BaTiO3/SrTiO3超晶格的二次谐波产生研究

用激光分子束外延技术生长了BaTiO3 /SrTiO3 超晶格并首次对之采用二次谐波产生的方法进行了研究 .实验表明其结构为类似BaTiO3 的四方相结构 .实验得到的材料的有效倍频系数远大于BaTiO3 薄膜 ,也大于BaTiO3 体材料的值 .这表明这种人为控制的BaTiO3 /SrTiO3 超晶格结构具有较大的非线性光学的应用前景 .     

时间反演对称性引起的自旋宇称效应

推广关于由有限重轴旋转对称性导致的自旋宇称效应的纯量子力学理论 ,建立了源于时间反演对称性的自旋宇称效应 .所涉及的量子系统既可以是单自旋的 ,也可以是多自旋的 ;所涉及的状态可以是自旋在任意轴上的投影的任意一对具有反号本征值的本征态 ;所涉及的自旋可以有任意的量子数 .结果还清楚地表明 :上述两种对称性所引起的自旋宇称效应互为补充 ,但并不等价     

聚乙烯高效催化剂的结构和机理研究

由X光粉末图和聚合数据得到:研磨法制聚乙烯高效催化剂TiCl₄-MgCl₂,研磨的作用是使层型结构的载体MgCl₂沿结合力较弱的层间碎裂变为～100的微晶,提供足够的比表面,使TiCl₄达单分子层分散,TiCl₄被烷基铝还原产生Ti³⁺在载体表面呈单原子分散,基本上都可起活性中心作用,这就是高效的根源,MgCl₂和TiCl₃具有类似的层型结构且Mg²⁺和Ti³⁺半径相近,是MgCl₂作为良好载体的结构基础,活性组分作单分子层分散,基本上都可起活性中心作用,这一“高效机理”可推广用于其它聚烯烃高效催化剂,文中还讨论了活性中心聚合速度和其它有关高效催化剂结构机理问题。     

A novel synthetic use of 2-bromo- 1-methylpyridinium iodide for macrolactamization

Using 2-bromo-1-methylpyridimium iodide as carboxyl activating agent, 10 ansa-macrolactams were prepared conveniently from the corresponding seco-precursor w-aminoacids in the yields of 78-2%.     

对于双未知参数均匀分布的序贯 minimax 估计

统计判决理论的一个重要问题,是对一个给定的分布族,当观测是独立同分布的,作n 次观测的费用为 cn(c>0)时,求其参数的序贯 minimax 估计.关于这一问题,Wald对损失函数 W(θ,d)=(θ-d)~2,得到了从 θ-1/2到 θ+1/2(-∞<θ<∞)上的均匀分布中均值θ的估计.Blyth将 Wald 的结果作了推广和改进.Kiefer 关于损失函数 W(θ,d)=[(θ-d)/θ]~2,解决了从0到 θ(0<θ<∞)上的均匀分布中参数θ的估计问题.本文所要讨论的是含有两个未知参数的均匀分布,其密度为     

反磁化形核行为的微磁学研究

本文指出,在对称情况下,微磁学中的反磁化形核问题是一个典型的分歧问题。利用对分歧问题的研究结果,在详细分析Brown方程分歧解的稳定性之后,得到的结论是:形核场是Brown方程的最大分歧点,Brown,Frei,Aharoni和Shtrikman等人用线性化方法获得的结果,包含在本文的笫一级微扰近似的结果中。不局限于线性化近似,文中还得到了形核场近旁的反磁化行为,它们或者连续地沿分歧解进行,或者是一个不连续跃变;同时,还给出了连续和不连续形核的判据。     

气孔率对陶瓷激光器性能影响及控制方法

透明激光陶瓷以其特有的优越性能,有望继单晶材料后成为新型高功率固体激光器的工作材料.制备高光学质量、高激光效率,高输出功率的透明陶瓷是目前的研究重点和热点.烧结而成的多晶陶瓷存在一定量的晶界以及气孔缺陷.文章介绍了气孔率与陶瓷激光器性能的关系及控制陶瓷材料气孔率的最新研究进展.研究发现,气孔率对激光陶瓷的散射系数、透过...     

液相自组装法制备铁酸铋薄膜的研究

采用液相自组装法成功制备出铁酸铋(BiFeO3)薄膜,并采用XRD、SEM和VSM等测试方法对BiFeO3薄膜进行了表征.研究了功能化的自组装单分子层(SAMs)表面对BiFeO3薄膜成核和生长的影响,以及沉积温度对铁酸铋薄膜的形成和微观形貌的影响.结果表明:功能化的SAMs表面上薄膜与基底结合牢固,结构致密均一;沉积温度在60～70 ℃之间,薄膜表面比较平整均一,当沉积温度高于70 ℃,薄膜表面出现多晶聚集体现象.     

Layer-by-layer functionalized porous Zinc sulfide nanospheres-based solid-phase extraction combined with liquid chromatography time-of-flight/mass and gas chromatography-mass spectrometry for the specific enrichment and identification of alkaloids from Crinum asiaticum var. sinicum

The current widely utilized polymer or C8, C18 end-capped material-based sorbents for solid-phase extraction could not capture alkaloids well only based on “like dissolves like” principle. In this paper, a layer-by-layer functionalized porous Zinc sulfide nanospheres-based solid-phase extraction (SPE) combined with liquid chromatography time-of-flight/mass spectrometry (LC-TOF/MS) and gas chromatography-mass spectrometry (GC-MS) was developed for the specific enrichment and identification of alkaloids from complex matrixes, Crinum asiaticum var. sinicum crude extracts. The functionalized porous Zinc sulfide nanospheres were prepared by the amidation reaction of poly-(acrylic acid) (PAA) homopolymer with amino groups onto the porous ZnS nanospheres. Tandem LC-TOF/MS spectrometry presented that the almost all of the twenty-three main peaks in elution fraction from the SPE could be inferred as alkaloids with ion of mass according to the nitrogen rule and hit formula with Peak View1.2@software from AB SCIEX, and seven alkaloids including two new found chemical entities were directly identified from their GC-MS spectra and retention indices. We believe that this SPE protocol can also be utilized in the future to selectively enrich alkaloids from extracts of other plant species.     

Infinitely-many conservation laws for two (2+1)-dimensional nonlinear evolution equations in fluids

In this paper, a method that can be used to construct the infinitely-many conservation laws with the Lax pair is generalized from the (1+1)-dimensional nonlinear evolution equations (NLEEs) to the (2+1)-dimensional ones. Besides, we apply that method to the Kadomtsev–Petviashvili (KP) and Davey–Stewartson equations in fluids, and respectively obtain their infinitely-many conservation laws with symbolic computation. Based on that method, we can also construct the infinitely-many conservation laws for other multidimensional NLEEs possessing the Lax pairs, including the cylindrical KP, modified KP and (2+1)-dimensional Gardner equations, in fluids, plasmas, optical fibres and Bose–Einstein condensates.