Density and energy relaxation in an open one-dimensional system

A new master equation to mimic the dynamics of a collection of interacting random walkers in an open system is proposed and solved numerically. In this model, the random walkers interact through excluded volume interaction (single-file system); and the total number of walkers in the lattice can fluctuate because of exchange with a bath. In addition, the movement of the random walkers is biased by an external perturbation. Two models for the latter are considered: (1) an inverse potential (V proportional, variant 1/r), where r is the distance between the center of the perturbation and the random walker and (2) an inverse of sixth power potential (V proportional, 1/r6). The calculated density of the walkers and the total energy show interesting dynamics. When the size of the system is comparable to the range of the perturbing field, the energy relaxation is found to be highly nonexponential. In this range, the system can show stretched exponential (e-(t/taus)beta) and even logarithmic time dependence of energy relaxation over a limited range of time. Introduction of density exchange in the lattice markedly weakens this nonexponentiality of the relaxation function, irrespective of the nature of perturbation.     

Preferential solvation in three component systems: Evaluation of Kirkwood-Buff parameters

The extent of local excess or deficiency of a component solvent near the solute in a mixed binary solvent has been calculated using the Hall formalism for the Kirkwood-Buff equation. The possibility of calculation of the two solute-solvent Kirkwood-Buff parameters using the values is discussed. A model calculation using literature data for preferential solvation in mixed binary solvents is presented. The solute-solvent and solvent-solvent interactions and the relative size of the solvents are also shown to be relevant factors in determining the values.     

Fluorescence resonance energy transfer (FRET) in chemistry and biology: Non-F?rster distance dependence of the FRET rate

Fluorescence resonance energy transfer (FRET) is a popular tool to study equilibrium and dynamical properties of polymers and biopolymers in condensed phases and is now widely used in conjunction with single molecule spectroscopy. In the data analysis, one usually employs the F?rster expression which predicts (l/R ⁶) distance dependence of the energy transfer rate. However, critical analysis shows that this e_xpression can be of rather limited validity in many cases. We demonstrate this by explicitly considering a donor-acceptor system, polyfluorene (PF₆)-tetraphenylporphyrin (TPP), where the size of both donor and acceptor is comparable to the distance separating them. In such cases, one may expect much weaker distance (as l/R ² or even weaker) dependence. We have also considered the case of energy transfer from a dye to a nanoparticle. Here we find l/R ⁴ distance dependence at large separations, completely different from F?rster. We also discuss recent application of FRET to study polymer conformational dynamics. Dedicated to Prof J Gopalakrishnan on his 62nd birthday.     

The field emission total energy distribution in the presence of adsorbates

The total energy distribution (TED) of field-emitted electrons from an adsorbate-covered metal surface is studied within the framework of the Anderson Hamiltonian, but taking overcompleteness of states into account. The correct asymptotic behavior of the adsorbate wavefunction, postulated in the previous work, is now established, and a numerical correction factor (~15) to the adsorbate induced current density is obtained.     

The large N limit of the O(N) Heisenberg spin system in two dimensions

The large N limit of the O(N) Heisenberg spin system in two dimensions (a lattice version of the non-linear σ-model) is analysed by the collective field technique. A compact expression for the mass gap and the β-function is obtained for arbitrary but fixed gN. The strong and weak coupling limits of this expression correctly reproduce the known results.     

Optics of metal surfaces by reflectance of p-polarized light

A new expression is derived for the differential reflectance from an arbitrary metal surface, with chemisorbed impurities, using $\text{p}$-polarized radiation. The use of the result, which depends entirely on the dielectric response tensor of the system, to study experimental Surface Reflectance data is discussed.     

Notes on binary codes related to the O(5, q) generalized quadrangle for odd q

In this note we determine the dimensions of the binary codes spanned by the lines or by the point neighborhoods in the generalized quadrangle Sp(4, q) and its dual O(5, q), where q is odd. Several more general results are given. As a side result we find that if a square generalized quadrangle of odd order has an antiregular point, then all of its points are antiregular.On leave from the Indian Statistical Institute, Calcutta; research supported by a grant from NWO.