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81.
Naik AD Annigeri SM Gangadharmath UB Revankar VK Mahale VB 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(8):1713-1719
A new binucleating ligand containing phenoxide as an endogenous bridging group, 2,6-diformyl-p-cresol bis(2-furanthiocarboxyhydrazone) and its binuclear Co(II), Ni(II), Cu(II) and Zn(II) complexes with chloride ion as an exogenous bridge, have been obtained. The complexes were characterized by elemental analysis, molar conductivities, magnetic moment measurements at room temperature, electronic, IR, 1H-NMR, EPR, FAB spectral studies and thermal data. The copper complex assumes a tetranuclear structure composed of two binuclear units related by a center of symmetry. The dimeric nature of copper(II) complex is supported by FAB. This complex is EPR silent. Room temperature magnetic moment reveals the operation of a significant antiferromagnetic spin exchange between the metal centers. Ligand and its copper and zinc complexes exhibit fluorescence at room temperature in DMF. All the compounds show an appreciable antimicrobial activity. 相似文献
82.
83.
Jayachamarajapura Pranesh Shubha Haralahalli Shivappa Savitha Syed Farooq Adil Mujeeb Khan Mohammad Rafe Hatshan Kiran Kavalli Baji Shaik 《Molecules (Basel, Switzerland)》2021,26(15)
Zinc oxide-ternary heterostructure Mn3O4/ZnO/Eu2O3 nanocomposites were successfully prepared via waste curd as fuel by a facile one-pot combustion procedure. The fabricated heterostructures were characterized utilizing XRD, UV–Visible, FT-IR, FE-SEM, HRTEM and EDX analysis. The photocatalytic degradation efficacy of the synthesized ternary nanocomposite was evaluated utilizing model organic pollutants of methylene blue (MB) and methyl orange (MO) in water as examples of cationic dyes and anionic dyes, respectively, under natural solar irradiation. The effect of various experimental factors, viz. the effect of a light source, catalyst dosage, irradiation time, pH of dye solution and dye concentration on the photodegradation activity, was systematically studied. The ternary Mn3O4/ZnO/Eu2O3 photocatalyst exhibited excellent MB and MO degradation activity of 98% and 96%, respectively, at 150 min under natural sunlight irradiation. Experiments further conclude that the fabricated nanocomposite exhibits pH-dependent photocatalytic efficacy, and for best results, concentrations of dye and catalysts have to be maintained in a specific range. The prepared photocatalysts are exemplary and could be employed for wastewater handling and several ecological applications. 相似文献
84.
Dewangan Pradeep Kumar Khan Fahmida Shrivas Kamlesh Sahu Vinayak 《Journal of Radioanalytical and Nuclear Chemistry》2019,320(3):757-763
Journal of Radioanalytical and Nuclear Chemistry - The unique properties of graphene quantum dots (GQDs) i.e. low toxicity, excellent water solubility, low cost, high photostability,... 相似文献
85.
Optical properties of phosphorene are tuned by adsorption of alkali metals (Li and Na) and halogens (Br and Cl). It has been found that on increasing the size of alkali metals and halogen adsorbed phosphorene layer the absorption coefficient reduces and shifts towards visible region. The refractive index in alkali metal adsorbed phosphorene increases with size of phosphorene layer. For halogen adsorbed structure it decreases with increase in size of phosphorene layer. Optical absorption is observed to depend on both dielectric constant and refractive index. Since adsorption of alkali and halogen materials modifies the refractive index of phosphorene, absorption is seen to reduce in all cases where refractive index increases due to adsorption even when the dielectric constant was high. 相似文献
86.
Kiran Kavalli Gurumoorthy S. Hebbar Jayachamarajapura Pranesh Shubha Syed Farooq Adil Mujeeb Khan Mohammad Rafe Hatshan Adibah Mukhlid Almutairi Baji Shaik 《Molecules (Basel, Switzerland)》2022,27(9)
Pollution and global warming are a few of the many reasons for environmental problems, due to industrial wastes and greenhouse gases, hence there are efforts to bring down such emissions to reduce pollution and combat global warming. In the present study, zinc oxide nanoparticles are green synthesized using cow dung as fuel, through combustion. Synthesized material was characterized by FTIR, XRD, UV, and FESEM. The as-prepared ZnO-GS NPs were employed as a transesterification catalyst for the preparation of biodiesel from discarded cooking oil. The biodiesel obtained is termed D-COME (discarded cooking oil methyl ester), which is blended with 20% commercial diesel (B20). Additionally, this blend, i.e., B20, is further blended with varying amounts of as-prepared ZnO-GS NPs, in order to ascertain its effects on the quality of emissions of various greenhouse gases such as hydrocarbons, COx, NOx. Moreover, the brake thermal efficiency (BTHE) and brake specific fuel consumption (BSFC) were studied for their blends. The blend (B20) with 30 mg of ZnO-GS, i.e., B20-30, displays the best performance and reduced emissions. Comparative studies revealed that the ZnO-GS NPs are as efficient as the ZnO-C NPs, indicating that the green synthetic approach employed does not affect the efficiency of the ZnO NPs. 相似文献
87.
88.
Vinayak Vishnu Pagar Rai‐Shung Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(16):5005-5008
Gold‐catalyzed cycloadditions of ethyl diazoacetate, nitrosoarenes, and vinyldiazo carbonyl species to yield isoxazolidine derivatives stereoselectively are described. Treatment of these isoxazolidine products with the same catalyst results in a novel 1,2‐H shift/[3,3] rearrangement to give benzo[b]azepine compounds. The mechanism of this skeletal rearrangement is elucidated with deuterium‐labeling experiments. 相似文献
89.
90.
Jingshan S. Du Peng-Cheng Chen Dr. Brian Meckes Dr. Zhuang Xie Jinghan Zhu Yuan Liu Prof. Vinayak P. Dravid Prof. Chad A. Mirkin 《Angewandte Chemie (International ed. in English)》2017,56(26):7625-7629
Multicomponent nanoparticles can be synthesized with either homogeneous or phase-segregated architectures depending on the synthesis conditions and elements incorporated. To understand the parameters that determine their structural fate, multicomponent metal-oxide nanoparticles consisting of combinations of Co, Ni, and Cu were synthesized by using scanning probe block copolymer lithography and characterized using correlated electron microscopy. These studies revealed that the miscibility, ratio of the metallic components, and the synthesis temperature determine the crystal structure and architecture of the nanoparticles. A Co-Ni-O system forms a rock salt structure largely owing to the miscibility of CoO and NiO, while Cu-Ni-O, which has large miscibility gaps, forms either homogeneous oxides, heterojunctions, or alloys depending on the annealing temperature and composition. Moreover, a higher-ordered structure, Co-Ni-Cu-O, was found to follow the behavior of lower ordered systems. 相似文献