Application of liquid-phase microextraction to the analysis of trihalomethanes in water

A liquid-phase microextraction method for the determination of trihalomethanes (THMs) including chloroform (CHCl₃), bromodichloromethane (CHBrCl₂), dibromochloromethane (CHBr₂Cl) and bromoform (CHBr₃) in water samples was developed, with analysis by gas chromatography-electron capture detection (GC-ECD). After the determination of the most suitable solvent and stirring rate for the extraction, several other parameters (solvent drop volume, extraction time and ionic strength of the sample) were optimized using a factorial design to obtain the most relevant variables. The optimized extraction conditions for 5 mL of sample volume in a 10 mL vial were as follows: n-hexane an organic solvent; a solvent drop volume of 2 μL; an extraction time of 5.0 min; a stirring rate of 600 rpm at 25 °C; sample ionic strength of 3 M sodium chloride. The linear range was 1-75 μg L⁻¹ for the studied THMs. The limits of detection (LODs) ranged from 0.23 μg L⁻¹ (for CHBr₂Cl) to 0.45 μg L⁻¹ (for CHCl₃). Recoveries of THMs from fortified distilled water were over 70% for a fortification level of 15 μg L⁻¹, and relative standard deviations of the recoveries were below 5%. Real samples collected from tap water and well water were successfully analyzed using the proposed method. The recovery of spiked water samples was from 73% to 78% with relative standard deviations below 7%.     

On the evolution law for the frozen fraction in linear theories of shape memory polymers

Shape memory properties of thermally responsive polymeric materials are due mainly to a phase transition from the rubbery phase above the transition temperature (glass transition or melting temperature) to the glassy or semicrystalline phase below this temperature. Within constitutive models of shape memory polymers (SMPs), this phase transition is mathematically accounted for by the frozen volume fraction for which a suitable evolution law must be postulated or derived. In this paper, the evolution laws that have been proposed in the literature are examined both from the experimental and from the theoretical point of view. It is found that the predictive capabilities of the phenomenological laws may be improved by admitting involved material constants to depend on parameters such as pre-strain, rate of heating and cooling, and other quantities characterizing thermomechanical cyclic tests. It is next shown that for a wide class of linear constitutive models of SMPs, the evolution law for the frozen volume fraction may be derived in a systematic way from strain and stress profiles experimentally obtained in the standard thermomechanical test.     

On the performance of West’s bubble test: A simulation approach

In this research we examine the ability of West’s bubble test [1] in detecting speculative bubbles using Brock’s (1982) [2] intertemporal general equilibrium model of asset pricing as the basis for a simulation study. In this setting, (1) the economy, by construction is efficient and produces the maximally possible amount of welfare for society, and (2) asset prices reflect the utility-maximizing behavior of consumers and the profit-maximizing behavior of firms. We find that the West’s bubble test flag as “bubbles” in the simulated data yet the data is produced from an economy in which markets are efficient in welfare production.     

A Distributed Evolutionary Simulated Annealing Algorithm for Combinatorial Optimisation Problems

In this paper, the Evolutionary Simulated Annealing (ESA) algorithm, its distributed implementation (dESA) and its application to two combinatorial problems are presented. ESA consists of a population, a simulated annealing operator, instead of the more usual reproduction operators used in evolutionary algorithms, and a selection operator. The implementation is based on a multi island (agent) system running on the Distributed Resource Machine (DRM), which is a novel, scalable, distributed virtual machine based on Java technology. As WAN/LAN systems are the most common multi-machine systems, dESA implementation is based on them rather than any other parallel machine. The problems tackled are well-known combinatorial optimisation problems, namely, the classical job-shop scheduling problem and the uncapacitated facility location problem. They are difficult benchmarks, widely used to measure the efficiency of metaheuristics with respect to both the quality of the solutions and the central processing unit (CPU) time spent. Both applications show that dESA solves problems finding either the optimum or a very near optimum solution within a reasonable time outperforming the recent reported approaches for each one allowing the faster solution of existing problems and the solution of larger problems.     

On Affine Connections Induced on the (1,1)-Tensor Bundle

Let M be an n-dimensional differentiable manifold with an affine connection without torsion and T_1~1(M) its(1, 1)-tensor bundle. In this paper, the authors define a new affine connection on T_1~1(M) called the intermediate lift connection, which lies somewhere between the complete lift connection and horizontal lift connection. Properties of this intermediate lift connection are studied. Finally, they consider an affine connection induced from this intermediate lift connection on a cross-section σ_ξ(M) of T_1~1(M) defined by a(1, 1)-tensor field ξ and present some of its properties.     

Boundary element analysis of driven cavity flow for low and moderate Reynolds numbers

A boundary element method for steady two‐dimensional low‐to‐moderate‐Reynolds number flows of incompressible fluids, using primitive variables, is presented. The velocity gradients in the Navier–Stokes equations are evaluated using the alternatives of upwind and central finite difference approximations, and derivatives of finite element shape functions. A direct iterative scheme is used to cope with the non‐linear character of the integral equations. In order to achieve convergence, an underrelaxation technique is employed at relatively high Reynolds numbers. Driven cavity flow in a square domain is considered to validate the proposed method by comparison with other published data. Copyright © 2001 John Wiley & Sons, Ltd.     

Effect of gamma Irradiation on Latex Film Dissolution

Latex films have been prepared by annealing pyrene (Py)-labeled poly(methyl methacrylate)-polyisobutylene particles at the glass transition temperature (100 degrees C). These films were then irradiated by gamma rays from (60)Co in a gamma cell at room temperature at various dose rates (rad/h). Before dissolution the films were annealed at 200 degrees C for a 30 min time interval to complete the film formation process. Steady-state fluorescence techniques were used to monitor the dissolution of irradiated latex films. Dissolution of films in a chloroform-heptane (80%-20%) mixture was monitored in real time by the Py fluorescence intensity change. Relaxation constants, k(0), and dissolution coefficients, D(d), of polymer chains were measured. Two different regimes of D(d) values were observed during dissolution, which are related to two different molecular weight distributions caused by scission and branching of polymer chains when they were irradiated and annealed. Copyright 2001 Academic Press.     

Surface roughness and color characteristics of wood treated with preservatives after accelerated weathering test

Wood samples treated with ammonium copper quat (ACQ 1900 and ACQ 2200), chromated copper arsenate (CCA), Tanalith E 3491 and Wolmanit CX-8 have been studied in accelerated weathering experiments. The weathering experiment was performed by cycles of 2 h UV-light irradiation followed by water spray for 18 min. The changes on the surface of the weathered samples were characterized by roughness and color measurements on the samples with 0, 200, 400 and 600 h of total weathering.

The objective of this study was to investigate the changes created by weathering on impregnated wood with several different wood preservatives. This study was performed on the accelerated weathering test cycle, using UV irradiation and water spray in order to simulate natural weathering.

Surface roughness and color measurement was used to investigate the changes after several intervals (0–200–400–600 h) in artificial weathering of treated and untreated wood.     

Analyse von Copolymeren aus Vinylestern und Acrylestern

Ohne Zusammenfassung     

Study of tissue engineered bone nodules by Fourier transform infrared spectroscopy

The key criteria for assessing the success of bone tissue engineering are the quality and quantity of the produced minerals within the cultured constructs. The accumulation of calcium ions and inorganic phosphates in culture medium serves as nucleating agents for the formation of hydroxyapatite, which is the main inorganic component of bone. Bone nodule formation is one of the hallmarks of mineralization in such cell cultures. In this study, we developed a new two-step procedure to accelerate bone formation in which mouse bone cell aggregates were produced first on various chemically treated non-adhesive substrates. After this step, the bone cells' growth and mineralization were followed in conventional culture plates. The number and size of cell aggregates were studied with light microscopy. The minerals' formation in the form of nodules produced by the cell aggregates and the bone crystal quality were studied with Fourier Transform Infrared (FTIR) spectroscopy. The FTIR spectra of the ash specimens (mineral phase only) from thermal gravimetric analysis (TGA) provided valuable information of the quality of the minerals. The υ(4) PO(4) region (550-650 cm(-1)), which reveals apatitic and non-apatitic HPO(4) or PO(4) environments, and phosphate region (910-1180 cm(-1)) were examined for the minerals produced in the form of nodules. The peak position and intensity of the spectra demonstrate that the quality of the bone produced by cell aggregates, especially from the bigger ones, which were formed on Plunoric treated substrates, exhibit a composition more similar to that of native bone. This work establishes a new protocol for high quality bone formation and characterization, with the potential to be applied to bone tissue engineering.