排序方式: 共有127条查询结果,搜索用时 15 毫秒
121.
Dipankar Bhattacharyya Ayan Ray Bibhas K. Dutta Pradip N. Ghosh 《Optics & Laser Technology》2002,34(1):93-96
It is shown that Fizeau interferometry provides an accurate optical method to measure the refractive index and wedge angle of transparent plates used as optical components in different experiments. A near IR external cavity diode laser having spectral resolution up to 10−7 has been employed to measure the refractive index of the test plates by introducing amplitude modulation technique in the detection system of our phase shifting Fizeau interferometry. Detection of spatial fringes has been performed to find out the wedge angles of the plates by using a He–Ne laser along with the CCD-image sensor. 相似文献
122.
In this Letter, we present results for detecting and recognizing 3D objects in photon counting images using integral imaging with maximum average correlation height filters. We show that even under photon starved conditions objects may be automatically recognized in passively sensed 3D images using advanced correlation filters. We show that the proposed filter synthesized with ideal training images can detect and recognize a 3D object in photon counting images, even in the presence of occlusions and obscuration. 相似文献
123.
Prof. Dr. Tarun K. Mandal Siddhartha Samanta Sourav Chakraborty Prof. Dr. Ayan Datta 《Chemphyschem》2013,14(6):1149-1154
Mixed cation (Li+, Na+ and K+) and anion (F?, Cl?, Br?) complexes of the aromatic π‐surfaces (top and bottom) are studied by using dispersion‐corrected density functional theory. The selectivity of the aromatic surface to interact with a cation or an anion can be tuned and even reversed by the electron‐donating/electron‐accepting nature of the side groups. The presence of a methyl group in the ? OCH3, ? SCH3, ? OC2H5 in the side groups of the aromatic ring leads to further cooperative stabilization of the otherwise unstable/weakly stable anion???π complexes by bending of the side groups towards the anion to facilitate C? H???anion interactions. The cooperativity among the interactions is found to be as large as 100 kcal mol?1 quantified by dissection of the three individual forces from the total interaction energy. The crystal structures of the fluoride binding tripodal and hexapodal ligands provide experimental evidence for such cooperative interactions. 相似文献
124.
P. Sreejyothi Dr. Kalishankar Bhattacharyya Shiv Kumar Dr. Pradip Kumar Hota Prof. Ayan Datta Prof. Swadhin K. Mandal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(45):11656-11662
In recent years, the applications of low-valent main group compounds have gained momentum in the field of catalysis. Owing to the accessibility of two lone pairs of electrons, NHC-stabilised phosphinidenes have been found to be excellent Lewis bases; however, they cannot yet be used as catalysts. Herein, an NHC-stabilised phosphinidene, 1,3-dimethyl-2-(phenylphosphanylidene)-2,3-dihydro-1H imidazole (1), for the activation of CO2 is reported.A closer inspection of the CO2 activation process by DFT calculations along with intrinsic bond orbital analysis shows that phosphinidene is associated with phenylsilane through a noncovalent π-π interaction between two phenyl rings which activates the Si−H bond facilitating hydride transfer to the CO2 molecule. Detailed DFT studies along with spectroscopic experiments were combined to understand the mechanism of CO2 activation and its catalytic reductive functionalisation leading to the formylation of a range of chemically inert primary amides under mild reaction conditions. 相似文献
125.
Sandip Chattopadhayay Anupam Ghosh Dr. Titas Kumar Mukhopadhyay Rashmi Sharma Prof. Ayan Datta Prof. Pinaki Talukdar 《Angewandte Chemie (International ed. in English)》2023,62(46):e202313712
The structural tropology and functions of natural cation-anion symporting channels have been continuously investigated due to their crucial role in regulating various physiological functions. To understand the physiological functions of the natural symporter channels, it is vital to develop small-molecule-based biomimicking systems that can provide mechanistic insights into the ion-binding sites and the ion-translocation pathways. Herein, we report a series of bis((R)-(−)-mandelic acid)-linked 3,5-diaminobenzoic acid based self-assembled ion channels with distinctive ion transport ability. Ion transport experiment across the lipid bilayer membrane revealed that compound 1 b exhibits the highest transport activity among the series, and it has interesting selective co-transporting functions, i.e., facilitates K+/ClO4− symport. Electrophysiology experiments confirmed the formation of supramolecular ion channels with an average diameter of 6.2±1 Å and single channel conductance of 57.3±1.9 pS. Selectivity studies of channel 1 b in a bilayer lipid membrane demonstrated a permeability ratio of , , and indicating the higher selectivity of the channel towards KClO4 over KCl salt. A hexameric assembly of a trimeric rosette of 1 b was subjected to molecular dynamics simulations with different salts to understand the supramolecular channel formation and ion selectivity pattern. 相似文献
126.
Ram Nandan Kumar Jeeban Kumar Nayak Subhasish Dutta Gupta Nirmalya Ghosh Ayan Banerjee 《Laser \u0026amp; Photonics Reviews》2024,18(2):2300189
The spin-orbit interaction (SOI) of light generated by tight focusing in optical tweezers is regularly employed in generating angular momentum - both spin and orbital - the effects being extensively observed in trapped mesoscopic particles. Specifically, the transverse spin angular momentum (TSAM), which arises due to the longitudinal component of the electromagnetic field generated by tight focusing is of special interest, both in terms of fundamental studies and associated applications. This study provides an effective and optimal strategy for generating TSAM in optical tweezers by tightly focusing first-order radially and azimuthally polarized vector beams with no intrinsic angular momentum (AM) into a refractive index stratified medium. The choice of such input fields ensures that the longitudinal spin angular momentum (LSAM) arising from the electric (magnetic) field for the radial (azimuthal) polarization is zero. As a result, the effects of the electric and magnetic TSAM are exclusively observed separately in the case of input first-order radially and azimuthally polarized vector beams on single optically trapped birefringent particles. This research opens up new and simple avenues for exotic and complex particle manipulation in optical tweezers. 相似文献
127.
Anurup Mukhopadhyay Ayan Gope Kabita Choudhury Jyotirmoy Chatterjee Rabibrata Mukherjee 《Macromolecular bioscience》2023,23(10):2300119
While a sticking plasteris enough for healing of most of the minor cuts they may get routinely, critical situations like surgical, gunshot, accidental or diabetic wounds;lacarations and other cutaneous deep cuts may require implants and simultaneous medications for healing. From the biophysical standpoint, an internal force-based physical surface stimulusis crucial for cellular sensing during wound repair. In this paper, the authors report the fabrication of a porous, biomimmetically patterned silk fibroin scaffold loaded with ampicillin, which exhibits controlled release of the drug along with possible replenishment of the same. In vitro swelling study reveals that the scaffolds with hierarchical surface patterns exhibit lower swelling and degradation than other types of scaffolds. The scaffolds, that show remarkable broad–spectrum antibacterial efficacy, exhibit Korsemeyer–Peppas model for the ampicillin release patterns due to the structural hydrophobicity imparted by the patterns. Four distinct cell-matrix adhesion regimes are investigated for the fibroblasts to eventually form cell sheets all over the hierarchical surface structures. 4',6–diamidino–2–phenylindole (DAPI) and Fluorescein Diacetate (FDA) fluorescent staining clearly demonstrate the superiority of patterned surface over its other variants. A comparative immunofluorescence study among collagen I, vinculin, and vimentin expressions substantiated the patterned surface to be superior to others. 相似文献