全文获取类型
收费全文 | 225篇 |
免费 | 5篇 |
专业分类
化学 | 154篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 36篇 |
物理学 | 37篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 8篇 |
2019年 | 7篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 5篇 |
2015年 | 6篇 |
2014年 | 11篇 |
2013年 | 19篇 |
2012年 | 17篇 |
2011年 | 26篇 |
2010年 | 9篇 |
2009年 | 9篇 |
2008年 | 13篇 |
2007年 | 8篇 |
2006年 | 12篇 |
2005年 | 9篇 |
2004年 | 10篇 |
2003年 | 3篇 |
2002年 | 6篇 |
2001年 | 2篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1980年 | 1篇 |
1933年 | 2篇 |
1932年 | 2篇 |
排序方式: 共有230条查询结果,搜索用时 15 毫秒
31.
Ridaphun Nongrum George Kupar Kharmawlong Jims World Star Rani Noimur Rahman Arup Dutta Rishanlang Nongkhlaw 《Journal of heterocyclic chemistry》2019,56(10):2873.-2883
The development of a metal‐free protocol for transformations in organic synthesis offers a significant potential environmental benefit. This article reports the exploration of meglumine, a nontoxic and biodegradable amino sugar, as an organocatalyst for the synthesis of biologically active 1H‐dibenzo[b,e][1,4]diazepin‐1‐ones, highly regioselective benzimidazole derivatives and derivatives of quinoxalines. Operational simplicity, mild reaction conditions, shorter reaction times, and use of green solvents are the highlights of this protocol. The advantage of ultrasonic irradiation has been significantly explored for the synthesis of the aforesaid compounds. Furthermore, the multifaceted use of o‐phenylenediamine has also been accentuated in the study. 相似文献
32.
Structural Chemistry - The N-methyl-D-aspartate (NMDA) is the family of glutamate receptor, which is involved in controlling synaptic plasticity and memory function; but overactivation of this... 相似文献
33.
G. Benz H. Lüers P. Bohrisch M. Tortelli R. Ruggeri W. Otte E. Kröger W. Lühr H. Schmalfuß H. Werner R. Strohecker J. Großfeld A. Beckel H. Thaler K. Täufel K. Richter H. Damm E. Ruppol H. A. A. Aitken R. Delaby Yvonne Breugnot S. F. Juschkewitsch N. M. Ssokolow P. Arup J. T. Minster 《Analytical and bioanalytical chemistry》1933,94(7-8):286-295
34.
Biswas R Das AR Pradhan T Touraud D Kunz W Mahiuddin S 《The journal of physical chemistry. B》2008,112(21):6620-6628
Catanionic microemulsions formed by dodecyltrimethylammonium bromide (DTAB), sodium dodecyl sulfate (SDS), n-hexanol, dodecane, and citrate buffer have been characterized by using dynamic light scattering (DLS) and spectroscopic studies. While the DLS measurements provide information about the hydrodynamic diameters of the microemulsion droplets formed upon variation of the constituents, steady-state and time-resolved fluorescence emission experiments probe the polarity and the dynamics of the trapped solvent pool inside of the microemulsion droplets of nanometer dimension. In addition, time-resolved fluorescence anisotropy shows the rigidity of the confined solvent pool as well as the coupling between the motion of a solute and those of the solvent molecules. The results obtained from the DLS and those from the steady-state and time-resolved fluorescence emission studies have been found to correlate well with the superactivity of horseradish peroxidase enzyme in the catanionic microemulsions. Subsequently, the time-zero estimate for the dynamic Stokes shift in these microemulsions reveals that approximately 50% of the total solvent dynamical response is missed due to the limited time resolution employed in our experiments. The amplitude of the missing portion is similar to what has been observed recently for nanoscopic water by Fayer and co-workers (Piletic, I. R.; Tan, H.-S.; Fayer, M. D. J. Phys. Chem. B 2005, 109, 21273). 相似文献
35.
We have studied the properties of various isomers of potassium clusters containing even number of atoms ranging from 2 to 20 at the ab initio level. The geometry optimization calculations of the isomers of each cluster are performed by using all-electron density functional theory with gradient corrected exchange-correlation functional. Using the optimized geometries of different isomers we investigate the evolution of binding energy, ionization potential, and static polarizability with the increasing size of the clusters. The polarizabilities are calculated by employing M?ller-Plesset perturbation theory and time-dependent density functional theory. The polarizabilities of dimer and tetramer are also calculated by employing large basis set coupled cluster theory with single and double excitations and perturbative triple excitations. The time-dependent density functional theory calculations of polarizabilities are carried out with two different exchange-correlation potentials: (i) an asymptotically correct model potential and (ii) within the local density approximation. A systematic comparison with the other available theoretical and experimental data for various properties of small potassium clusters mentioned above has been performed. These comparisons reveal that both the binding energy and the ionization potential obtained with gradient-corrected potential match quite well with the already published data. Similarly, the polarizabilities obtained with M?ller-Plesset perturbation theory and with model potential are quite close to each other and also close to experimental data. 相似文献
36.
This article deals with isomeric ruthenium complexes [RuIII(LR)2(acac)] (S=1/2) involving unsymmetric β‐ketoiminates (AcNac) (LR=R‐AcNac, R=H ( 1 ), Cl ( 2 ), OMe ( 3 ); acac=acetylacetonate) [R=para‐substituents (H, Cl, OMe) of N‐bearing aryl group]. The isomeric identities of the complexes, cct (cis‐cis‐trans, blue, a ), ctc (cis‐trans‐cis, green, b ) and ccc (cis‐cis‐cis, pink, c ) with respect to oxygen (acac), oxygen (L) and nitrogen (L) donors, respectively, were authenticated by their single‐crystal X‐ray structures and spectroscopic/electrochemical features. One‐electron reversible oxidation and reduction processes of 1 – 3 led to the electronic formulations of [RuIII(L)(L ? )(acac)]+ and [RuII(L)2(acac)]? for 1 +‐ 3 + (S=1) and 1? – 3? (S=0), respectively. The triplet state of 1 +‐ 3 + was corroborated by its forbidden weak half‐field signal near g≈4.0 at 4 K, revealing the non‐innocent feature of L. Interestingly, among the three isomeric forms ( a – c in 1 – 3 ), the ctc ( b in 2 b or 3 b ) isomer selectively underwent oxidative functionalization at the central β‐carbon (C?H→C=O) of one of the L ligands in air, leading to the formation of diamagnetic [RuII(L)(L ′ )(acac)] (L ′ =diketoimine) in 4 / 4′ . Mechanistic aspects of the oxygenation process of AcNac in 2 b were also explored via kinetic and theoretical studies. 相似文献
37.
BOSE Arup 《中国科学A辑(英文版)》2009,(6)
We study the asymptotic distribution of the L1 regression estimator under general condi-tions with matrix norming and possibly non i.i.d.errors.We then introduce an appropriate bootstrap procedure to estimate the distribution of this estimator and study its asymptotic properties.It is shown that this bootstrap is consistent under suitable conditions and in other situations the bootstrap limit is a random distribution. 相似文献
38.
Stachowiak JC Yue M Castelino K Chakraborty A Majumdar A 《Langmuir : the ACS journal of surfaces and colloids》2006,22(1):263-268
When biomolecular reactions occur on one surface of a microcantilever beam, changes in intermolecular forces create surface stresses that bend the cantilever. While this phenomenon has been exploited to create label-free biosensors and biomolecular actuators, the mechanisms through which chemical free energy is transduced to mechanical work in such hybrid systems are not fully understood. To gain insight into these mechanisms, we use DNA hybridization as a model reaction system. We first show that the surface grafting density of single-stranded probe DNA (sspDNA) on a surface is strongly correlated to its radius of gyration in solution, which in turn depends on its persistence length and the DNA chain length. Since the persistence length depends on ionic strength, the grafting density of sspDNA can be controlled by changing a solution's ionic strength. The surface stresses produced by the reaction of complementary single-stranded target DNA (sstDNA) to sspDNA depend on the length of DNA, the grafting density, and the hybridization efficiency. We, however, observe a remarkable trend: regardless of the length and grafting density of sspDNA, the surface stress follows an exponential scaling relation with the density of hybridized sspDNA. 相似文献
39.
40.
Somshubhro Bandyopadhyay Manik Banik Some Sankar Bhattacharya Sibasish Ghosh Guruprasad Kar Amit Mukherjee Arup Roy 《Foundations of Physics》2017,47(2):265-273
We show that within the class of ontological models due to Harrigan and Spekkens, those satisfying preparation-measurement reciprocity must allow indeterminism comparable to that in quantum theory. Our result implies that one can design quantum random number generator, for which it is impossible, even in principle, to construct a reciprocal deterministic model. 相似文献