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181.
Maria Celeste Dias Diana C. G. A. Pinto Artur M. S. Silva 《Molecules (Basel, Switzerland)》2021,26(17)
In recent years, more attention has been paid to natural sources of antioxidants. Flavonoids are natural substances synthesized in several parts of plants that exhibit a high antioxidant capacity. They are a large family, presenting several classes based on their basic structure. Flavonoids have the ability to control the accumulation of reactive oxygen species (ROS) via scavenger ROS when they are formed. Therefore, these antioxidant compounds have an important role in plant stress tolerance and a high relevance in human health, mainly due to their anti-inflammatory and antimicrobial properties. In addition, flavonoids have several applications in the food industry as preservatives, pigments, and antioxidants, as well as in other industries such as cosmetics and pharmaceuticals. However, flavonoids application for industrial purposes implies extraction processes with high purity and quality. Several methodologies have been developed aimed at increasing flavonoid extraction yield and being environmentally friendly. This review presents the most abundant natural flavonoids, their structure and chemical characteristics, extraction methods, and biological activity. 相似文献
182.
183.
Maciej Dawidowski Sławomir Sobczak Marcin Wilczek Artur Kulesza Jadwiga Turło 《Molecular diversity》2014,18(1):61-77
Various symmetrical and unsymmetrical ketones were successfully coupled with secondary amino acids in the course of Ugi five-center, four-component reaction (U-5C-4CR), thus expanding the molecular diversity possible to be achieved by the reaction. The chemical yields depended on the degree of hindrance of the components employed and were satisfactory in view of possible steric interactions in the U-5C-4CR zwitterionic intermediate. The sense of diastereoinduction for reactions employing unsymmetrical ketones was examined by converting the resulting Ugi adducts into the corresponding rigid 2,6-diketopiperazine derivatives. 相似文献
184.
A computational analysis of excited round jets is presented with emphasis on jet bifurcation phenomenon due to superposition of axial and flapping forcing terms. Various excitation parameters are examined including the amplitudes of the forcing, their frequencies and phase shift. It is shown that alteration of these parameters significantly influences the spatial jet evolution. This dependence may be used to control the jet behaviour in a wide range of qualitatively different flow structures, starting from a modification of the spreading rate of a single connected jet, through large scale deformation of an asymmetric jet, onto jet bifurcation leading to a doubly and even triply split time-averaged jet, displaying different strengths and locations of the branches. We establish that: (i) jet splitting is possible only when the amplitudes of the forcing terms are comparable to or larger than the level of natural turbulence; (ii) the angle between the developing jet branches can be directly controlled by the frequency of the axial forcing and the phase shift between axial and flapping forcing. An optimum forcing frequency is determined, leading to the largest spreading rate. 相似文献
185.
Mariusz P. Mitoraj Goran V. Janjić Vesna B. Medaković Dušan Ž. Veljković Artur Michalak Snežana D. Zarić Miloš K. Milčić 《Journal of computational chemistry》2015,36(3):171-180
The water/aromatic parallel alignment interactions are interactions where the water molecule or one of its O? H bonds is parallel to the aromatic ring plane. The calculated energies of the interactions are significant, up to ΔECCSD(T)(limit) = ?2.45 kcal mol?1 at large horizontal displacement, out of benzene ring and CH bond region. These interactions are stronger than CH···O water/benzene interactions, but weaker than OH···π interactions. To investigate the nature of water/aromatic parallel alignment interactions, energy decomposition methods, symmetry‐adapted perturbation theory, and extended transition state‐natural orbitals for chemical valence (NOCV), were used. The calculations have shown that, for the complexes at large horizontal displacements, major contribution to interaction energy comes from electrostatic interactions between monomers, and for the complexes at small horizontal displacements, dispersion interactions are dominant binding force. The NOCV‐based analysis has shown that in structures with strong interaction energies charge transfer of the type π → σ*(O? H) between the monomers also exists. © 2014 Wiley Periodicals, Inc. 相似文献
186.
Pereira RF Valente AJ Fernandes M Burrows HD 《Physical chemistry chemical physics : PCCP》2012,14(20):7517-7527
The interaction of sodium octanoate, decanoate or dodecanoate with calcium(ii) in aqueous solutions has been studied using turbidity, conductivity and potentiometric measurements. These show a marked alkyl chain length dependence on the behaviour. At the calcium concentration used (1.0 mM), there is little interaction with the octanoate, the decanoate shows initially formation of a 1:1 complex, followed by precipitation, while the dodecanoate precipitates at low surfactant concentrations. The solid calcium carboxylates were prepared, and show lamellar, bilayer structures with planes of calcium(II) ions coordinated to carboxylate groups through bidentate chelate linkages. Thermogravimetry and elemental analyses indicate the presence of coordinated water with the calcium decanoate but not with longer chain carboxylates. The results of both the solution and solid state studies suggest that precipitation of long-chain carboxylates depends on a balance between hydration effects and hydrophobic (largely van der Waals') interactions. Electrostatic effects make little energetic contribution but play the important structural role of ordering the carboxylate anions before precipitation. Differences are observed in the interactions between calcium(II) and long chain alkylcarboxylates and alkylsulfates, and are interpreted in terms of stronger binding to the metal of the carboxylate group. A general mechanism is proposed for calcium carboxylate precipitation from aqueous solution based on this and previous studies. 相似文献
187.
Organically modified clays exhibit adsorption capacities for cations, anions, and nonpolar organic compounds, which make them valuable for various environmental technical applications. To improve the understanding of the adsorption processes, the molecular-scale characterization of the structures of organic aggregates assembled on the external basal surfaces of clay particles is essential. The focus of this Monte Carlo simulation study was on the effects of the surface coverage and the alkyl chain length n on the structures of alkyltrimethylammonium chloride ((C(n)TMA)Cl) aggregates assembled on the montmorillonite-water interface. We found that the amount of adsorbed C(n)TMA(+) ions is independent of the alkyl chain length and increases with the C(n)TMA(+) surface coverage. The C(n)TMA(+) ions predominantly adsorb as inner-sphere complexes; the fraction of outer-sphere adsorbed ions equals only about 10%. The conformational order of the C(n)TMA(+) alkyl chains substantially decreases with decreasing alkyl chain length. In agreement with previous experiments, the amount of C(n)TMA(+) ions that are aggregated at the mineral surface increases with increasing chain length. The maximum value of 0.66 C(n)TMA(+) adsorption complex per unit cell area of the clay surface considerably exceeds the amount of cations required to compensate the negative charge of the montmorillonite surface. Furthermore, in most of the studied systems, fractions of Na(+) surface cations remain adsorbed on montmorillonite. The resulting interfacial positive charge excess is counterbalanced by coadsorbed chloride ions forming ion pairs with both C(n)TMA(+) and Na(+). 相似文献
188.
Protein microspheres have been prepared by sonicating a mixture of pure fragrant oil (amyl acetate (AA)) with an aqueous protein (bovine serum albumin) solution. The prepared protein spheres are nano- to micrometer sized with an encapsulation efficiency of approx. 97% for the AA present on the surface and inside the BSA capsule. Containers were found stable for more than 6 months when stored sealed at 4 °C and 20 °C. For the release profile measurements, we used a simple, automated and direct method. We continuously weighed the encapsulated microspheres and measured the evaporation rates. The release profiles at 15 °C and 25 °C display two different evaporation rates. The higher rate is the sum of a few evaporation rates, including water molecules, while the slower rate is due to the evaporation of pure AA. The changes in the evaporation rates occur upon the collapse of the container. This event coincides with the full evaporation of water. For morphological characterization we dyed the AA with Nile red, and used SEM, ESEM, Cryo-SEM, light microscopy, and confocal laser scanning microscopy measurements. 相似文献
189.
Deperasińska I Gryko DT Karpiuk E Kozankiewicz B Makarewicz A Piechowska J 《The journal of physical chemistry. A》2012,116(9):2109-2116
Absorption, fluorescence, and fluorescence excitation spectra of 12-hydroxy-1-azaperylene (HAP) and 1-azaperylene were studied in n-alkane matrices at 5 K. Two stable tautomers of HAP, each of them in n-nonane embedded in two sites, were identified and attributed to the enol and keto forms. Theoretical calculations of the energy and vibrational structure of the spectra suggest that tautomer A, with the (0, 0) transition energy at 18,980 ± 10 cm(-1) (and 19,060 ± 10 cm(-1) in the high energy site), should be identified as the keto form, whereas tautomer B, with the (0, 0) energy at 19,200 ± 20 cm(-1) (19,290 ± 20 cm(-1)), as the enol form. Observation of absorption and fluorescence of both tautomeric forms and lack of large Stokes shift of fluorescence of the keto form classify HAP as the limiting case of the excited-state intramolecular proton transfer system. 相似文献
190.
Shimanovich U Cavaco-Paulo A Nitzan Y Gedanken A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(1):365-369
A novel antibacterial coating for cotton and polyester fabrics has been developed by using drug-loaded proteinaceous microspheres made of bovine serum albumin and casein proteins. The microbubbles were created and anchored onto the fabrics (see figure) in a one-step reaction that lasts 3 min. The sonochemically produced "antibacterial fabrics" have been characterized. The efficiency of the sonochemical process in converting the native proteins into microspheres, encapsulating the drug, and coating the fabric has also been studied. 相似文献