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151.
P. N. Jayaram Gouriprasanna Roy Govindasamy Mugesh 《Journal of Chemical Sciences》2008,120(1):143-154
The keto-enol type tautomerism in anti-thyroid drugs and their selenium analogues are described. The commonly used anti-thyroid
drug methimazole exists predominantly in its thione form, whereas its selenium analogue exists in a zwitterionic form. To
understand the effect of thione/thiol and selone/selenol tautomerism on the inhibition of peroxidase-catalysed reactions,
we have synthesized some thiones and selones in which the formation of thiol/selenol forms are blocked by different substituents.
These compounds were synthesized by a carbene route utilizing an imidazolium salt. The crystal structures of these compounds
reveal that the C=Se bonds in the selones are more polarized than the C=S bonds in the corresponding thiones. The structures
of selones were studied in solution by NMR spectroscopy and the 77Se NMR chemical shifts for the selones show large upfield shifts in the signals, confirming their zwitterionic structures
in solution. The inhibition of lactoperoxidase by the synthetic thiones indicates that the presence of a free N-H moiety is
essential for an efficient inhibition. In contrast, such moiety is not required for an inhibition by the selenium compounds. 相似文献
152.
The paper presents two different methods to calculate the current density along silicone rubber (SiR) insulator surface under salt-fog testing conditions. The first method which is based on field theory approach uses the commercial software COMSOL® to compute the current density. The conductivity of the contamination layer used in the calculations was extracted from the measured equivalent salt deposit density (ESDD) separately for different regions of the insulator surfaces. The second method is based on circuit theory approach. The insulator surface was divided into different sections for resistance calculations to account for different contamination levels. Rankings based on the calculated current densities based on segmentation of the insulator surface for ESDD measurements match with those extracted from measured leakage currents. 相似文献
153.
P. P. Lee R. J. Hwu L. P. Sadwick H. Balasubramaniam B. R. Kumar J. H. Chern R. T. Lareau 《Physica E: Low-dimensional Systems and Nanostructures》1998,2(1-4)
Details of the structural and electrical properties of epitaxial DyP/GaAs and DyAs/GaAs is reported. DyP is lattice matched to GaAs, with a room temperature mismatch of less than 0.01%. DyAs, on the other hand, has a mismatch of nearly 2.4%. Both DyP and DyAs have been grown by solid source MBE using custom designed group V thermal cracker cells and group III high-temperature effusion cells. High-quality DyP and DyAs epilayers, as determined by XRD, TEM, and AFM analysis, were obtained for growth temperatures ranging from 500°C to 600°C with growth rates between 0.5 and 0.7 μm/h. The DyP epilayers are n-type with measured electron concentrations of the order of 3×1020 to 4×1020 cm−3, with room temperature mobilities of 250–300 cm2/V s, and with a barrier height of 0.75 eV to GaAs. The DyAs epilayers are also n-type with concentration of 1×1021 to 2×1021 cm−3, with mobilities between 25 and 40 cm2/V s. DyP is stable in air with no apparent oxidation taking place, even after months of ambient exposure to untreated air. 相似文献
154.
S. R. Jayaram 《Graphs and Combinatorics》1987,3(1):357-363
A setS of lines is a line dominating set if every line not inS is adjacent to some line ofS. The line domination number of a graph is the cardinality of a minimum line dominating set. In this paper we study the line dominating sets and obtain bounds for the line domination number. Also, Nordhaus-Gaddum type results are obtained for the line domination number and the line domatic number. 相似文献
155.
156.
Microwave induced d.c. voltage due to inverse a.c. Josephson effect has been observed across bulk samples of multiphase Y2BaSrCu3O8. Results indicate that weakly coupled superconducting grains probably exist up to 26°C. 相似文献
157.
158.
C. Jayaram 《Czechoslovak Mathematical Journal》2003,53(2):351-363
In this paper we investigate prime divisors, B
w-primes and zs-primes in C-lattices. Using them some new characterizations are given for compactly packed lattices. Next, we study Noetherian lattices and Laskerian lattices and characterize Laskerian lattices in terms of compactly packed lattices. 相似文献
159.
160.
K. Shravan Kumar Krishanu Biswas R. Balasubramaniam 《Journal of nanoparticle research》2011,13(11):6005-6012
This article reports the effect of addition of small amount of thiourea on mechanism of film growth, levelling and grain refinement
of pulsed electrodeposition of nanocrystalline copper on stainless steel substrate using simple aqueous acidic copper sulphate
solution prepared from 0.25 M CuSO4·5H2O and 0.5 M H2SO4. The amount of thiourea used in the electrolyte is 0 and 36 mg/l. The results indicate the change in morphology of the deposits
with addition of thiourea leading to dendrite free copper deposits. The growth mechanism of the copper deposition is found
to change from Volmer–Weber type to Frank-Vander Merwe type making the deposits smoother when deposited with thiourea addition.
A small amount (36 mg/l) of thiourea addition leads to decrease in the average grain size of copper from 1160 nm to 14 nm.
The results clearly reveal the formation of nanocrystalline copper by addition of thiourea with three orders of magnitude
reduction in grain size as compared to the sample deposited without thiourea. Preferential segregation of sulphur (present
in thiourea) along the grain boundaries of nanocrystalline copper is shown by energy filter imaging using ultra high resolution
transmission electron microscope (TEM), thereby restricting the growth of copper grains during pulsed electrodeposition. 相似文献