/dynamic water contact angle measurements. It was found that solvent evaporation and non-solvent (methanol) addition to the solvent (THF) are the most decisive parameters to change the surface topography. The non-solvent addition and the decrease in solvent evaporation temperature from room temperature to -20 °C caused increased polymeric chain mobility and crystallization time. Such changes in crystallization parameters led to the formation of micro/nano-sized features on the membrane. Cell culture studies indicated that in contrast to Madin Darby kidney (MDBK) epithelial cells, L929 mouse fibroblast preferred rough and porous surfaces. 相似文献
22.
A necessary and sufficient condition for the convexity of the Bézier surface over the k-dimensional simplex is presented.
We also consider a multidimensional version of the variation diminishing property of the Bernstein polynomials. 相似文献
23.
Süheyla Çehreli Be?ir Tatlí Pelin Bagˇman 《The Journal of chemical thermodynamics》2005,37(12):1288-1293
(Liquid + liquid) equilibrium (LLE) data for (water + propionic acid + cyclohexanone) were measured under atmospheric pressure and at T = (293.2, 298.2 and 303.2) K. Phase diagrams were obtained by determining solubility and tie-line data. The LLE data of the ternary systems were predicted by UNIFAC method. Distribution coefficients and separation factors were evaluated over the immiscibility regions. 相似文献
24.
Gabriel Okša Yusaku Yamamoto Martin Bečka Marián Vajteršic 《BIT Numerical Mathematics》2018,58(4):1099-1123
The proof of the asymptotic quadratic convergence is provided for the parallel two-sided block-Jacobi EVD algorithm with dynamic ordering for Hermitian matrices. The discussion covers the case of well-separated eigenvalues as well as clusters of eigenvalues. Having p processors, each parallel iteration step consists of zeroing 2p off-diagonal blocks chosen by dynamic ordering with the aim to maximize the decrease of the off-diagonal Frobenius norm. Numerical experiments illustrate and confirm the developed theory. 相似文献
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27.
Study of Langmuir monolayers consisting of stearic acid (SA) and dipalmitoylphosphatidylcholine (DPPC) molecules was done by surface pressure-area isotherms (π-A), the Maxwell displacement current (MDC) measurement, X-ray reflectivity (XRR) and atomic force microscopy (AFM) to investigate the selected mechanic, thermodynamic and dielectric properties based on orientational structure of monolayers. On the base of π-A isotherms analysis we explain the creation of stable structures and found optimal monolayer composition. The dielectric properties represented by MDC generated monolayers were analyzed in terms of excess dipole moment, proposing the effect of dipole-dipole interaction. XRR and AFM results illustrate deposited film structure and molecular ordering. 相似文献
28.
New Perspectives for Old Clusters: Anderson–Evans Anions as Building Blocks of Large Polyoxometalate Frameworks in a Series of Heterometallic 3 d–4 f Species
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Dr. Beñat Artetxe Dr. Santiago Reinoso Dr. Leire San Felices Prof. Luis Lezama Prof. Juan M. Gutiérrez‐Zorrilla Dr. Cristian Vicent Fadi Haso Prof. Tianbo Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(13):4616-4625
A series of nine [Sb7W36O133Ln3M2(OAc)(H2O)8]17? heterometallic anions ( Ln3M2 ; Ln=La–Gd, M=Co; Ln=Ce, M=Ni and Zn) have been obtained by reacting 3 d metal disubstituted Krebs‐type tungstoantimonates(III) with early lanthanides. Their unique tetrameric structure contains a novel {MW9O33} capping unit formed by a planar {MW6O24} fragment to which three {WO2} groups are condensed to form a tungstate skeleton identical to that of a hypothetical trilacunary derivative of the ?‐Keggin cluster. It is shown, for the first time, that classical Anderson–Evans {MW6O24} anions can act as building blocks to construct purely inorganic large frameworks. Unprecedented reactivity in the outer ring of these disk‐shaped species is also revealed. The Ln3M2 anions possess chirality owing to a {Sb4O4} cluster being encapsulated in left‐ or right‐handed orientations. Their ability to self‐associate in blackberry‐type vesicles in solution has been assessed for the Ce3Co2 derivative. 相似文献
29.
Vaden TD de Boer TS Simons JP Snoek LC Suhai S Paizs B 《The journal of physical chemistry. A》2008,112(20):4608-4616
The conformational structures of protonated polyalanine peptides, Ala(n)H(+), have been investigated in the gas phase for n = 3, 4, 5, and 7 using a combination of resonant-infrared multiphoton dissociation (R-IRMPD) spectroscopy in the NH and OH stretch regions and quantum chemical calculations. Agreement between theoretical IR and experimental R-IRMPD spectral features has enabled the assignment of specific hydrogen-bonded conformational motifs in the short protonated peptides and revealed their conformational evolution under elevated-temperature conditions, as a function of increasing chain length. The shortest peptide, Ala(3)H(+), adopts a mixture of extended and cyclic chain conformations, protonated, respectively, at a backbone carbonyl or the N-terminus. The longer peptides adopt folded, cyclic, and globular charge-solvated conformations protonated at the N-terminus, consistent with previous ion-mobility studies. The longest peptide, Ala(7)H(+), adopts a globular conformation with the N-terminus completely charge-solvated, demonstrating the emergence of "physiologically relevant" intramolecular interactions in the peptide backbone. The computed conformational relative free energies highlight the importance of entropic contributions in these peptides. 相似文献
30.
E. Makrlík P. Vańura V. Bečková 《Journal of Radioanalytical and Nuclear Chemistry》1999,241(3):659-661
From extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium Pb2+(aq)+SrL2
2+(nb)⇆PbL2
2+(nb)+Sr2+(aq) taking place in the two-phase water-nitrobenzene system (L=15-crown-5; aq = aqueous phase, nb = nitrobenzene phase) was
evaluated: logK
ex (Pb2+,SrL2
2+)=3.0. Further, the stability constant of the PbL2
2+ complex in nitrobenzene saturated with water was calculated: log βnb(PbL
2
2+
)=17.8 相似文献