Nighttime enhancements in TEC near the crest of northern equatorial ionization anomaly during low solar activity period

Enhancement in nighttime total electron content (TEC) near the crest of equatorial ionization anomaly at Bhopal (Geog. 23.2°N, 77.4°E, and MLAT 14.2°N) has been studied for the solar minimum period March 2005- November 2006. TEC data recorded by GPS Ionospheric Scintillation and TEC Monitor (GISTM) GSV4004A receiver is used for the study and results are presented in the paper. More than 10% increase in TEC with respect to background content is considered for analysis. Out of total 138 enhancements, 65 observed during pre midnight hours and 73 during post midnight hours. It is observed that nighttime enhancement in TEC at Bhopal occurs in all seasons; it is more frequent during summer, less during equinox and least during winter months. The enhancement in nighttime TEC can be observed both in geomagnetic disturbed time and in quiet time. We found that mean peak amplitude for pre-midnight TEC enhancement are more in equinox and less in winter, while in post-midnight TEC enhancement it is highest in summer and less in winter. Post-midnight enhancements have smaller peak amplitude as compared to pre-midnight. Also the most probable values for pre- and post-midnights are 4.4 TECU and 2.17 TECU respectively. The percentage occurrence of nighttime TEC enhancement does not show any dependence on solar activity whereas the peak amplitude depends on solar activity. The percentage occurrence of nighttime TEC enhancement decreases as the magnetic activity increases whereas there is no such dependency found with peak amplitude. It is also observed that majority of nighttime TEC enhancements are occurred without scintillation. The localised nighttime TEC enhancements near the crest of equatorial ionization anomaly region have been observed most of the nights during the period of study.     

Thermoluminescence characteristics of inorganically and organically capped ZnS:Cu nanophosphors

ZnS:Cu nanophosphors were prepared by wet chemical methods and characterized by X-ray diffraction (XRD). The typical morphologies of the nanophosphors were investigated by scanning electron microscopy (SEM). The thermoluminescence (TL) properties of inorganically and organically passivated ZnS:Cu nanophosphors were investigated after γ-irradiation using a ⁶⁰Co source at room temperature. The TL glow curve of capped ZnS:Cu showed variation in TL peak and intensity as the capping agent was changed. Amongst the synthesized samples the TL glow curve of SiO₂ capped ZnS:Cu showed the highest TL intensity. It has been found that TL response of SiO₂ capped ZnS:Cu is linear in the range 10-550 Gy. A discussion of the obtained results is also presented.     

Ultrasonic degradation of polymers: effect of operating parameters and intensification using additives for carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA)

Use of ultrasound can yield polymer degradation as reflected by a significant reduction in the intrinsic viscosity or the molecular weight. The ultrasonic degradation of two water soluble polymers viz. carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) has been studied in the present work. The effect of different operating parameters such as time of irradiation, immersion depth of horn and solution concentration has been investigated initially using laboratory scale operation followed by intensification studies using different additives such as air, sodium chloride and surfactant. Effect of scale of operation has been investigated with experiments in the available different capacity reactors with an objective of recommending a suitable type of configuration for large scale operation. The experimental results show that the viscosity of polymer solution decreased with an increase in the ultrasonic irradiation time and approached a limiting value. Use of additives such as air, sodium chloride and surfactant helps in increasing the extent of viscosity reduction. At higher frequency operation the viscosity reduction has been found to be negligible possibly attributed to less contribution of the physical effects. The viscosity reduction in the case of ultrasonic horn has been observed to be more as compared to other large capacity reactors. Kinetic analysis of the polymer degradation process has also been performed. The present work has enabled us to understand the role of the different operating parameters in deciding the extent of viscosity reduction in polymer systems and also the controlling effects of low frequency high power ultrasound with experiments on different scales of operation.     

Resonance effects in the nonadiabatic nonlinear quantum dimer

In the presence of 1/f ^β noise, we investigate the logical stochastic resonance (LSR) in an asymmetric bistable model driven by various cycling combinations of two logic inputs. The probability of correct logic outputs is calculated according to true table of logic relationships. Two major results are presented. Firstly, it is shown that the LSR effect can be obtained by changing noise strength. Over entire range of noise variance, white noise can be considered to be better than 1/f noise or 1/f ² noise to obtain clean logic operation. At a smaller noise level, 1/f noise can realize higher output probability than white noise or 1/f ² noise. In the sense, 1/f noise can be considered to be better than white noise or 1/f ². On the other hand, the correct probability can evolves nonmonotonically as noise exponent β increases, and a kind of SR-like effect can be obtained as a result of β. At certain intermediate noise variance, the output probability is able to attain its minimum at β = 1. It is also shown that actually some finite β sometime can be better than β = 0 at small range of noise variance. The study might provide some potential complement to LSR effect in the presence of 1/f ^β noise.     

Synthesis and characterization of β-Ga2O3 nanostructures grown on GaAs substrates

β-Ga₂O₃ nanostructures including nanowires, nanoribbons and nanosheets were synthesized via thermal annealing of gold coated GaAs substrates in N₂ ambient. GaAs substrates with different dopants were taken as the starting material to study the effect of doping on the growth and photoluminescence properties of β-Ga₂O₃ nanostructures. The nanostructures were investigated by Grazing Incident X-ray Diffraction, Scanning Electron Microscopy, Transmission Electron Microscopy, Energy Dispersive X-ray Spectroscopy, room temperature photoluminescence and optical absorbance. The selected area electron diffraction and High resolution-TEM observations suggest that both nanowires and nanobelts are single crystalline. Different growth directions were observed for nanowires and nanoribbons, indicating the different growth patterns of these nanostructures. The PL spectra of β-Ga₂O₃ nanostructures exhibit a strong UV-blue emission band centered at 410 nm, 415 nm and 450 nm for differently doped GaAs substrates respectively. A weak red luminescence peak at 710 nm was also observed in all the samples. The optical absorbance spectrum showed intense absorption features in the UV spectral region. The growth and luminescence mechanism in β-Ga₂O₃ nanostructures are also discussed.     

Dielectric relaxation in polyvinylidenefluoride–polysulfone blends

Dielectric properties of polymer blend of polyvinylidenefluoride (PVDF) and polysulfone (PSF) of different wt. % have been studied to understand the molecular motion and their relaxation behavior in the frequency range of 100 Hz to 10 kHz at different temperatures between 30 and 190 °C. The dielectric constant of the blend decreased with frequency and increased with the increasing temperature and PSF content in the blend. The magnitude of dielectric loss also increased with increase in temperature and PSF content. The observed characteristic has been consistently explained in terms of dipolar motions and the plasticization effect brought about by blending of PSF with PVDF. At constant frequency and temperature, the blend follows a linear relationship between logarithm of their dielectric constant and different ratios of blend. The appearance of a peak for each concentration in dielectric loss suggests the presence of relaxing dipoles in the blend. In addition of PSF with PVDF, the peak shifts toward higher frequency side suggesting the speed up the relaxation process. AC dielectric data is also combined with thermally stimulated depolarization current (TSDC) data which is generally studied for low-frequency dielectric properties of polymers blends so as to produce the results in a wide frequency range. The glass transition temperature (T_g) of the blend was studied by differential scanning calorimetric technique (DSC), the T_g was compared and correlated with TSDC peak. The blend samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) to study the formation of blend and micro structural properties of the materials. The shifting of peak toward lower diffraction angle side confirms the reduction in particle size with increasing amorphous content in the blend.     

Absence of morphotropic phase boundary effects in BiFeO<Subscript>3</Subscript>–PbTiO<Subscript>3</Subscript> thin films grown via a chemical multilayer deposition method

We report an unusual behavior observed in (BiFeO₃)_1−x –(PbTiO₃) _x (BF–xPT) thin films prepared using a multilayer chemical solution deposition method. Films of different compositions were grown by depositing several bilayers of BF and PT precursors of varying BF and PT layer thicknesses followed by heat treatment in air. X-ray diffraction showed that samples of all compositions show mixing of two compounds resulting in a single-phase mixture, also confirmed by transmission electron microscopy. In contrast to bulk compositions, samples show a monoclinic (M_A-type) structure suggesting disappearance of the morphotropic phase boundary (MPB) at x=0.30 as observed in the bulk. This is accompanied by the lack of any enhancement of the remanent polarization at the MPB, as shown by the ferroelectric measurements. Magnetic measurements showed an increase in the magnetization of the samples with increasing BF content. Significant magnetization in the samples indicates melting of spin spirals in the BF–xPT films, arising from a random distribution of iron atoms. Absence of Fe²⁺ ions was corroborated by X-ray photoelectron spectroscopy measurements. The results illustrate that thin film processing methodology significantly changes the structural evolution, in contrast to predictions from the equilibrium phase diagram, besides modifying the functional characteristics of the BP-xPT system dramatically.     

Second order symmetric duality in nondifferentiable multiobjective fractional programming with cone convex functions

In the present paper, we consider Mond-Weir type nondifferentiable second order fractional symmetric dual programs over arbitrary cones and derive duality results under second order K?F-convexity/K?F-pseudoconvexity assumptions. Our results generalize several known results in the literature.     

Nano-iron oxide-encapsulated chitosan microspheres as novel adsorbent for removal of Ni (II) ions from aqueous solution

The present study investigates the utility of composite beads of nano-particles of iron oxide and chitosan for removing Ni (II) ions from aqueous solution by batch and column adsorption techniques. In the batch mode experiment, the influence of pH, concentration, adsorbent dose, temperature, column mode, bed height, flow rate and initial concentration were studied on the adsorption profiles of nickel ions. The maximum uptake of Ni (II) ions was obtained at pH 4.0 in 30 min at room temperature.