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931.
An expeditious one-pot synthesis of substituted pyrimidinone derivatives with aromatic aldehydes, cyclopentanone, and urea (or thiourea) was developed with boric acid (10 mol%) and glycerol (0.1 mL) in aqueous medium at 45–50 °C. The methodology is simple, highly efficient, and high yielding. The idea behind this methodology is that boric acid, being a weak acid, behaves as a strong acid in presence of glycerol in aqueous medium. 相似文献
932.
Utility of ferritin in molecular electronics, especially in single molecule electronics based devices, has recently been proposed, since the iron core of holoferritin is semiconducting in nature. However, the practical aspects, e.g., how its electronic properties can be varied/tuned, need to be better addressed. In this direction, we have performed direct tunneling experiments using scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) on several metal core reconstituted ferritins, where the reconstitution has been carried out using biocompatible metals like copper, cobalt, and manganese that are found naturally in the human body. We show, for the first time, that, by metal core reconstitution of the ferritin protein, the band gap of the protein can be tuned to different values (here, within the range 1.17-0.00 eV, considering iron-containing holoferritin and apoferritin as well). From the respective current-voltage curves and the well-defined band gaps, clear distinction can be made among the five different ferritins indicating that the metal core has direct contribution in the observed electrical conductivities of ferritins. It is further revealed that the electrical conductivities of the reconstituted ferritins are of the same order as that for the free metal conductivities, meaning that the relative changes in the free metal conductivities are reflected in the contributions of the metals in protein shell-confinement (i.e., the ~8 nm core of ferritin). This finding could lead to a strategy for fine-tuning ferritin band gap by preselecting a metal on the basis of the free metal conductivity values. 相似文献
933.
Monte Carlo simulation using the Wang-Landau algorithm has been performed in an one-dimensional Lebwohl-Lasher model. Both one-dimensional and two-dimensional random walks have been carried out. The results are compared with the exact results which are available for this model. 相似文献
934.
In data and image processing the role of optics is already well established. Due to inherent parallelism the optical systems run faster than its electronic counterparts. Optical nonlinear material can be used as a successful optical switch. The primary requirement for proper functioning of such nonlinear material based logic devices is a fixed intensity level of the optical signal against a specific logic state. In this communication, the authors propose a new concept to obtain a fixed intensity level of optical signal against a specific logic state for data processing. The scheme may extend a tremendous application not only to the area of all-optical computation, but also to optical communication process. 相似文献
935.
Sandip Chattopadhayay Anupam Ghosh Dr. Titas Kumar Mukhopadhyay Rashmi Sharma Prof. Ayan Datta Prof. Pinaki Talukdar 《Angewandte Chemie (International ed. in English)》2023,62(46):e202313712
The structural tropology and functions of natural cation-anion symporting channels have been continuously investigated due to their crucial role in regulating various physiological functions. To understand the physiological functions of the natural symporter channels, it is vital to develop small-molecule-based biomimicking systems that can provide mechanistic insights into the ion-binding sites and the ion-translocation pathways. Herein, we report a series of bis((R)-(−)-mandelic acid)-linked 3,5-diaminobenzoic acid based self-assembled ion channels with distinctive ion transport ability. Ion transport experiment across the lipid bilayer membrane revealed that compound 1 b exhibits the highest transport activity among the series, and it has interesting selective co-transporting functions, i.e., facilitates K+/ClO4− symport. Electrophysiology experiments confirmed the formation of supramolecular ion channels with an average diameter of 6.2±1 Å and single channel conductance of 57.3±1.9 pS. Selectivity studies of channel 1 b in a bilayer lipid membrane demonstrated a permeability ratio of , , and indicating the higher selectivity of the channel towards KClO4 over KCl salt. A hexameric assembly of a trimeric rosette of 1 b was subjected to molecular dynamics simulations with different salts to understand the supramolecular channel formation and ion selectivity pattern. 相似文献
936.
The European Physical Journal H - The Inter-University Centre for Astronomy and Astrophysics (IUCAA) is the second Inter-University Centre established by the Government of India for promotion of... 相似文献
937.
Kumar Ajay Chakraborty Dwaipayan Nabi Zubair Wadibhasme Nilesh Dusane Rajiv O. Johari Priya Mukhopadhyay Amartya 《Journal of Solid State Electrochemistry》2023,27(5):1227-1240
Journal of Solid State Electrochemistry - While Li transport in Si is well understood, little is known about Na transport, despite Si being considered a potential anode material for the upcoming... 相似文献
938.
Patel Yashkumar Vanpariya Anjali Mukhopadhyay Indrajit 《Journal of Solid State Electrochemistry》2023,27(2):501-510
Journal of Solid State Electrochemistry - We have developed a method which is adaptable and straightforward for the production of a negative electrode material based on Si/carbon nanotube (Si/CNTs)... 相似文献
939.
Anurup Mukhopadhyay Ayan Gope Kabita Choudhury Jyotirmoy Chatterjee Rabibrata Mukherjee 《Macromolecular bioscience》2023,23(10):2300119
While a sticking plasteris enough for healing of most of the minor cuts they may get routinely, critical situations like surgical, gunshot, accidental or diabetic wounds;lacarations and other cutaneous deep cuts may require implants and simultaneous medications for healing. From the biophysical standpoint, an internal force-based physical surface stimulusis crucial for cellular sensing during wound repair. In this paper, the authors report the fabrication of a porous, biomimmetically patterned silk fibroin scaffold loaded with ampicillin, which exhibits controlled release of the drug along with possible replenishment of the same. In vitro swelling study reveals that the scaffolds with hierarchical surface patterns exhibit lower swelling and degradation than other types of scaffolds. The scaffolds, that show remarkable broad–spectrum antibacterial efficacy, exhibit Korsemeyer–Peppas model for the ampicillin release patterns due to the structural hydrophobicity imparted by the patterns. Four distinct cell-matrix adhesion regimes are investigated for the fibroblasts to eventually form cell sheets all over the hierarchical surface structures. 4',6–diamidino–2–phenylindole (DAPI) and Fluorescein Diacetate (FDA) fluorescent staining clearly demonstrate the superiority of patterned surface over its other variants. A comparative immunofluorescence study among collagen I, vinculin, and vimentin expressions substantiated the patterned surface to be superior to others. 相似文献