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51.
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53.
V.K. Sharma S. Mitra P. Maheshwari D. Dutta P.K. Pujari R. Mukhopadhyay 《The European physical journal. Special topics》2010,189(1):273-277
Dynamics of ethylene glycol (EG) adsorbed in H-ZSM5 zeolite as studied using quasielastic neutron scattering (QENS) technique
is reported here. Analysis of QENS data revealed that observed dynamics correspond to isotropic rotational motion of EG. Rotational
diffusion coefficient of EG adsorbed in H-ZSM5 zeolite is found to be slower compared to bulk and comparable to that of benzene
adsorbed in the same host. Positron Annihilation Spectroscopy (PAS) technique is used to understand the nature of guest-host
interaction and the results of both QENS and PAS are found to be consistent with each other. 相似文献
54.
Optics has already been proved as a successful candidate for conducting parallel logic, arithmetic and algebraic operations. Several all-optical data processors were proposed since last few decades. To implement these systems, different data encoding decoding techniques such as polarization encoding, tristate, quartenary state, multivalued state, symbolic substitution technique etc. have already been proposed. All these are done to use optics in a suitable platform. We propose here a new concept of encoding data by adopting frequencies variation technique for conducting a inversion operation successfully. 相似文献
55.
We study, using fluorescence correlation spectroscopy, translational diffusion in molecularly thin liquids confined within a surface forces apparatus. The diffusion coefficient decreases exponentially from the edges towards the center of the Hertzian contact and further suggests the presence of a small number of distinct diffusion processes. This holds alike a crystallizable fluid (OMCTS) and a glass-former (1,2-propane diol), both of which displayed static friction. We conclude that friction, the average of an ensemble of molecules, masked massively heterogeneous molecular mobility. 相似文献
56.
M. Jackson G. R. Sudhakaran A. Silveira Jr. I. Mukhopadhyay R. M. Lees 《International Journal of Infrared and Millimeter Waves》1999,20(4):583-594
The high resolution Stark spectra of the singly deuterated methanol isotope, CH3OD, have been studied using the HCN laser with Stark fields up to approximately 60 000 V/cm. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations, resulting in the following assignments: with the 311 m line – J
K = 181 180
E
2,
t = 1; and with the 337 m line – J
k = 64 53
E
2,
t = 0 and J
K = 146 135
A,
t = 1. Zero-field frequencies for the assigned transitions are in agreement with Fourier transform measurements and those calculated from the available molecular constants. 相似文献
57.
Amarendra Patra Apurba K. Mukhopadhyay Alok K. Mitra Aditi K. Acharyya 《Magnetic resonance in chemistry : MRC》1981,15(1):99-101
Some carbon-13 NMR signal assignments of diazepam, flurazepam, clonazepam and chlordiazepoxide have been revised and the assignments of nitrazepam are reported. The assignments of the various resonances were made by considering the changes in chemical shifts produced by the change of substituents and also by comparison with the chemical shifts of model compounds. 相似文献
58.
59.
Mukhopadhyay S Zerella M Bell AT Srinivas RV Smith GS 《Chemical communications (Cambridge, England)》2004,(4):472-473
Methane is transformed selectively to methanesulfonyl chloride at low temperature by liquid-phase reaction of methane with SO(2)Cl(2) in the presence of a free radical initiator and a promoter using 100% H(2)SO(4) as the solvent. 相似文献
60.
Methane is catalytically converted primarily to acetic acid in concentrated sulfuric acid using a combination of Pd(2+) and Cu(2+) in the presence of oxygen. 相似文献