全文获取类型
收费全文 | 1099篇 |
免费 | 22篇 |
国内免费 | 14篇 |
专业分类
化学 | 721篇 |
晶体学 | 15篇 |
力学 | 12篇 |
数学 | 228篇 |
物理学 | 159篇 |
出版年
2022年 | 18篇 |
2021年 | 21篇 |
2020年 | 7篇 |
2019年 | 12篇 |
2018年 | 24篇 |
2017年 | 10篇 |
2016年 | 21篇 |
2015年 | 31篇 |
2014年 | 42篇 |
2013年 | 78篇 |
2012年 | 60篇 |
2011年 | 68篇 |
2010年 | 40篇 |
2009年 | 41篇 |
2008年 | 61篇 |
2007年 | 43篇 |
2006年 | 36篇 |
2005年 | 58篇 |
2004年 | 38篇 |
2003年 | 40篇 |
2002年 | 41篇 |
2001年 | 17篇 |
2000年 | 11篇 |
1999年 | 12篇 |
1997年 | 19篇 |
1996年 | 14篇 |
1995年 | 18篇 |
1994年 | 16篇 |
1993年 | 12篇 |
1992年 | 11篇 |
1991年 | 9篇 |
1990年 | 13篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 12篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 12篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 7篇 |
1977年 | 8篇 |
1975年 | 9篇 |
1974年 | 5篇 |
1968年 | 6篇 |
1965年 | 6篇 |
1962年 | 6篇 |
排序方式: 共有1135条查询结果,搜索用时 15 毫秒
71.
Zusammenfassung Die Bestimmungsmethode für Mikromengen elementaren, in Sulfiden enthaltenen Schwefels mit Natriumazid und Jod wurde modifiziert. Der Analyse geht die Aufspaltung des S8-Ringes voraus, die man dank der nukleophilen Wirkung von N3
– in DMF-Lösung erreicht. Diese Methode wurde auf die Bestimmung des Schwefels in Indium-, Blei-, Antimon- und Wismutsulfid angewandt. Sie ist einfach und empfindlich. Ihre Fehlergrenze liegt bei ± 4%.
Determination of microamounts of sulfur after cleavage of the S8 king in indium, lead, antimony and bismuth sulfides by means of an induced reaction of sodium azide with iodine
Summary The determination of microamounts of elemental sulfur contained in sulfides using sodium azide and iodine was modified. The analysis was preceded by cleavage of the S8 ring, which is achieved by virtue of the nucleophilic action of N3 – in DMF solution. This method was applied to the determination of sulfur in indium, lead, antimony and bismuth sulfides. It is simple and sensitive. Its limit of error is ±4%.相似文献
72.
Zbigniew J. Jurek 《Journal of multivariate analysis》1983,13(4):578-604
Let
= {Ut: t > 0} be a strongly continuous one-parameter group of operators on a Banach space X and Q be any subset of a set
(X) of all probability measures on X. By
(Q;
) we denote the class of all limit measures of {Utn(μ1 * μ2*…*μn)*δxn}, where {μn}Q, {xn}X and measures Utnμj (j=1, 2,…, n; N=1, 2,…) form an infinitesimal triangular array. We define classes Lm(
) as follows: L0(
)=
(
(X);
), Lm(
)=
(Lm−1(
);
) for m=1, 2,… and L∞(
)=m=0∞Lm(
). These classes are analogous to those defined earlier by Urbanik on the real line. Probability distributions from Lm(
), m=0, 1, 2,…, ∞, are described in terms of their characteristic functionals and their generalized Poisson exponents and Gaussian covariance operators. 相似文献
73.
We show that if u is a plurisubharmonic function defined on an open subset of 2 then the Monge-Ampère measure (ddcu)2 can be well defined if and only if u belongs to the Sobolev space W1,2loc().Partially supported by KBN Grant #2 P03A 028 19 相似文献
74.
Let K be the field of real or complex numbers. Let (X K2n,) be a symplectic vector space and take 0 < k < n,N =. Let L1,...,LN X be 2k-dimensionallinear subspaces which are in a sufficiently general position.It is shown that if F : X X is a linear automorphism whichpreserves the form k on all subspaces L1,...,LN, then F is ank-symplectomorphism (that is, F* = k, where ). In particular, if K = R and k is odd then F mustbe a symplectomorphism. The unitary version of this theoremis proved as well. It is also observed that the set Al,2r ofall l-dimensional linear subspaces on which the form has rank 2r is linear in the Grassmannian G(l,2n), that is, there isa linear subspace L such that Al,2r = L G(l, 2n). In particular,the set Al,2r can be computed effectively. Finally, the notionof symplectic volume is introduced and it is proved that itis another strong invariant. 相似文献
75.
76.
Howarth DF Weil JA Zimpel Z 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,161(2):215-221
A new lineshape function is derived from the Tsallis distribution to describe electron paramagnetic resonance (EPR) spectra, and possibly nuclear magnetic resonance (NMR) spectra as well. This lineshape generalizes the Gaussian and Lorentzian lineshapes that are widely used in simulations. The main features of this lineshape function are presented: the normalization, moments, and first derivative. A number of experimental EPR spectra are compared with the results of simulations employing the new lineshape function. The results show that the new lineshape often provides a better approximation of the experimental spectrum. It is also shown that the new parameter of the lineshape function can be used to quantify the intermolecular spin-spin interactions. 相似文献
77.
Addition of dipropylamine to multiacrylate and its model compound catalyzed by lithium dipropylamide
The nucleophilic addition reaction of dipropylamine to vinyl groups of multiacrylate - poly(2-acryloyloxyethyl methacrylate)
and to 2-butyrylethyl acrylate as model compound has been investigated. Based on the results obtained, it has been shown that
the addition reaction rate of dipropylamine to multiacrylate and 2-butyrylethyl acrylate is proportional to [CH2=CH-] and to [(C3H7)2NLi] with the ratio [(C3H7)2NH]o/[(C3H7)2NLi]o = 20. Second-order addition reaction rate constants and activation energies for the systems under investigation have been
determined.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
78.
79.
Pacholska E Latos-Grazyński L Ciunik Z 《Angewandte Chemie (International ed. in English)》2001,40(23):4466-4469
80.
Ivanov PC Nunes Amaral LA Goldberger AL Havlin S Rosenblum MG Stanley HE Struzik ZR 《Chaos (Woodbury, N.Y.)》2001,11(3):641-652
We explore the degree to which concepts developed in statistical physics can be usefully applied to physiological signals. We illustrate the problems related to physiologic signal analysis with representative examples of human heartbeat dynamics under healthy and pathologic conditions. We first review recent progress based on two analysis methods, power spectrum and detrended fluctuation analysis, used to quantify long-range power-law correlations in noisy heartbeat fluctuations. The finding of power-law correlations indicates presence of scale-invariant, fractal structures in the human heartbeat. These fractal structures are represented by self-affine cascades of beat-to-beat fluctuations revealed by wavelet decomposition at different time scales. We then describe very recent work that quantifies multifractal features in these cascades, and the discovery that the multifractal structure of healthy dynamics is lost with congestive heart failure. The analytic tools we discuss may be used on a wide range of physiologic signals. (c) 2001 American Institute of Physics. 相似文献