Adsorbate interactions of Cu(II) in Cu(II)-exchanged K-L gallosilicate studied by CW and Pulsed electron spin resonance

The interactions of Cu(II) in Cu(II)-exchanged K-L gallosilicate with adsorbates containing coordinative nitrogens in ammonia, pyridine, aniline, acetonitrile and hydrazine, and with the adsorbates carbon monoxide, benzene, propanol and dimethyl sulfoxide are investigated by electron spin resonance (ESR) and electron spin echo modulation (ESEM) spectroscopies. These results are compared with those in Cu(II)-exchanged K-L aluminosilicate and the differences are discussed. Adsorption of ammonia produces a complex containing four molecules of ammonia based on resolved nitrogen superhyperfine interaction. Upon equilibrium with pyridine, Cu(II) forms a complex containing four molecules of pyridine in CuK-L gallosilicate and a complex containing only three molecules of pyridine in CuK-L aluminosilicate based on resolved nitrogen superhyperfine. Upon adsorption of aniline and acetonitrile, Cu(II) forms complexes containing two molecules of each in CuK-L gallosilicate based on resolved nitrogen superhyperfine. However, no resolved nitrogen superhyperfine between hydrazine and Cu(II) is seen. Adsorption of carbon monoxide, benzene, propanol and dimethyl sulfoxide causes changes in the ESR spectrum of Cu(II), indicating migration of Cu(II) into cation positions in the main channels where adsorbate coordination can occur. Cu(II) forms complexes with one molecule of benzene and two molecules of propanol based on ESEM data in both K-L gallosilicate and K-L aluminosilicate. However, Cu(II) interacts directly with one dimethyl sulfoxide in K-L aluminosilicate but only indirectly at a longer distance with one dimethyl sulfoxide in K-L gallosilicate based on ESEM data.     

On the integrability of hyperbolic systems of riccati-type equations

We consider equations of the form U_xy = U * U_x, where U(x, y) is a function taking values in an arbitrary finite-dimensional algebra T over the field ℂ. We show that every such equation can be naturally associated with two characteristic Lie algebras, L_x and L_y. We define the notion of a ℤ-graded Lie algebraB corresponding to a given equation. We prove that for every equation under consideration, the corresponding algebraB can be taken as a direct sum of the vector spaces L_x and L_y if we define the commutators of the elements from L_x and L_y by means of the zero-curvature relations. Assuming that the algebra T has no left ideals, we classify the equations of the specified type associated with the finite-dimensional characteristic Lie algebras L_x and L_y. All of these equations are Darboux-integrable. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 113, No. 2, pp. 261–275, November, 1997.     

A Method for Establishing Optimality Conditions for a Nonsmooth Vector-Valued Minimax Problem

Using a method of uniform approximations, necessary and sufficient conditions for a nonsmooth constrained vector-valued minimax problem are established in terms of Mordukhovich subdifferentials.     

Inhibition of the radioactive decay of the isomer 119m Sn with the use of Mössbauer backscattering

In research on the production of beams of coherent γ rays (γ-ray lasers), conditions under which a substantial change Δλ/λ=?(0.114 ±0.027) in the radioactive decay constant λ (the isomeric level 89.53 keV ^119m Sn, T _1/2=293 days) can occur have been found experimentally for the first time. This is made possible by coherent Mo ssbauer (23.87 keV) backscattering from a resonant screen located nearby. An interpretation of the effect observed is proposed on the basis of the idea of dynamic synchronization of oscillations between a nuclear level and a standing wave of Mössbauer radiation. Possibilities for further increasing Δλ/λ up to 0.5 are found.