Chirag R. Sharma  Huma Khan  Rajendra S. Thakur  Saroj Sharma 《Macromolecular Symposia》2017,376(1):1600191

  相似文献   

    

Abad Khan  Zafar Iqbal 《液相色谱法及相关技术杂志》2017,40(4):210-216

The aim of this study is to evaluate the effect of Ramadan fasting on the fat-soluble antioxidants [all-trans-retinol (vitamin A) and α-tocopherol (vitamin E)] in healthy Pakistani subjects. Thirty (30) healthy male volunteers (aged 30–50 years) with Ramadan fasting have participated in the study. Blood sampling from these subjects was conducted 1 day before and on 15th and 28th days of Ramadan. The serum levels of vitamin A and vitamin E were measured using liquid chromatography linked with UV–visible (HPLC–UV). The comparison between the samples taken at different times was made by Minitab software applying two samples and paired t-test at (p?<?0.05) as significant. No significant changes have been found in the levels of all-trans-retinol before and during Ramadan values. The levels of α-tocopherol on 28th Ramadan have been decreased significantly when compared with its values before Ramadan (p?<?0.0001). It is concluded that there is nonsignificant change in the levels of vitamin A during the month of Ramadan while the levels of α-tocopherol have been decreased significantly on the 28th day of Ramadan. It is therefore suggested that the fasting of Ramadan has effect on the levels of α-tocopherol and food-based interventions might be necessary to modify the diet during Ramadan.  相似文献   

    

Muhammad Irfan  Javed Iqbal  Sana Sadaf  Bertil Eliasson  Usman Ali Rana  Salah Ud‐din Khan  Khurshid Ayub 《International journal of quantum chemistry》2017,117(10)

Four Donor–Acceptor–Donor (D–A–D) type of donor molecules (M1‐M4) with triphenylamine (TPA) as donor moiety, thiophene as bridge, and thiazolothiazole as acceptor unit were designed and its photovoltaic parameters were equated with reference molecule “R.” DFT functional CAM‐B3LYP/6‐31G (d,p) was found best for geometry optimization and TD‐CAM‐B3LYP/6‐31G (d,p) was found suitable for excited state calculations. Among designed donor molecules, M4 manifests suitable lowest band gap of 4.73 eV, frontier molecular orbital energy levels as well as distinctive broad absorption of 455.3 nm due to the stronger electron withdrawing group. The electron‐withdrawing substituents contribute to red shifts of absorption spectra and better stabilities for designed molecules. The theoretically determined reorganization energies of designed donor molecules suggested excellent charge mobility property. The lower λ_e values in comparison with λ_h illustrated that these four donor materials would be ideal for electron transfer and M4 would be best amongst the investigated molecules with lowest λ_e of 0.0177. Furthermore, the calculated Voc of M4 is 2.04 V with respect to PC₆₀BM (phenyl‐C61‐butyric acid methyl ester). This study revealed that the designed donor materials are suitable and recommended for high performance organic solar cell devices.  相似文献   

    

Sadia Naureen  Fatima Ijaz  Areesha Nazeer  Faryal Chaudhry  Munawar Ali Munawar  Misbahul Ain Khan 《合成通讯》2017,47(16):1478-1484

An efficient, convenient green approach for the synthesis of indole-based 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles by multicomponent reaction of substituted 2-arylindole-3-carbaldehydes, benzil, substituted anilines, and ammonium acetate using catalytic amino acid (glycine) in ethanol is described. Several amino acids have also been evaluated as organic catalysts for these reactions. The structures of the compounds have been established on the basis of infrared, mass, and ¹H NMR spectral data. The mild reaction conditions, inexpensive/economical reagents, and good yield show the usefulness of this approach.  相似文献   

    

Farah Khan  Malik Abdul Rub  Naved Azum  Abdullah M. Asiri 《Journal of Physical Organic Chemistry》2018,31(6)

Aggregation as well as thermodynamic behavior of amphiphilic imipramine hydrochloride (IMH) drug (antidepressant) and anionic surfactant (sodium dodecyl sulfate [NaDS] as well as sodium dodecylbenzenesulfonate [NaDBS]) mixtures as a function of solution composition in aqueous solutions have been evaluated by conductometry method at different temperatures. Surfactant (NaDS and NaDBS) employed in the current study is anionic in nature. Various theoretical models such as Clint, Rubingh, Motomura, and Rodenas were employed to gain information regarding the type of interaction between the components in the solution mixtures. The value of micellar mole fraction evaluated by different utilized models is found to be more for IMH‐NaDBS mixtures in comparison with IMH‐NaDS mixtures, signifying that participation of NaDBS is more in mixed micelles as compared with NaDS. Owing to the different charge of employed drug and surfactant, which sources high synergistic results in the mixed system comparative to the possessions of their pure compounds, means here anionic surfactants were elected in favor of the quantitation of cationic drug. The value of interaction parameters (β) was also evaluated by employing the Rubingh's model. The values of Gibbs free energy (∆G⁰_m) for all systems attained to be negative in all studied systems showing that the systems are spontaneous in nature.  相似文献   

    

Asim Ullah Khan  Klaus Hackl  Mattias Baitsch 《PAMM》2018,18(1)

The objective of this work is to study the effect of grain orientation on the thermal grooving by surface diffusion. Hackl et al. [1] have presented a finite element model for thermal grooving in three‐dimensions. This variational model involves surface energy, grain boundary energy, external and internal triple line energy. In this study, We use an orientation dependent surface energy. For {1 0 0} grain orientation in the normal direction, we have self‐similar groove profiles for increasing extent of anisotropy of the surface energy. For {1 1 0} and {1 1 1} orientations, there are formation of facets for critical anisotropic cases. These formations are due to so‐called missing orientations concerning the shape of an unconstrained crystal in equilibrium. The rate of grooving varies with change in the extent of surface free energy anisotropy. Flux along the triple line is also important in determining the groove root shape. Triple line energy and its mobility lead to deviate from a typical t^1/4 scaling law. For all theses simulations, grain boundary energies are constant, satisfying Herring's relation. Comparisons are made for different values of mobilities for groove shape and its growth rate, using different grain orientations.  相似文献   

         下载免费PDF全文

Hasib Khan  Cemil Tun  Wen Chen  Aziz Khan 《Journal of Applied Analysis & Computation》2018,8(4):1211-1226

In this paper, we prove necessary conditions for existence and uniqueness of solution (EUS) as well Hyers-Ulam stability for a class of hybrid fractional differential equations (HFDEs) with $p$-Laplacian operator. For these aims, we take help from topological degree theory and Leray Schauder-type fixed point theorem. An example is provided to illustrate the results.  相似文献   

    

Z. H. Khan  O. D. Makinde  R. Ahmad  W. A. Khan 《理论物理通讯》2018,70(5):641-650

This article investigates an unbiased analysis for the unsteady two-dimensional laminar flow of an incompressible, electrically and thermally conducting fluid across the space separated by two infinite rotating permeable walls.The influence of entropy generation, Hall and slip effects are considered within the flow analysis. The problem is modeled based on valid physical arguments and the unsteady system of dimensionless PDEs (partial differential equations) are solved with the help of Finite Difference Scheme. In the presence of pertinent parameters, the precise movement of the flow in terms of velocity, temperature, entropy generation rate, and Bejan numbers are presented graphically, which are parabolic in nature. Streamline profiles are also presented, which exemplify the accurate movement of the flow. The current study is one of the infrequent contributions to the existing literature as previous studies have not attempted to solve the system of high order non-linear PDEs for the unsteady flow with entropy generation and Hall effects in a permeable rotating channel. It is expected that the current analysis would provide a platform for solving the system of nonlinear PDEs of the other unexplored models that are associated to the two-dimensional unsteady flow in a rotating channel.  相似文献   

    

M. Waqas  M. Ijaz Khan  T. Hayat  A. Alsaedi 《理论物理通讯》2018,70(1):25-30

Here thermal dependence conductivity and nonlinear convection features in third-grade liquid flow bounded by moving surface having varying thickness are formulated. Stagnation point flow is considered. Revised FourierFick relations and double stratification phenomena are utilized for modeling energy and concentration expressions. Mathematical model of considered physical problem is achieved by implementing the idea of boundary layer theory. The acquired partial differential system is transformed into ordinary ones by employing relevant variables. The homotopic scheme yield convergent solutions of governing nonlinear expressions. Graphs are constructed for distinct values of physical constraints to elaborate the heat/mass transportation mechanisms.  相似文献   

    

Saeed Ullah Khattak  Zafar Iqbal  Irshad Ur Rehman  Jamshaid Ahmad  Abid Ali Khan 《Natural product research》2018,32(10):1212-1215

In the quest for bioactive natural products of fungal origin, Aspergillus flavus was isolated from rhizosphere of Mentha piperita using Potato Dextrose Agar (PDA) and Czapec Yeast Broth (CYB) nutrient media for metabolites production. In total, three different metabolites were purified using HPLC/LCMS and the structures were established using 500 Varian NMR experiments. Further the isolated metabolites in different concentrations (10, 100, 1000 μg/mL) were tested for herbicidal activity using Completely Randomized design (CRD) against the seeds of Silybum marianum and Avena fatua which are major threats to wheat crop in Pakistan. Among the isolated metabolites, one compound was found active against the test weed species whose activity is reported in the present work. The chemical name of the compound is 2-(1, 4-dihydroxybutan-2-yl)-1, 3-dihydroxy-6, 8-dimethoxyanthracene-9, 10(4aH, 9aH)-dione with mass of 388. Results showed that all seeds germinated in control treatment; however, with the metabolite treated, the growth was retarded to different levels in all parts of the weeds. At a dose of 1000 μg/mL of the pure compound, 100% seeds of S. marianum and 60% seeds of A. fatua were inhibited. Interestingly, the pure compound exhibited less inhibition of 10% towards the seeds of common wheat (Triticum aestivum).  相似文献