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61.
The ability of vesicle-coated silica to aid the extraction of organic compounds from water prior to liquid chromatographic analysis is presented for the first time. The method is based on the formation of silica supported cationic multi-lamellar vesicles of gemini surfactants inherently ensuring the presence of hydrophilic and hydrophobic sites for the partitioning of analytes bearing different properties. Method development is illustrated by studying the adsolubilization of UV absorbing chemicals from swimming pool water. Due to the requirement for external energy input (intense shearing) a method based on solid-phase dispersion (SPD) was applied producing better results than off-line solid-phase extraction (SPE). Meticulous investigation of the experimental parameters was conducted in order to elucidate the mechanisms behind the proposed extraction pattern. Analyte recoveries were quantitative under the optimum experimental conditions offering recoveries higher than 96% with RSD values below 5%. 相似文献
62.
Reaction of 1-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl]sulfonyl}acetone with sodium hydroxide with or without zinc gave 1-(2-nitrophenyl)(1H-pyrrol-2-ylsulfonyl)methane by a Truce-Smiles type of transformation and 1-(2-nitrophenyl)-2-methylsulfonylpyrrole by deacetylation. Similar treatment of 1-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl]sulfinyl}acetone gave only 1-(2-nitro-phenyl)(1H-pyrrol-2-ylsulfinyl)methane. 1-{[1-(2-Nitrophenyl)-1H-pyrrol-2-yl]sulfanyl}acetone, 2-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl]sulfanyl}-1-phenyl-ethan-1-one or 2-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl]sulfanyl}acetonitrile were reductively cyclised with sodium borohydride and 5% palladium-on-carbon into 6-methyl(or phenyl)-5,6-dihydro-7H-pyrrolo[1,2-a][3.1.6]benzothiadiazocin-7-ol or 6-amino-5H-pyrrolo[1,2-a][3.1.6]benzothiadiazocine-7-oxide, respectively. 相似文献
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66.
Enrico Riccardi Jee‐Ching Wang Athanasios I. Liapis 《Journal of separation science》2009,32(18):3084-3098
Recently published results determined from molecular dynamics (MD) modeling and simulation studies have shown that the spatial distribution of the density of immobilized charged ligands in ion‐exchange porous adsorbent particles is most likely nonuniform and the adsorbent particles also exhibit local nonelectroneutrality. In this work, the functional forms of the nonuniform spatial distributions of the density of the immobilized ligands in four different porous adsorbent media that were determined by MD studies were employed in a macroscopic continuum model describing the transport and adsorption of a single protein in the porous particles of the four different adsorbent media. The results clearly show that inner radial humps in the concentration profiles of the adsorbed protein can occur when the spatial distribution of the density of the immobilized ligands in the porous adsorbent particles is nonuniform and also has local maxima or minima along the radial direction in the particle. The results also indicate that the rate at which the equilibrium condition is approached depends significantly on the functional form of the spatial distribution of the density of the immobilized ligands. When adsorption equilibrium has been reached, the concentration profile of the adsorbed protein exhibits the shape of the spatial distribution of the density of the immobilized ligands. The results suggest that the technique of confocal scanning laser microscopy could be used to measure the concentration profile of an adsorbed protein at equilibrium and this measurement could provide the spatial distribution of the density of the immobilized ligands, and such measurements could also be used for quality control of the adsorbent medium. The results in this work have also implications in the modeling, design, analysis, and quality control of systems involving biocatalysis. Furthermore, the results clearly indicate that it is very important to study the dynamic behavior of an adsorption system having a nonuniform spatial distribution in the density of the immobilized charged ligands and where (i) both monovalent and multivalent interactions between the single charged adsorbate and the immobilized charged ligands occur and (ii) the values of the pH and ionic strength are such that the electrophoretic effects are active. 相似文献
67.
In general, divergences and measures of information are defined for probability vectors. However, in some cases, divergences are ‘informally’ used to measure the discrepancy between vectors, which are not necessarily probability vectors. In this paper we examine whether divergences with nonprobability vectors in their arguments share the properties of probabilistic or information theoretic divergences. The results indicate that divergences with nonprobability vectors share, under some conditions, some of the properties of probabilistic or information theoretic divergences and therefore can be considered and used as information measures. We then use these divergences in the problem of actuarial graduation of mortality rates. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
68.
Ion Victor Gosea Mihaly Petreczky Athanasios C. Antoulas Christophe Fiter 《Advances in Computational Mathematics》2018,44(6):1845-1886
We propose a model order reduction approach for balanced truncation of linear switched systems. Such systems switch among a finite number of linear subsystems or modes. We compute pairs of controllability and observability Gramians corresponding to each active discrete mode by solving systems of coupled Lyapunov equations. Depending on the type, each such Gramian corresponds to the energy associated to all possible switching scenarios that start or, respectively end, in a particular operational mode. In order to guarantee that hard to control and hard to observe states are simultaneously eliminated, we construct a transformed system, whose Gramians are equal and diagonal. Then, by truncation, directly construct reduced order models. One can show that these models preserve some properties of the original model, such as stability and that it is possible to obtain error bounds relating the observed output, the control input and the entries of the diagonal Gramians. 相似文献
69.
Grigorios Pantoleontos George Skevis George Karagiannakis Athanasios G. Konstandopoulos 《国际化学动力学杂志》2016,48(5):239-252
The present work aims to establish a generic reforming reaction scheme to evaluate the performance of catalytic reforming systems with the aid of a one‐dimensional heterogeneous dynamic model. The novelty of the numerical model stems from the direct inclusion of interphase (fluid‐to‐particle surface), intraparticle (within particle), and intrareactor heat and mass transport resistances under transient conditions. The developed model accounts for the multicomponent gas mixture physicochemical properties and correlations for calculating mass and heat transfer coefficients. Effective macroscopic properties within the particle are calculated by incorporating diffusivities and conductivities of the porous network characteristics accounting for Knudsen and molecular transport as well as tortuosity and porosity of the overall porous path. The industrial case of a steam‐methane reforming multitubular reactor was studied as the most representative case of the generic reaction scheme, with all mass/energy resistances present under severe pressure and temperature conditions. It was shown that there are notable diffusional limitations within the particle, whereas there are also temperature and partial pressure gradients due to the heat and mass transport resistances in the particle film layer. It is further demonstrated that the proposed model can be utilized as a versatile design tool for catalytic reactor development and optimization. 相似文献
70.
Georgakilas V Gournis D Bourlinos AB Karakassides MA Petridis D 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(16):3904-3908
A new approach for the synthesis of amide macrocycles, based on the use of organo-clay derivatives as controlling template, is proposed as an alternative to the rotaxane method. Dications of p-xylylene diamine inserted in the clay interlayer space act as molding pillars around which neutral diamine molecules are erected via hydrogen bonding and pi-pi interactions to form supramolecular arrays. Condensation of diamines in the supramolecular arrays with diacetyl dichlorides yields various tetramide macrocycles in good yields. Shape, aromaticity and dimensions of the reactants are factors affecting the condensation reaction. 相似文献