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41.
42.
43.
Summary At first, a necessary and sufficient condition for a K?hler-Norden manifold to be holomorphic Einstein is found. Next, it
is shown that the so-called (real) generalized Einstein conditions for K?hler-Norden manifolds are not essential since the
scalarcurvature of such manifolds is constant. In this context, we study generalized holomorphic Einstein conditions. Using
the one-to-one correspondence between K?hler-Norden structures and holomorphic Riemannian metrics, we establish necessary
and sufficient conditions for K?hler-Norden manifolds to satisfy the generalized holomorphic Einstein conditions. And a class
of new examples of such manifolds is presented. Finally, in virtue of the obtained results, we mention that Theorems 1 and
2 of H. Kim and J. Kim [10] are not true in general. 相似文献
44.
Zbigniew Romanowski 《Molecular physics》2013,111(13):1339-1348
The h-adaptive, high order finite element method is applied to solve a second order one dimension eigenvalue problem. The finite element formulation for the Lobatto basis is given, for which basis functions of arbitrary order can be constructed. The adaptive algorithm is simple, yet very efficient and straightforward to implement. The algorithm is based on the observation that the expansion coefficients of Lobatto basis functions decay rapidly. It allows evaluating the smallest eigenvalues simultaneously with the comparable accuracy for all eigenvalues. The presented algorithm is applied to solve the radial Schrödinger equation with the Coulomb and the Woods–Saxon potentials. For both potentials the convergence rate is presented. After seven adaptive iterations nine-digit accuracy was obtained. 相似文献
45.
Stachurski ZH 《Physical review letters》2003,90(15):155502
It is proposed that two ideal amorphous structures, type I and type II, based on maximally random jammed packing of spheres of equal size, form a distinct class of ideal amorphous solids. The ideal amorphous structures contain wide variations in local density, limited by the condition of solidity. Four distinct characteristics, based on statistical geometry and topology, are shown to define this class. Voronoi tessellations carried out on simulated cells of random packed spheres and amorphous polymers give a broad distribution of individual volumes, skewed, with a tail at the high volume end. 相似文献
46.
Xin-tao Shuai Zbigniew Jedlinski Qiang Luo Nozirow Farhod Institute of Chemistry Chinese Academy of Sciences Beijing China Institute of Polymer Chemistry Polish Academy of Sciences - Zabrze Poland Institute of Synthetic Fibre Chinese Academy of Textile Sciences Beijing China 《高分子科学》2000,(1):19-23
A novel kind of copolymer with ABA-type block structure was synthesized by anionic ring-openingpolymerization of β-butyrolactone (β-BL) in the presence of a PEG-based dicarboxylates as macroinitiators which wereprepared by the esterification of aliphatic cyclic anhydride and poly(ethylene glycol) (PEG) oligomers (M_n=2000, 4000 and6000) and conversion of potassium dicarboxylates. The resultant copolymers as well as the intermediates were characterizedby IR,~1H-NMR and GPC. 相似文献
47.
Marek Daszkiewicz Zbigniew Staszak Adam Pietraszko Wiesława Bronowska Maria Cieślak-Golonka 《Structural chemistry》2006,17(6):599-608
Two polymeric complexes: catena(μ-CrO4-O,O′)[Co(HIm)3H2O] (1) and catena(μ-CrO4-O,O′)[Co0.43Ni0.57(HIm)3H2O] (2) (where HIm=imidazole) with a cis-bridging coordination mode of the CrO4
2− anion have been synthesized and characterized by X-ray and spectroscopic methods. These crystals were isolated from nine
systems of varying reagent molar ratios and three excluding anions: Cl−, NO3
− and SO4
2− exclusively as mer [M(HIm)3O3]-type isomers. The unit cell of these isostructural complexes (monoclinic crystal system P21
/n) contains two independent helixes, left- and right handed, stabilized by intrahelical and interhelical hydrogen bonding and
π–π interaction between pairs of the imidazole rings from neighbouring helixes. The Raman spectra at 77 K of 1 and 2 deconvoluted into lorentzian components revealed the block-type polymeric structure of the complexes. Moreover, the solution
studies at millimolar concentrations of 1 and 2 indicated their complete decomposition in water. Four K electronic spectral analysis of the crystals (band deconvolution
into gaussian components) enhanced with the data obtained in the polarized light allowed for assignment of the bands to the
respective d–d transition (D4h symmetry). It was found that the metallic centres are independently absorbing species, which supports the suggestion of a
block-type structure of the polymers. The respective crystal field parameters for Co and Ni were calculated. 相似文献
48.
Wojtczak BA Andrysiak A Grüner B Lesnikowski ZJ 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(34):10675-10682
A general approach to the synthesis of nucleoside conjugates containing carborane and metallocarborane complexes, based on Huisgen 1,3-dipolar cycloaddition ("chemical ligation"), is described. Boron-cluster-donors bearing terminal azide or ethynyl groups were prepared in the ring-opening reaction of dioxane-boron-cluster adducts and an azide anion or suitable alkynol-derived alcoholate nucleophile. Analogous derivatives bearing terminal sulfhydryl groups were also prepared. Nucleosides with various spacers containing terminal azide or ethynyl groups, located within nucleobases or sugar residues, were used as boron-cluster acceptors. The proposed methodology provides a convenient way to synthesize libraries of boron-cluster-modified nucleosides for various applications. 相似文献
49.
Pryjomska I Bartosz-Bechowski H Ciunik Z Trzeciak AM Ziółkowski JJ 《Dalton transactions (Cambridge, England : 2003)》2006,(1):213-220
The new phosphinite and phosphonite complexes (1-8) are very efficient catalysts for the methoxycarbonylation of iodobenzene and Heck cross-coupling of bromobenzene with butyl acrylate. High catalytic activity of these complexes can be explained by their in situ transformations during the reaction, stimulated by the presence of water, acid (HCl) or base (NEt(3)). Hydrolysis of phosphinite palladium complexes of the form trans-PdCl(2)[PPh(2)(OR)](2) (R = C(6)F(5), 2, (t)Bu 3, or O-menthyl 4) results in the formation of the dimeric complex [mu-ClPd(PPh(2)OH)(PPh(2)O)](2) 5, which is deprotonated by NEt(3), producing a polymeric complex of formula [Pd(P(O)PPh(2))(2)](n) 8. The reverse reaction, protonolysis of 8 with HCl, leads back to 5 and the monomeric complex 5a. The phosphinite complex PdCl(2)[PPh(2)(OBu)](2)1 with a more lipophilic ligand, PPh(2)(OBu), does not undergo hydrolysis under the same conditions. In the reaction of PdCl(2)(cod) with P(OPh)(2)(OH), the new dimer [mu-ClPd(P(OPh)(2)OH)(P(OPh)(2)O)](2) 6 was obtained, whereas reaction of Pd(OAc)(2) with P(OPh)(2)(OH) leads to the polymeric complex [Pd[P(O)(OPh)(2)](2)](n) 7. Protonolysis of 7 with HCl results in the formation of 6. 相似文献
50.
Piotr Kurcok Andrzej Matuszowicz Zbigniew Jedliski 《Macromolecular rapid communications》1995,16(3):201-206
The anionic polymerization of 2-oxetanone and 4-methyl-2-oxetanone initiated with the potassium hydride/18-crown-6 complex was investigated. The α-proton abstraction of the monomer was found to proceed at the initiation step of this polymerization. The salt of the unsaturated carboxylic acid formed initiates further propagation, leading to functionalized polyesters with unsaturated, dead end-groups. 相似文献