Glacial influences on solar radiation in a subarctic sea

Understanding macroscale processes controlling solar radiation in marine systems will be important in interpreting the potential effects of global change from increasing ultraviolet radiation (UV) and glacial retreat. This study provides the first quantitative assessment of UV in the water column of Prince William Sound, a subarctic, semienclosed sea surrounded by mountains, glaciers, rivers, bays and fjords in south central Alaska. Glacial influences on diffuse attenuation coefficients (Kd) were determined along an approximate 120 km transect running NE (61 degrees 07'43'N, 146 degrees 17'1'W) to SW (60 degrees 27'25'N, 148 degrees 05'27' W). Glacial meltwater and flour caused a 10-fold increase in Kd for visible light, UV-A and UV-B, whereas high optical clarity was present in a diversity of areas away from glacial influences. Transition areas and locations affected by calving of a tidewater glacier had intermediate Kd values. Depths at 99% attenuation ranged from less than 0.2 m near glacial streams to greater than 5 m in bays and open ocean distant from sources of glacial sediments. These results suggest that potential global change from increasing UV and glacial retreat may have heterogeneous effects on subarctic marine systems.     

Phosphonate mediated surface reaction and reorganization: implications for the mechanism controlling cement hydration inhibition

Vertical scanning interferometry and XPS show the reaction of CaCO3 with the hydration retarder nitrilo-tris-(methylene)phosphonic acid follows a pathway of dissolution of the calcium followed by precipitation of a calcium phosphonate; subsequent surface reorganization/restructuring of the calcium phosphonate exposes the underlying CaCO3 for further hydration.     

A new approach to the solution of the Navier-Stokes equations

In the present paper a numerical algorithm is given for solving a standard problem in fluid dynamics, that of inviscid, irrotational, incompressible flow over an arbitrary symmetric profile. The purpose of the paper is to propose an alternative approach to solve certain fluid dynamic flows. This paper may be thought of as the first of a possible series of papers solving new and fundamental problems. In a sense, this new approach asks the question: what is the simplest and most efficient method of solving the problem considered by finite difference methods. It is believed that the following algorithm answers this question. Standard second-order finite difference techniques, such as SLOR and ADI, are used to solve numerically a mixed boundary value problem comprised of a pair of elliptic partial differential equations with constant coefficients.     

Arene-mercury complexes stabilized aluminum and gallium chloride: synthesis and structural characterization.

Reaction of HgCl(2) with 2 equiv of MCl(3) in an aromatic solvent yields Hg(arene)(2)(MCl(4))(2) where, arene = C(6)H(5)Me, M = Al (1), Ga (2); arene = C(6)H(5)Et, M = Al (3) and Ga (4); o-C(6)H(4)Me(2), M = Al (5), Ga (6); C(6)H(3)-1,2,3-Me(3), M = Al (7) and Ga (8). The solid-state structures of compounds 1-5 and 7 have been determined by X-ray crystallography. In the solid state, compounds 1-4 and 7 exist as neutral complexes in which two arenes are bound to the mercury, and the MCl(3) groups are bound through bridging chlorides to the mercury; compound 5 exists as a cation-anion pair [Hg(o-C(6)H(4)Me(2))(2)(AlCl(4))][AlCl(4)]. However, in solution compounds 1-8 all exist as neutral complexes. The structures of Hg(arene)(2)(AlCl(4))(2) and [Hg(arene)(2)(AlCl(4))](+) have been determined by DFT calculations [B3LYP level] to facilitate the assignment of the (13)C CPMAS NMR spectra and are in good agreement with the X-ray diffraction structures of compounds 1 and 5. Reaction of HgCl(2) with MCl(3) in benzene, m-xylene, and p-xylene results in the formation of liquid clathrates whose spectroscopic characterization is consistent with ionic structures, [Hg(arene)(2)(MCl(4))][MCl(4)]. The calculated energy difference between Hg(C(6)H(5)Me)(2)(AlCl(4))(2) and [Hg(C(6)H(5)Me)(2)(AlCl(4))][AlCl(4)] is discussed with respect to the structure of compound 5 in the solid state versus solution state and the proposed speciation in the liquid clathrates.     

Ergodic Control in L∞

The infinite horizon discounted L ^∞ problem is studied as the discount factor goes to zero. It is related to the limit of the finite horizon problem as the horizon becomes infinite. The deterministic problem with and without a running cost is considered.     

Analysis of the squeezing flow of dusty fluids

The current investigation deals with the study of the effect of introducing a small fraction of dust, by volume, to the fluid in a squeeze film on the viscous resistance to a steady moving disc. Expressions are obtained for the fluid-phase and the dust-phase velocity distributions and the dust particle number density. Analysis based on an iterative procedure indicates that the resistance to motion experienced by the moving disc increases due to the presence of dust.Nomenclature A arbitrary function of integration - B bulk concentration - F resistance to motion experienced by the disc (dusty fluid case) - F _c resistance to motion experienced by the disc (clean fluid case) - F* difference in resistance between the clean fluid and dusty fluid films - f mass concentration - h thickness of the squeeze film - K Stokes coefficient of resistance - m mass of a single dust particle - fluid viscosity coefficient - N dust particles number density - N ₀ dust particles number density at r=R - n iteration level - p fluid pressure in the squeeze film - P pressure in the surrounding - R radius of the disc - fluid density - (r, , y) cylindrical coordinates - t time - U fluid-phase velocity vector - V dust-phase velocity vector - ₁ fluid-phase radial velocity component - U ₂ dust-phase radial velocity component