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31.
S. Mann 《Fresenius' Journal of Analytical Chemistry》1960,173(1):112
Ohne Zusammenfassung 相似文献
32.
The effect of a weak convective heat transfer on the thermocapillary interaction of two bubbles with an arbitrary orientation relative to an externally imposed temperature gradient is examined. Asymptotic analysis of the case of large separation distances, Z, suggests that the corrections to the bubbles' velocities are of
(Pe/Z2), rather than
(Pe2) previously found for an isolated bubble. Equal-sized bubbles are known to move with the same velocities, as if they were isolated, when heat conduction is the only transport mechanism. However, the convective transport results in a relative motion of the bubbles. The tendency of equal bubbles to line up in a plane perpendicular to the applied thermal gradient is shown analytically in the weakly nonlinear limit of small Pe numbers, and an interesting interaction behavior in the case of unequal bubbles is discussed. 相似文献
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Mori M Oyama Y Suzuki A Takahashi K Yamada M Miyano K Miyata H Takei H Hirata KS Kajita T Kihara K Nakahata M Nakamura K Ohara S Sato N Suzuki Y Totsuka Y Yaginuma Y Koshiba M Suda T Tajima T Fukuda Y Nagashima Y Takita M Kaneyuki K Tanimori T Beier EW Frank ED Frati W Kim SB Mann AK Newcomer FM Van Berg R Zhang W 《Physical review D: Particles and fields》1991,43(9):2843-2846
36.
Microcolumns with self-assembled particle frits for proteomics 总被引:1,自引:0,他引:1
LC-MS-MS experiments in proteomics are usually performed with packed microcolumns employing frits or outlets smaller than the particle diameter to retain the packing material. We have developed packed microcolumns using self-assembled particles (SAPs) as frits that are smaller than the size of the outlet. A five to one ratio of outlet size to particle diameter appears to be the upper maximum. In these situations the particles assembled into an arch over the outlet like the stones in a stone bridge. When 3 microm particles were packed into a tapered column with an 8 microm outlet, two particles bridged the outlet with 0.3 pl dead volume and perfect success rate. In peptide analysis by LC-MS, the peak width at half height was normally less than 6 s, compared to 12 s without SAPs. The LC-MS-MS system provided 37% sequence coverage (21 matched peptides) for a tryptically-digested sample of 10 fmol bovine serum albumin. We also describe application of the SAP principle to make disposable pipette tip columns with short pieces of fused-silica capillary as the outlet. 相似文献
37.
Mann DL Ware GM Bonnin E Eitenmiller RR Barna E Christiansen S De Borde JL DeVries J Gilliland P Hemmer J Kalman A Konings E Levin D Salvati L Woollard D 《Journal of AOAC International》2005,88(1):30-37
A liquid chromatographic (LC) method was validated for the determination of total vitamin B6 in infant formula. Total vitamin B6 was quantified by converting the phosphorylated and free vitamers into pyridoxine. Pyridoxine was determined by ion pair reversed-phase LC with fluorescence detection. The method was subjected to an AOAC collaborative study involving a factory-manufactured, milk- and soy-based infant formula. Each was spiked at 3 concentrations in the range of 0-1 microg/g and sent as blind duplicate to participant laboratories. Nine laboratories returned valid data which were statistically analyzed for outliers and precision parameters. The repeatability relative standard deviation (RSD(r)) ranges were 2.0-4.0 and 3.5-5.9% for fortified milk- and soy-based formulas, respectively. The reproducibility relative standard deviation (RSD(R)) ranges were 8.2-8.4 and 6.7-11.2% for fortified milk- and soy-based formulas, respectively. HORRAT values ranged from 0.42 to 0.53, indicating that the precision of the method is acceptable. The mean RSD(r):RSD(R) values were 0.60 and 0.55 for milk- and soy-based formulas, respectively. As expected, RSDs for the unfortified samples were higher, but their HORRAT values (0.81 and 2.06) helped define a realistic limit of quantitation as 0.05 microg/g. Recovery data were quantitative and varied between 81.4 and 98.0% (mean = 89.8%) for each of 6 spiked materials. 相似文献
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(2S)- and (2R)-2-Amino-4-bromobutanoic acid were prepared starting from N-Boc-glutamic acid α tert-butyl ester. The double tert-butyl protection was necessary to prevent a partial racemisation during Barton’s radical decarboxylation used to transform the γ-carboxylic group into a bromide. This bromide reacted with different nitrogen, oxygen and sulphur nucleophiles to give nonnatural amino acids characterised by basic or heterocyclic side chains. The title compound was also used to prepare a conformationally constrained peptidomimetic. 相似文献
39.
Firas A. Khasawneh Brian P. Mann 《Communications in Nonlinear Science & Numerical Simulation》2013,18(8):2129-2141
This paper describes a general spectral element approach to study the stability of multiple time delay systems (MTDS). We show, for the first time, how this approach can be applied to periodic MTDS where the delays and the period are incommensurate. In contrast to prior works on MTDS, the spectral element approach is applicable to both autonomous as well as non-autonomous MTDS. Both MTDS of first order or higher can be obtained and systems with or without damping can be investigated. Since the spectral element approach uses efficient interpolation and a set of well-distributed interpolation points, the size of the matrices necessary for convergence is kept small. Further, since the spectral element approach is a semi-analytical procedure, it avoids the need to use tedious time marching algorithms to explore the stability behavior of the system. 相似文献
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