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991.
M. M. Eisl B. M. Reichl S. D. Böhmig H. Störi 《Fresenius' Journal of Analytical Chemistry》1994,349(1-3):194-196
Using a discrete model for the segregation kinetics based on the Darken theory of diffusion and on the regular solution model (RSM), one and two dimensional simulations of interface segregation in binary and ternary systems have been performed. The aim of the calculations was to investigate the kinetics of segregation sequences in ternary systems, the segregation kinetics in discrete systems during the initial phase and finally the kinetics of surface segregation in the region of a grain boundary intersected by the surface. 相似文献
992.
H.-J. Kluge B. A. Bushaw G. Passler K. Wendt N. Trautmann 《Fresenius' Journal of Analytical Chemistry》1994,350(4-5):323-329
Resonance ionization spectroscopy (RIS) and its combination with mass spectrometry (RIMS) have grown to become powerful techniques, which offer high sensitivity as well as elemental and isotopic selectivity. The principles of RIS and RIMS are introduced; they primarily concern the analysis of the optical spectra for the choice of efficient excitation schemes and the suitable design of the experimental apparatus. Recent applications span from studies of short-lived isotopes at on-line mass separators to a wide variety of trace analysis applications for radioactive isotopes, which can range from measurements of solar neutrino flux to environmental assessment.On leave from Pacific Northwest Laboratory, Richland, USA 相似文献
993.
B. Hornetz H.-J. Michel J. Halbritter 《Fresenius' Journal of Analytical Chemistry》1994,349(1-3):233-235
ARXPS (angle resolved X-ray photoelectron spectroscopy) measurements are used to obtain informations about surfaces and grain boundaries. Data acquired from nanocrystalline carbidic hard coatings have been employed to establish structural models. Magnetron-sputtered coatings of TiC, SiC and TiC/SiC were examined. In such coatings, partly defective TiC nanocrystallites are surrounded by interfacial carbide. This excess carbon shows a binding state similar to that of doped graphite or fullerenes. X-ray amorphous SiC is found in the residue. On top of sputtered SiC coatings, less oxide and graphite is found as compared to TiC/SiC or TiC coatings. 相似文献
994.
The soft mode dielectric response of three ferroelectric chiral smectic C* substances is studied in the vicinity of the smectic C*-smectic A* phase transition. For some substances the soft mode dielectric strength exhibits a pronounced anomaly in the C* phase just below the phase transition. We show how this anomaly can be systematically correlated with a corresponding anomaly in the experimentally determined ratio of spontaneous polarization over tilt. By comparing the experimental results with the theoretical predictions of an extended Landau model, we demonstrate how the crossover behaviour of the system can be interpreted as being the consequence of the presence of a biquadratic coupling between tilt and polarization in the Landau free-energy of the system. 相似文献
995.
Oxyethylene macrocyclic compounds (crown-ethers) act as ligands of intracrystalline cations of certain layered silicates as montmorillonites. Stable intercalation materials are formed which are used to prepare organic-inorganic membranes by encapsulating these intercalation compounds with a poly-butadiene thin coating. Electrochemical Impedance Spectroscopy (EIS) is used to study the resulting composite membranes in contact with aqueous electrolytes. From the impedance plots, the ionic resistance of the membranes is obtained. The thickness of the polybutadiene coating is an important factor determining the ability of ions to pass across the membrane. Marked differences in the ionic resistance are observed as a function of the nature of the interlayer macrocyclic compound. For non-intercalated montmorillonite membranes, the ionic resistance is strongly reduced, whereas for some crown-ether intercalated materials such as 18-crown-6 and dibenzo 24-crown-8, iono-selective membranes are obtained. Concerning the nature of the electrolyte, cations exhibiting greater hydration energies show higher difficulties to pass through the membrane and, consequently, the ionic resistance increases. 相似文献
996.
Equations are derived, which allow one to determine the electrode's surface coverage with adsorbate, charge, differential capacitance, and interfacial tension within the framework of a phenomenological model, for which the Grahame–Parsons and Alekseev–Popov–Kolotyrkin models are the limiting cases. 相似文献
997.
Simulation results are presented for the focusing of shock waves in conical and wedge-shaped cavities. Results are reported for plane waves and explosion waves. The distribution of parameters in the focusing zone is found to depend on the specific conditions. 相似文献
998.
Here we study the behaviour of the spin 0 sector of the DKP field in spaces with torsion. First we show that in a Riemann-Cartan manifold the DKP field presents an interaction with torsion when minimal coupling is performed, contrary to the behaviour of the KG field, a result that breaks the usual equivalence between the DKP and the KG fields.Next we analyse the case of the Teleparallel Equivalent of General Relativity (Weitzenböck manifold), showing that in this case there is a perfect agreement between KG and DKP fields. The origins of both results are also discussed.On leave from 相似文献
999.
In contrast to stochastic differential equation models used for the calculation of the term structure of interest rates, we
develop an approach based on linear dynamical systems under non-stochastic uncertainty with perturbations. The uncertainty
is described in terms of known feasible sets of varying parameters. Observations are used in order to estimate these parameters
by minimizing the maximum of the absolute value of measurement errors, which leads to a linear or nonlinear semi-infinite
programming problem. A regularized logarithmic barrier method for solving (ill-posed) convex semi-infinite programming problems
is suggested. In this method a multi-step proximal regularization is coupled with an adaptive discretization strategy in the
framework of an interior point approach. A special deleting rule permits one to use only a part of the constraints of the
discretized problems. Convergence of the method and its stability with respect to data perturbations in the cone of convexC
1-functions are studied. On the basis of the solutions of the semi-infinite programming problems a technical trading system
for future contracts of the German DAX is suggested and developed.
Supported by the Stiftung Rheinland/Pfalz für Innovation, No. 8312-386261/307. 相似文献
1000.
K. B. Aleinikova E. N. Zinchenko A. V. Arakcheeva V. V. Grinevich 《Crystallography Reports》2002,47(4):555-558
An amorphous sediment was prepared by the decomposition of potassium oxofluoroniobate K2 ? x Nb4O3(O, F)3F in water. For this sediment, the atomic radial distribution function was analyzed with the use of a fragment model, which allows one to interpret expanded coordination spheres as being formed by first several strongest diffusion maxima. These spheres carry the most reliable information on the structure. It is shown that the amorphous sediment consists of the randomly packed Nb(O,F)6-octahedra with interatomic distances close to those observed in the ordered region in the N-Nb2O5 structure. During decomposition in water, the initial K2 ? x Nb4O3(O, F)3F phase loses KF-layers, whereas Nb6 clusters with metal bonds are destroyed. 相似文献