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961.
962.
Gas-phase cigarette smoke (GPCS) was able to induce lipid peroxidation in lecithin liposomes, rat liver microsomes, and rat lung cells (RLC), and change the membrane fluidity of RLCs. Lipid free radicals were trapped in a GPCS-treated microsomal suspension by using 4-POBN as the spin trap. In addition, it was found that GPCS-peroxidized liposomes in appropriate degree of lipid peroxidation had the ability to increase the generation of superoxide anions in rat peritoneal neutrophils (RPN). Effects of green tea polyphenols (GTP) on the GPCS-induced damages were investigated The results showed that GTP was capable of inhibiting the GPCS-induced damages. 相似文献
963.
The breakup of suspended, agglomerated submicron particles was studied by exposing the aerosol to weak shock waves of varying strength under conditions 400 ms?1?v?880 ms?1. A newly developed laser light-scattering diagnostic employing a top hat laser profile was used to size the particles passing through a very small scattering volume. By Comparing the optically measured particle size in front of and behind shock waves, the breakup of agglomerated particles could be clearly identified. The experiments indicate that the aerodynamic forces behind an incident shock overcome the particle binding force resulting in disintegration of the submicron agglomerates. The results are presented in form of a modified Weber number. 相似文献
964.
Jürgen Kurths M. Carmen Romano Marco Thiel Grigory V. Osipov Mikhail V. Ivanchenko István Z. Kiss John L. Hudson 《Nonlinear dynamics》2006,44(1-4):135-149
We present two different approaches to detect and quantify phase synchronization in the case of coupled non-phase coherent
oscillators. The first one is based on the general idea of curvature of an arbitrary curve. The second one is based on recurrences
of the trajectory in phase space. We illustrate both methods in the paradigmatic example of the R?ssler system in the funnel
regime. We show that the second method is applicable even in the case of noisy data. Furthermore, we extend the second approach
to the application of chains of coupled systems, which allows us to detect easily clusters of synchronized oscillators. In
order to illustrate the applicability of this approach, we show the results of the algorithm applied to experimental data
from a population of 64 electrochemical oscillators. 相似文献
965.
E. M. Glebov V. P. Grivin V. F. Plyusnin A. V. Udaltsov 《Journal of Structural Chemistry》2006,47(3):476-483
Interaction between MnCl2 and diethylamine (DEA) in aqueous solutions has been studied by UV, IR, and EPR spectroscopy as part of the design and research program on models of natural photosystems. The composition of the precipitate for comparable concentrations of reagents and solute oxygen has been investigated. Mn(II) was found to be oxidized with oxygen to give MnO2·H2O as a precipitate. In the solution over the precipitate, Mn(III) complexes with DEA are formed; the complex molecule has four and six amine molecules in the coordination sphere. 相似文献
966.
967.
V. F. Tret’yakov A. G. Zakirova V. A. Matyshak T. N. Burdeinaya V. N. Korchak L. S. Glebov V. V. Lunin 《Kinetics and Catalysis》2006,47(6):873-880
According to X-ray diffraction analysis data, the test catalyst was a Ni-Cr spinel with an impurity of NiO. With the use of in situ IR spectroscopy, it was found that nitrite, nitrate, and acetate surface complexes occurred under the reaction conditions of the selective catalytic reduction of nitrogen oxides by propane in the presence of oxygen on the nickel-chromium catalyst. As the temperature was increased, the nitrite complexes were converted into nitrate species. The molar absorption coefficient of surface nitrate complexes was determined. According to IR-spectroscopic and TPD data, the nitrate complexes were bound relatively weakly to the surface. The temperature region of their existence was 50–200°C. The temperature region of existence of the surface acetate complexes was 200–400°C. The individual adsorption of oxygen was not observed; however, oxygen-containing surface sites (Cr5+=O) participated in the formation of the surface complexes of reactants. 相似文献
968.
Marko D. Mihovilovic Bernhard Müller Markus Spina Arjumand I. Durrani Peter Stanetty Georg Dazinger Karl Kirchner 《Monatshefte für Chemie / Chemical Monthly》2006,137(6):785-794
Summary. Recombinant Escherichia coli overexpressing Pseudomonas sp. NCIMB 9872 cyclopentanone monooxygenase (CPMO, EC 1.14.13.16) and Acinetobacter sp. NCIMB 9871 cyclohexanone monooxygenase (CHMO, EC 1.14.13.22) have been utilized in whole-cell Baeyer-Villiger biotransformations of prochiral bicycloketones. A significant difference in substrate acceptance and stereoselectivity was
observed for bicyclo[3.3.0] and bicyclo[4.3.0] substrates. A plausible mechanism of these transformations was established
by means of high level DFT/B3LYP calculations suggesting an essential difference in electronic requirements for a successful
enzymatic conversion, which was similarly encountered in recombinant whole-cell mediated biooxidations. Some of the lactones
produced in the biocatalytic Baeyer-Villiger oxidation represent key intermediates for the synthesis of indole alkaloids. 相似文献
969.
970.