全文获取类型
收费全文 | 302篇 |
免费 | 11篇 |
国内免费 | 1篇 |
专业分类
化学 | 171篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 95篇 |
物理学 | 44篇 |
出版年
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2017年 | 5篇 |
2016年 | 4篇 |
2015年 | 5篇 |
2014年 | 15篇 |
2013年 | 18篇 |
2012年 | 9篇 |
2011年 | 12篇 |
2010年 | 15篇 |
2009年 | 5篇 |
2008年 | 7篇 |
2007年 | 11篇 |
2006年 | 16篇 |
2005年 | 13篇 |
2003年 | 7篇 |
2002年 | 4篇 |
2001年 | 3篇 |
1987年 | 4篇 |
1982年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1973年 | 2篇 |
1971年 | 4篇 |
1970年 | 2篇 |
1969年 | 3篇 |
1968年 | 4篇 |
1967年 | 3篇 |
1966年 | 7篇 |
1965年 | 6篇 |
1964年 | 3篇 |
1963年 | 5篇 |
1962年 | 5篇 |
1961年 | 7篇 |
1960年 | 8篇 |
1959年 | 4篇 |
1958年 | 4篇 |
1957年 | 3篇 |
1956年 | 2篇 |
1947年 | 7篇 |
1946年 | 6篇 |
1945年 | 2篇 |
1944年 | 3篇 |
1943年 | 2篇 |
1942年 | 3篇 |
1941年 | 5篇 |
1940年 | 2篇 |
排序方式: 共有314条查询结果,搜索用时 31 毫秒
61.
M. Narasimhulu S. Malla Reddy K. Rajesh N. Suryakiran D. Ramesh Y. Venkateswarlu 《Heteroatom Chemistry》2008,19(4):429-433
A mild and highly efficient synthesis of chiral tetrahydroquinolino pyranose derivatives is described. The reaction of a chiral α,β‐unsaturated aldehyde containing a hydroxyl group with different aryl amines using lanthanum(III) nitrate hexahydrate as a catalyst afforded corresponding chiral tetrahydroquinolinated pyranosides in excellent yields. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:429–433, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20441 相似文献
62.
Rama Moorhy Appa S. Siva Prasad Jangam Lakshmidevi Bandameeda Ramesh Naidu Manchala Narasimhulu Katta Venkateswarlu 《应用有机金属化学》2019,33(10)
An agro waste‐derived, ‘water extract of pomegranate ash’ (WEPA), has been utilized for the first time as a renewable medium for Pd(OAc)2‐catalysed Suzuki–Miyaura cross‐coupling at room temperature. This method offers a simple and sustainable synthesis of biaryls from aryl halides and arylboronic acids under ligand‐ and external base‐free aerobic and ambient conditions. This method has been found effective for both activated and unactivated aryl halides in the production of biaryls with moderate to nearly quantitative yields. The protocol shows high chemoselectivity over identical/similar reactive sites in aryl halides (i.e. selectivity over identical halogens or different halogens of aryl halides). This method exhibits high regioselectivity, i.e. the selective reactivity of a halogen over other identical halogens at different positions on the aromatic nucleus. Therefore, we disclose here a clean, benign, substantial chemo‐ and regioselective and highly economic alternative method for the palladium‐assisted synthesis of biaryls using an agro waste‐derived medium. 相似文献
63.
Peddikotla Prabhakar Singanaboina Rajaram Yenamandra Venkateswarlu 《Tetrahedron: Asymmetry》2009,20(15):1806-1808
An Oppolzer anti-aldol approach for the synthesis of the sex pheromone (3S,5R,6S)-3,5-dimethyl-6-isopropyl-3,4,5,6-tetrahydropyran-2-one is reported. 相似文献
64.
Juttukonda V Paddock RL Raymond JE Denomme D Richardson AE Slusher LE Fahlman BD 《Journal of the American Chemical Society》2006,128(2):420-421
Tin(IV) oxide nanoparticles were synthesized via the reaction of carbon dioxide with stannate ions immobilized by dendritic polymers. For PAMAM and PPI dendrimer hosts, resultant nanoparticle diameters were 2.5-3 nm; 3-3.5 nm nanoparticles resulted from use of a poly(ethyleneimine) hyperbranched polymer. Our conditions represent the only precedent for SnO2 nanoparticulate growth using dendritic architectures, as well as a novel application for CO2 as a reactive gas for the controlled growth of metal oxide nanoparticles. 相似文献
65.
Jeon J Panchagnula V Pan J Dobrynin AV 《Langmuir : the ACS journal of surfaces and colloids》2006,22(10):4629-4637
We performed molecular dynamics simulations of multilayer assemblies of flexible polyelectrolytes and nanoparticles. The film was constructed by sequential adsorption of oppositely charged polymers and nanoparticles in layer-by-layer fashion from dilute solutions. We have studied multilayer films assembled from oppositely charged polyelectrolytes, oppositely charged nanoparticles, and mixed films containing both nanoparticles and polyelectrolytes. For all studied systems, the multilayer assembly proceeds through surface overcharging after completion of each deposition step. There is almost linear growth in the surface coverage and film thickness. The multilayer films assembled from nanoparticles show better layer stratification but at the same time have higher film roughness than those assembled from flexible polyelectrolytes. 相似文献
66.
Sana Siva Prasad Bandameeda Ramesh Naidu Marlia M. Hanafiah Jangam Lakshmidevi Ravi Kumar Marella Sivarama Krishna Lakkaboyana Katta Venkateswarlu 《Molecules (Basel, Switzerland)》2021,26(17)
Metalloporphyrins (and porphyrins) are well known as pigments of life in nature, since representatives of this group include chlorophylls (Mg-porphyrins) and heme (Fe-porphyrins). Hence, the construction of chemistry based on these substances can be based on the imitation of biological systems. Inspired by nature, in this article we present the preparation of five different porphyrin, meso-tetraphenylporphyrin (TPP), meso-tetra(p-anisyl)porphyrin (TpAP), tetrasodium meso-tetra(p-sulfonatophenyl)porphyrin (TSTpSPP), meso-tetra(m-hydroxyphenyl)porphyrin (TmHPP), and meso-tetra(m-carboxyphenyl)porphyrin (TmCPP) as well as their N-pincer Pd(II)-complexes such as Pd(II)-meso-tetraphenylporphyrin (PdTPP), Pd(II)-meso-tetra(p-anisyl)porphyrin (PdTpAP), Pd(II)-tetrasodium meso-tetra(p-sulfonatophenyl)porphyrin (PdTSTpSPP), Pd(II)-meso-tetra(m-hydroxyphenyl)porphyrin (PdTmHPP), and Pd(II)-meso-tetra(m-carboxyphenyl)porphyrin (PdTmCPP). These porphyrin N-pincer Pd(II)-complexes were studied and found to be effective in the base-free self-coupling reactions of potassium aryltrifluoroborates (PATFBs) in water at ambient conditions. The catalysts and the products (symmetrical biaryls) were characterized using their spectral data. The high yields of the biaryls, the bio-mimicking conditions, good substrate feasibility, evading the use of base, easy preparation and handling of catalysts, and the application of aqueous media, all make this protocol very attractive from a sustainability and cost-effective standpoint. 相似文献
67.
VA Tamhane DG Dhaware N Khandelwal AP Giri V Panchagnula 《Journal of colloid and interface science》2012,383(1):177-183
Bicontinuous microemulsions (BCMEs) have excellent solubulizing properties along with low interfacial tension and aqueous content that can be controlled. In this work, water soluble plant protease inhibitor (PI), well characterized for its activity against insect pests, was incorporated into a BCME system and explored for permeation on hydrophobic leaf surfaces and protease inhibition activity. The bicontinuous nature of the microemulsion containing water:2-propanol:1-butanol (55:35:10 w/w) was characterized using conductivity and self-diffusion coefficient measurements. The PI was soluble in the water-rich bicontinuous domains, stable in the microemulsions, and protease inhibition activity was retained for a prolonged duration. The microemulsions ensured greater wettability and a wider spread of the PI on hydrophobic leaf surfaces as revealed by contact angle measurements. Significantly, trypsin inhibition activity assays of the PI recovered from the leaves after delivery from the microemulsion indicated a significant increase in the PI retention on the leaf. This BCME enabled greater leaf permeation and retention of the PI can be attributed to a temporary disruption of the waxy leaf surface followed by self-repair without causing any long term damage to the plant. 相似文献
68.
Somepalli Venkateswarlu Meka Satyanarayana Gandrothu Narasimha Murthy Vidavalur Siddaiah 《Tetrahedron letters》2012,53(21):2643-2646
Cyclisation of 2-(2-aminophenyl)quinazolin-4(3H)-ones on to N3 and on to N1 leading to 6-alkyl-(8H)-quinazolino[4,3-b]quinazolin-8-one and 6-alkyl-(13H)-quinazolino[3,4-a]quinazolin-13-one, respectively was described for the first time. The differences in the IR and carbon NMR data of these isomeric fused quinazolinoquinazolinones afford a useful method for distinguishing between the two series. 相似文献
69.
With a view to understanding the role of photo-induced valence changes of impurities in BaTiO3 in the phenomena of photorefraction, EPR experiments were conducted under in situ He-Ne laser illumination. These experiments gave evidence for photoinduced valence change of Fe in BaTiO3 at room temperature. The EPR signal due to trivalent iron was found to reduce in intensity with laser illumination The kinetics
of the valence change has been investigated. Under large fringe width condition, the time constant of the decay is identified
as the dielectric relaxation time τd. The changes in line shape on laser illumination to Dysonian form, appeared most predominantly in mechanically poled crystal
compared to electrically poled single domain crystals. This demonstrated the possible role of domain walls and the defects
there, as source or sinks of charge carriers on photo excitation. It is observed, that there is transient growth of Fe3+, when the laser illumination was put on, before its decay. This was attributed to charge transfer between electrons in oxygen
vacancies and Fe4+. This predicted the growth of a transient grating under depleted pump condition in a two beam coupling experiment. This was
experimentally proved by following the diffracted signal of the reading beam under the depleted pump condition. 相似文献
70.
G A V Ramanamurthy K Ramachandra Rao Y Rama Krishna P Venkateswarlu K Bhaskara Rao P V Ramana Rao S Venkata Ratnam V Seshagiri Rao G J Nagaraju S Bhuloka Reddy 《Pramana》2001,56(5):697-703
The Measurement of K
β
K
/α
intensity ratios are measured in some 3d shell elements by using a 2 MeV proton beam along with a high resolution Si(Li) detector. The present Measurement of K
β
K
/α
intensity ratios are in good agreement with Scofield modified theoretical values, thus supporting the basic assumptions in
that theory. From the present Measurement of K
β
K
/α
intensity ratios, it is evident that due to chemical effects, the experimental Measurement of K
β
K
/α
intensity ratios will be increased while they will be decreased due to the presence of simultaneous M-shell vacancies which are produced due to proton excitation. 相似文献