Silver(Ⅱ) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin:An unexpected six-coordinate linear assembled structure

A novel six-coordinated silver porphyrin linear assembly was observed in silver(II) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin crystal.     

An approximation algorithm for sorting by reversals and transpositions

Genome rearrangement algorithms are powerful tools to analyze gene orders in molecular evolution. Analysis of genomes evolving by reversals and transpositions leads to a combinatorial problem of sorting by reversals and transpositions, the problem of finding a shortest sequence of reversals and transpositions that sorts one genome into the other. In this paper we present a 2k-approximation algorithm for sorting by reversals and transpositions for unsigned permutations where k is the approximation ratio of the algorithm used for cycle decomposition. For the best known value of k our approximation ratio becomes 2.8386+δ for any δ>0. We also derive a lower bound on reversal and transposition distance of an unsigned permutation.     

Synthetic transformations and biological screening of benzoxazole derivatives: A review

The presence of benzoxazole moiety in most of the heterocyclic compounds is well reported. The present literature review mainly highlights the novel synthetic transformation and describes the biological potential of most of the heterocyclic compounds by virtue of presence of benzoxazole framework. Most of the researchers have revealed that benzoxazole derivatives exhibit significant antibacterial, anti-inflammatory, antifungal, anticancer, analgesic, antiviral, anti-tubercular, and anthelmintic activities. Benzoxazole moieties also act as tyrosinase inhibitor and cholesterol ester transfer protein inhibitor. This literature review may provide an opportunity to the chemists to design new derivatives of benzoxazole that proved to be the successful agent in view of safety, effectiveness, and efficacy.     

Synthesis and Characterization of Functionalized Nanosilica for Zinc Ion Mitigation; Experimental and Computational Investigations

Zinc is an essential trace metal and its concentration above 4ppm reduces the aesthetic value of water. This study explores the possibility of using functionalized nanohybrids as Zn(II) ion scavengers from aqueous solution. Functionalized nanohybrids were synthesized by the attachment of thiosemicarbazide to silica. The material was characterized by TGA, SEM, FTIR, EDX, and BET analysis, which revealed ligand bonding to silica. The functionalized silica was employed as Zn(II) ion extractant in batch experiments and removed about 94.5% of the Zn(II) ions at pH 7, near zero point charge (6.5) in 30 min. Kinetics investigations revealed that zinc adsorption follows an intra particle diffusion mechanism and first-order kinetics (K = 0.1020 min⁻¹). The data were fitted to Freundlich, Dubinin–Radushkevich, and Langmuir models and useful ion exchange parameters were determined. The impact of co-existing ions on Zn(II) ion sequestration was also studied and it was found that the adsorbent can be used for selective removal of zinc with various ions in the matrix. Quantum mechanical investigations revealed that the Zn(II) ion adsorption on ZnBS1 is more favorable, having higher binding energy (BE) (−178.1 kcal/mol) and ∆H (−169.8), and making tridentate complex with the N and S sites of the chelating ligand. The negative ∆G and BE values suggest highly spontaneous Zn(II) adsorption on the modified silica even at low temperatures.     

Facile Oxidation Approach to Amend Surface Chemistry of Carbon Particles for Augmented Dispersion in Epoxy Matrix

Russian Journal of Applied Chemistry - Surface chemistry of carbon black (CB) plays a major role towards its dispersion in liquid media. In this study a simple approach of surface modification has...     

Magnetization of sol-gel prepared zinc ferrite nanoparticles: Effects of inversion and particle size

Nanoparticles of ZnFe₂O₄ have been prepared by using sol-gel method in two different mediums (acidic and basic) in order to observe the influence of the medium on the magnetic properties of the obtained nanoparticles. X-ray diffraction and Mössbauer studies of these samples show the presence of single-phase spinel structure. The average size of the particles as determined by X-ray diffraction increases with the annealing temperature from 18 to 52 nm. With the increase in particle size, magnetization decreases while the magnetization blocking temperature increases. Magnetization studies show that the samples prepared in basic medium have more ferrimagnetic nature as compared to those prepared in acidic medium. We understand this increase in magnetization as reflective of the increased degree of inversion (transfer of Fe³⁺ ions from octahedral to tetrahedral sites) in the particles of smaller size unit cells. From lattice parameter calculations on different particles it is determined that inversion is more favorable in the particles prepared in a basic medium than in the acidic medium due to the smaller cell size in the former.     

Analysis of flow and heat transfer of viscous fluid between contracting rotating disks

The present work investigates the effects of disks contracting, rotation and heat transfer on the viscous fluid between heated contracting rotating disks. By introducing the Von Kármán type similarity transformations through which we reduced the highly nonlinear partial differential equation to a system of ordinary differential equations. This system of differential equations with appropriate boundary conditions is responsible for the flow behavior between large but finite coaxial rotating and heated disks. It is important to note that the lower disk is rotating with angular velocity Ω while the upper one with SΩ, the disks are also contracting and the temperatures of the upper and lower disks are T₁ and T₀, respectively. The agents which driven the flow are the contraction and also the rotation of the disks. On the other hand the velocity components and especially radial component of velocity strongly influence the temperature distribution inside the flow regime. The basic equations which govern the flow are the Navier Stokes equations with well known continuity equation for incompressible flow. The final system of ordinary differential equations is then solved numerically with given boundary conditions. In addition, the effect of physical parameters, the Reynolds number (Re), the wall contraction ratio (γ) and the rotation ratio (S) on the velocity and pressure gradient, as well as, the effect of Prandtl number (Pr) on temperature distribution are also observed.