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71.
The electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols on graphite electrodes was studied using cyclic voltammetry, chronoamperometry, constant-potential coulometry and preparative constant-potential electrolysis techniques. The data revealed that the reduction on graphite was irreversible and followed an EC mechanism. The diffusion coefficients and the number of electrons transferred were determined using the chronoamperometric Cottrell slope and the ultramicro disc Pt-electrode steady-state current. The number of electrons was also determined by bulk electrolysis. The compounds were subjected to constant-potential preparative electrolysis and the electrolysis products were purified and identified by spectroscopic methods. Based on these findings, a mechanism for the electro-reduction process is proposed. 相似文献
72.
Stefan Cobzaş 《Acta Appl Math》2004,80(3):363-363
73.
The control of piecewise-deterministic processes is studied where only local boundedness of the data is assumed. Moreover the discount rate may be zero. The value function is shown to be solution to the Bellman equation in a weak sense; however the solution concept is strong enough to generate optimal policies. Continuity and compactness conditions are given for the existence of nonrelaxed optimal feedback controls. 相似文献
74.
75.
Selecting, modifying or creating appropriate problems for mathematics class has become an activity of increaing importance in the professional development of German mathematics teachers. But rather than asking in general: “What is a good problem?” there should be a stronger emphasis on considering the specific goal of a problem, e.g.: “What are the ingredients that make a problem appropriate for initiating a learning process” or “What are the characteristics that make a problem appropriate for its use in a central test?” We propose a guiding scheme for teachers that turns out to be especially helpful, since the newly introduced orientation on outcome standards a) leads to a critical predominance of test items and b) expects teachers to design adequate problems for specific learning processes (e.g. problem solving, reasoning and modelling activities). 相似文献
76.
A. Hoffknecht O. Uwira A. Frank S. Schennach W. Spies M. Wagner S. Schippers A. Müller R. Becker M. Kleinod N. Angert P.H. Mokler 《Hyperfine Interactions》1998,114(1-4):257-261
The origin of the widely observed enhancement of rates for electron-ion recombination at very low energies is still unknown.
We investigated the recombination of Au25+ with free electrons in a merged-beams experiment at the UNILAC accelerator of the GSI in Darmstadt. At E
rel= 0 eV we found an enormous enhancement factor of 365 compared to the theory of radiative recombination. An increase of the
electron density by a factor of 10 had not much influence on the measured rate coefficient.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
77.
78.
S. Pumplün 《manuscripta mathematica》1998,97(1):93-108
For a Brauer–Severi variety X over a field k of characteristic not two, every symmetric bilinear space over X up to Witt equivalence is defined over k.
Received: 2 February 1998 相似文献
79.
C. A. Lütken 《Journal of statistical physics》1995,78(1-2):441-451
Charge transport in two dimensions provides an ideal laboratory for investigating parameter space geometries. The Onsager relations for anisotropic transport in a parity-violating external field endow these spaces with a highly nontrivial complex (and Kähler) structure, which can be given a simple geometrical interpretation. A large class of Coulomb gases exhibiting this structure have a generalized Kramers-Wannier symmetry (complexfield duality) which is contained in the modular group. Knowledge of this symmetry and the degrees of freedom encoded in the Coulomb gas appear to be sufficient to determine the global phase diagram and the renormalization group fixed-point structure, including the critical exponents. This accounts for all the scaling behavior observed so far in the quantum Hall system. 相似文献
80.
Arno Jüschke Johannes Jahn Andreas Kirsch 《Computational Optimization and Applications》1997,7(3):261-276
In this paper we consider a special optimization problem withtwo objectives which arises in antenna theory. It is shown that thisabstract bicriterial optimization problem has at least one solution.Discretized versions of this problem are also discussed, and therelationships between these finite dimensional problems and the infinitedimensional problem are investigated. Moreover, we presentnumerical results for special parameters using a multiobjectiveoptimization method. 相似文献