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排序方式: 共有110条查询结果,搜索用时 15 毫秒
21.
Yousuke Yamada Dr. Mariko Kitajima Dr. Noriyuki Kogure Dr. Sumphan Wongseripipatana Prof. Dr. Hiromitsu Takayama 《化学:亚洲杂志》2011,6(1):166-173
Seven new indole alkaloids were isolated from the roots of Gelsemium elegans Benth. and their structures were determined by spectroscopic analysis and chemical transformation from known alkaloids. Kounaminal ( 1 ) is a new koumine‐type alkaloid that contains an unusual aminal moiety. Humantenoxenine ( 2 ) and 15‐hydroxyhumantenoxenine ( 3 ) are humantenine‐type alkaloids that contain a novel β‐amino‐α,β‐unsaturated ketone residue. The other four novel alkaloids are two gelsedilam‐related and two gelsenicine‐related alkaloids. 相似文献
22.
We present a Bayesian approach to pricing longevity risk under the framework of the Lee-Carter methodology. Specifically, we propose a Bayesian method for pricing the survivor bond and the related survivor swap designed by Denuit et al. (2007). Our method is based on the risk neutralization of the predictive distribution of future survival rates using the entropy maximization principle discussed by Stutzer (1996). The method is illustrated by applying it to Japanese mortality rates. 相似文献
23.
According to one suggested model, bending of a single crystal introduces edge dislocations of the same sign. In the present study, this model is examined by computer simulation using molecular dynamics. When a notch is present on the tension surface, Heidenreich-Shockley partial dislocations are created near the tip of the notch. In the compression surface, partial dislocations are created due to wrinkling of the crystal plane. The results of simulation shows that dislocations are more easily created in a compressive bending region than in a tension bending region or simple tension region. 相似文献
24.
Mariko Kitajima Tomomi Yanagisawa Mari Tsukahara Yasuka Yamaguchi Noriyuki Kogure Ruri Kikura-Hanajiri Yukihiro Goda Osamu Iida Yasushi Sugimura Nobuo Kawahara Hiromitsu Takayama 《Tetrahedron》2018,74(4):441-452
Three new biphenyl ether quinolizidine lactone alkaloids (1–3) and 13 new biphenyl quinolizidine lactone alkaloids (4–16) were isolated from Heimia salicifolia (Lythraceae) together with seven known alkaloids. Their structures were determined by spectroscopic analyses and chemical conversions. 相似文献
25.
Inoue Y Kogure M Matsumoto K Hamashima H Tsukada M Endo K Tanaka T 《Chemical & pharmaceutical bulletin》2008,56(5):692-694
Silver loaded zeolite (Ag-Z) was previously found to have effective bactericidal activity against Escherichia coli. To understand the mechanisms of bactericidal activity of Ag-Z, role of light irradiation was focused and investigated in this study. In this study, we focused on light irradiation. Antibacterial assay and spectroscopic study revealed that light irradiation enabled Ag-Z to reduce dioxygen to form a reactive oxygen species, which led to bactericidal activity. These results indicate that the onset of bactericidal activity can be controlled by light irradiation. 相似文献
26.
Two new Phlegmarine-type alkaloids, lycoposerramines-V and -W, were isolated from Lycopodium serratum, and their structures including the absolute configuration were established by asymmetric total synthesis involving such key steps as Johnson-Claisen rearrangement, asymmetric allylation, and ring-closing metathesis (RCM)- or SmI(2)-mediated stereoselective piperidine ring construction. 相似文献
27.
Ooya T Choi HS Yamashita A Yui N Sugaya Y Kano A Maruyama A Akita H Ito R Kogure K Harashima H 《Journal of the American Chemical Society》2006,128(12):3852-3853
A biocleavable polyrotaxane, having a necklace-like structure consisting of many cationic alpha-cyclodextrins (alpha-CDs) and a disulfide-introduced poly(ethylene glycol) (PEG), was synthesized and examined as a nonviral gene carrier. The polyrotaxane formed a stable polyplex having positively charged surface even at low charge ratio. This is likely to be due to structural factors of the polyrotaxane, such as the mobile motion of alpha-CDs in the necklace-like structure. Rapid endosomal escape was observed 90 min after transfection. The positively charged surface and the good buffering capacity are advantageous to show the proton sponge effect. The pDNA decondensation occurred through disulfide cleavage of the polyrotaxane and subsequent supramolecular dissociation of the noncovalent linkages between alpha-CDs and PEG. Transfection of the DMAE-SS-PRX polyplex is independent of the amount of free polycation. Those properties played a key role for delivery of pDNA clusters to the nucleus. Therefore, the polyplex nature and the supramolecular dissociation of the polyrotaxane contributed to the enhanced gene delivery. 相似文献
28.
Iwata N Tani K Watada A Ikeura-Sekiguchi H Araki T Hitchcock AP 《Micron (Oxford, England : 1993)》2006,37(4):290-295
Toners are micron scale polymer particles constructed of several kinds of resin, pigment, wax, etc. Transmission electron microscopy (TEM) is used for observation of the dispersion of the component materials in toners, but TEM images cannot identify simultaneously all components. Scanning transmission X-ray microscopy (STXM) not only provides simultaneous observation of spatial distributions of wax, resin and carbon black in toners, but it also provides detailed, quantitative, chemical information about the wax and resin environments through chemical component maps derived from multiple energy image sequences. The capabilities of STXM for toner analysis are illustrated by results of a study of a toner for black/white copy/print applications. 相似文献
29.
Tetsuya Izu Jun Kogure Takeshi Koshiba Takeshi Shimoyama 《Designs, Codes and Cryptography》2007,43(1):47-59
The low-density attack proposed by Lagarias and Odlyzko is a powerful algorithm against the subset sum problem. The improvement
algorithm due to Coster et al. would solve almost all the problems of density <0.9408... in the asymptotical sense. On the
other hand, the subset sum problem itself is known as an NP-hard problem, and a lot of efforts have been paid to establish
public-key cryptosystems based on the problem. In these cryptosystems, densities of the subset sum problems should be higher
than 0.9408... in order to avoid the low-density attack. For example, the Chor-Rivest cryptosystem adopted subset sum problems
with relatively high densities. In this paper, we further improve the low-density attack by incorporating an idea that integral
lattice points can be covered with polynomially many spheres of shorter radius and of lower dimension. As a result, the success
probability of our attack can be higher than that of Coster et al.’s attack for fixed dimensions. The density bound is also
improved for fixed dimensions. Moreover, we numerically show that our improved low-density attack makes the success probability
higher in case of low Hamming weight solution, such as the Chor-Rivest cryptosystem, if we assume SVP oracle calls.
相似文献
30.
The present paper examines the sequential location—allocation problems of public facilities in one- and two-dimensional space under several policies. It is shown that the efficiency loss due to the adoption of a myopic policy is not so large, contrary to common belief, provided that the efficiency can be measured by the total transportation cost of users and by the total capacity of facilities. If the total serving area is sufficiently narrow, then the spatial allocations of optimal solutions in two-dimensional problems can be closely approximated by those in one-dimensional problems. 相似文献