The density of superconductivity in domains with corners

We compute the \(L^2\)-norm of any minimizer of the Ginzburg–Landau functional in a planar domain with a finite number of corners. Our computations are valid for a uniform applied magnetic field, large Ginzburg–Landau parameter and in the regime where superconductivity is confined near the corners of the domain.     

Dilectric and thermal properties of PEO doped with cadimium chloride salt

The main aim of this research is to investigate the effect of salt concentration on the dielectric properties(AC (σ_AC),permittivity（ε′）,dielectric loss（ε″）,and dielectric relaxation process) and melting behavior of polyethylene oxide （PEO）/CdCl₂ complexes.The dielectric study was carried out over a frequency range 10-335 kHz and a temperature range 25-45℃.The AC conductivity,permittivity and dielectric loss of the PEO/CdCl₂ complexes increase with increasing salt concentration and temperature.Also,it was found that the addition of CdCl₂ salt to PEO host reduced the melting temperature of PEO host.Dielectric results reveal that the relaxation process of these complexes is due to viscoelastic relaxation or non-Debye relaxation at room temperature.Additionally,it was found that relaxation behavior remained viscoelastic at different temperatures and salt concentrations.     

Multimaterial preform coextrusion for robust chalcogenide optical fibers and tapers

The development of robust infrared fibers is crucial for harnessing the capabilities of new mid-infrared lasers. We present a novel approach to the fabrication of chalcogenide glass fiber preforms: one-step multimaterial extrusion. The preform consists of a glass core and cladding surrounded by a built-in, thermally compatible, polymer jacket for mechanical support. Using this approach we extrude several preform structures and draw them into robust composite fibers. Furthermore, the polymer cladding allows us to produce robust tapers with submicrometer core diameter.     

Composition of the essential oil of wild growing Artemisia vulgaris from Erie, Pennsylvania

Essential oil from wild growing Artemisia vulgaris L. originating in Erie, Pennsylvania was obtained by hydrodistillation of the aerial parts of the plant. Gas chromatographic-mass spectral analysis was used to identify the major volatiles present. Up to 22 components were detected in the essential oils. Germacrene D (25%), Caryophyllene (20%), alpha-Zingiberene (15%) and Borneol (11%) represent the major components of leaf oil, while the buds were rich in 1,8-Cineole (32%), Camphor (16%), Borneol (9%), and Caryophyllene (5%). trans-2-Hexenal was also detected in the aerial parts of the plant. alpha-Zingiberene and trans-2-Hexenal have not been previously reported for Artemisia vulgaris L. The major analytes are compared to those from Artemisia vulgaris L, originating outside of the United States.     

Bromination and diazo-coupling of pyridinethiones; microwave assisted synthesis of isothiazolopyridine, pyridothiazine and pyridothiazepines

Isothiazolopyridines, pyridothiazines and pyridothiazepines are important compounds that possess valuable biological activities. This paper reports on the synthesis of these compounds using both conventional chemical methods and modern microwave techniques. 3-Bromo-6-hydroxy-4-methyl-2-thioxo-2,3-dihydropyridine-3-carboxamide, 5-arylazo-6-hydroxy-4-methyl-2-thioxo-1,2-dihydropyridine-3-carboxamides, 3,5-bis-arylazo-6-hydroxy-4-methyl-2-thioxo-2,3-dihydropyridine-3-caboxamide, 4-methyl-2,3,6,7-tetra-hydroisothiazolo[5,4-b]-pyridine-3,6-dione, 2,2'-(methylene-bis-(sulfanediyl))bis(4-methyl-6-oxo-1,6-dihydropyridine-3-carboxamide), 2-hydroxy-5-methyl-4H-pyrido[3,2-e][1,3]-thiazine-4,7(8H)-dione and 2-arylmethylene-8-hydroxy-6-methyl-2,3,4,5-tetrahydropyrido-[3,2-f][1,4]thiazepine-3,5-diones have been prepared from 6-hydroxy-4-methyl-2-thioxo-2,3-dihydropyridine-3-carboxamide. Some of these compounds were prepared using microwave-assisted reaction conditions, that provided higher yields in shorter times than the conventional methods.     

Nonlinear modeling and control of flexible-link manipulators subjected to parametric excitation

This paper presents nonlinear dynamic modeling and control of flexible-link manipulators subjected to parametric excitation. The equations of motion are obtained using the Lagrangian-assumed modes method. Singular perturbation methodology is developed for the nonlinear time varying equations of motion to obtain a reduced-order set of equations. Control strategies, computed torque control and a composite control, based on the singular perturbation formulation developed, are utilized to reduce mechanical vibrations of the flexible-link and enable better tip positioning. Under the composite control technique, the effect of the value of perturbation parameter on the control signal is investigated. Numerical simulations supported by real-time experiments show that the singular-perturbation control methodology developed for the nonlinear time-varying system offers better system response over the computed torque control as the manipulator is commanded to follow a certain trajectory.     

Synthesis,magnetic and spectral studies of iron(III), cobalt(II,III), nickel(II), copper(II) and zinc(II) complexes of 4–formylantipyrine N(4)-antipyrinylthiosemicarbazone

4–Formylantipyrine N(4)-antipyrinylthiosemicarbazone and its metal complexes have been synthesized and characterized. Elemental analyses, molar conductivities, magnetic measurements and spectral (i.r., electronic, n.m.r., e.s.r.) studies have been used to characterize the complexes. The i.r. spectra show that the thiosemicarbazones behave as bidentate (NS) or tridentate ligands (ONS), either in the thione or thiolato form. Stereochemistries are proposed for the complexes on the basis of both spectral and magnetic studies.     

Efficient penetration of the basal plane (0001) face of ice Ih by HF at Ts=150 K: dependence on incidence energy, incidence angle, and rotational energy

Classical trajectory simulations are carried out to investigate the influence of incidence energy, incidence angle, and rotational energy on the penetration of the basal plane (0001) face of ice I(h) by HF at a surface temperature (T(s)) of 150 K. The interaction of HF with ice is modelled by pair interactions, with the pair potential fitted to ab initio (Hartree-Fock+MP2) calculations. The penetration of ice by HF occurs already at very low incidence energies, viz., E(i)>/=20 kJ mol(-1). This is much lower than the threshold incidence energy obtained for penetration of ice by HCl (E(i) approximately 96.5 kJ mol(-1)); the calculated average barrier to penetration of ice by HF is 16.0 kJ mol(-1) and is much lower than that previously reported for HCl. As was the case for HCl, penetration of ice by HF decreases with decreasing incidence energy and increasing incidence angle. Though in general, the penetration probability is independent of the molecule's initial rotational energy, penetration beyond the second bilayer (deep penetration) is suppressed by initial rotation. This suggests that, like was found for HCl, the steering operative in deep penetration is inhibited by initial rotation. Finally, because HF is a weak acid experimental observation of HF penetrated into ice may well be possible using infrared spectroscopy, and we suggest experiments along this line.     

Three-fold barrier and normal coordinate analyses of (trihalomethyl)sulfenyl halides CX3-SX (X = F and Cl)

The structural stability of (trihalomethyl)sulfenyl halides CX3-SX (X is F and Cl) was investigated by DFT-B3LYP and ab initio MP2 calculations using 6-311 + G** basis set. Full energy optimizations were carried out from which the three-fold barrier about C-S bond was calculated to be about 3 kcal mol(-1) in (trifluoromethyl)sulfenyl fluoride and (trifluoromethyl)sulfenyl chloride and about 6 kcal mol(-1) in (trichloromethyl)sulfenyl fluoride and (trichloromethyl)sulfenyl chloride. The vibrational frequencies of the four molecules were computed at the DFT-B3LYP level and the vibrational assignments for the normal modes of the compounds in their ground state structure were made on the basis of normal coordinate calculations and reported experimental data.