全文获取类型
收费全文 | 1345篇 |
免费 | 22篇 |
国内免费 | 6篇 |
专业分类
化学 | 686篇 |
晶体学 | 14篇 |
力学 | 81篇 |
数学 | 115篇 |
物理学 | 477篇 |
出版年
2023年 | 9篇 |
2022年 | 16篇 |
2021年 | 17篇 |
2020年 | 21篇 |
2019年 | 19篇 |
2018年 | 15篇 |
2017年 | 21篇 |
2016年 | 27篇 |
2015年 | 18篇 |
2014年 | 41篇 |
2013年 | 81篇 |
2012年 | 70篇 |
2011年 | 71篇 |
2010年 | 46篇 |
2009年 | 56篇 |
2008年 | 60篇 |
2007年 | 54篇 |
2006年 | 42篇 |
2005年 | 44篇 |
2004年 | 36篇 |
2003年 | 28篇 |
2002年 | 16篇 |
2001年 | 17篇 |
2000年 | 17篇 |
1999年 | 15篇 |
1996年 | 14篇 |
1995年 | 20篇 |
1994年 | 14篇 |
1993年 | 22篇 |
1992年 | 19篇 |
1991年 | 20篇 |
1990年 | 13篇 |
1989年 | 21篇 |
1988年 | 15篇 |
1987年 | 9篇 |
1986年 | 11篇 |
1985年 | 17篇 |
1984年 | 20篇 |
1983年 | 17篇 |
1982年 | 15篇 |
1981年 | 17篇 |
1980年 | 15篇 |
1979年 | 20篇 |
1978年 | 15篇 |
1977年 | 19篇 |
1976年 | 20篇 |
1975年 | 12篇 |
1974年 | 10篇 |
1973年 | 10篇 |
1936年 | 13篇 |
排序方式: 共有1373条查询结果,搜索用时 31 毫秒
31.
Nath P 《Physical review letters》1996,76(13):2218-2221
32.
Spin configuration of Gd13 clusters 总被引:1,自引:0,他引:1
33.
A facile and efficacious route to the benzooxabicyclo[3.2.1]octane system has been developed and applied to a synthesis of filiformin (1). The cycloaddition of ethylene to the methoxychromone 13 furnished the oxetanol 14 through a tandem cycloaddition and gamma-hydrogen abstraction sequence. Lithium aluminum hydride reduction to the diol 15 followed by acid-catalyzed rearrangement produced benzooxabicyclooctanone (16), arising from exclusive external bond migration. Similarly, ethoxychromone (17) under the same sequence of reactions afforded the homologous bridged ketone 20. For the synthesis of filiformin (1), methoxychromone 24 on ethylene cycloaddition followed by reduction of resultant oxetanol 25 with lithium aluminum hydride furnished diol 10. Acid-catalyzed rearrangement of 10 provided the bridged ketone 11 which was brominated to give 26. This bromo ketone had previously been converted to filiformin (1), and also aplysin 9, and hence, the present work represents a short, high-yield formal synthesis of these sequiterpenes from a single starting material. 相似文献
34.
A review is given of the StandardSU(5) supergravity model. This model has passed an important check regarding unification of the electro-weak and the strong couplings using high precision LEP data. It is shown that for a significant domain of the parameter space the model also satisfies constraints on the SUSY spectrum from CDF and LEP, as well as proton stability and cosmological relic density constraints. 相似文献
35.
36.
37.
38.
The synthesis and structure-activity-relationship (SAR) for a series of N-substituted piperazinyl carbamoyl 7-15 and piperazinyl acetyl 18-26 derivatives of tetrahydropapaverine have been carried out. The general synthetic methods of carbamoyl tetrahydropapaverine analogues involve N-substituted piperazines and carbamoyl imidazole tetrahydropapaverine as starting materials. Another route for synthesizing these compounds, involving the formation of carbamoyl imidazole piperazine has also been explored. Acylation of tetrahydropapaverine followed by substitution with various piperazinyl moities afforded the acetyl tetrahydropapaverine derivatives. Variously substituted piperazines have been used to monitor the effect of electron releasing and electron withdrawing substituents upon the antispasmodic activity of the molecules. Effect of varying electron densities on the antispasmodic activity, by altering the position of these groups on the benzene ring has also been monitored. Pharmacological methods involve the in vitro antispasmodic activity studies on a freshly removed guinea pig ileum using a force displacement transducer amplifier connected to a physiograph. Among the analogues synthesized in the present study, a promising compound 7, a potent muscle relaxant as compared to papaverine has been obtained. 相似文献
39.
The compatibility of cast films of a vinylchloride–vinylacetate–maleic acid terpolymer (VMCH) and nitrocellulose (NC) blends is influenced by solvents. Transparent films of VMCH/NC blends are obtained when cast from solvents such as tetrahydrofuran or cyclohexanone, whereas hazy films are obtained when cast from solvents such as acetone or ethylacetate. Visible spectroscopy and phase morphology were used to analyse the compatibility–incompatibility of the blend. Differential scanning calorimetry (DSC) studies demonstrate that the transparent film is compatible, but the hazy film is incompatible. Fourier transform infra-red (FTIR) studies establish that a greater interaction is observed between the polymer pair in case of the compatible blend than in the case of the incompatible blend. A solvent dependency of blend compatibility is reflected in this study. The conformational state of the polymers in solution, which is responsible for the compatibility phenomena, may depend on the donor number and/or Taft-β value of the solvent. The greater the donor number and/or the Taft-β value, the higher may be the level of interaction between the solvent and the polymer molecules, which in turn may give a compatible blend after removal of the solvent. 相似文献
40.
Summary A series of square planar complexes of the type [PdX2L2] where X=Cl, Br, I; L=telluracyclopentane (tcp), telluracyclohexane (tch) or benzotelluracyclopentane (btp) have been synthesised. The complexes were characterised by far-i.r., n.m.r. and u.v.-vis. spectroscopy. The data implytrans-geometries except for the complex [PdCl2(tch)2] where a mixture ofcis- andtrans-isomers is obtained. 相似文献