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排序方式: 共有188条查询结果,搜索用时 31 毫秒
151.
Arkadiusz Matwijczuk Iwona Budziak-Wieczorek Grzegorz Czernel Dariusz Karcz Alicja Baraska Aleksandra Jedliska Katarzyna Samborska 《Molecules (Basel, Switzerland)》2022,27(12)
Fourier transform infrared spectroscopy (FTIR) in connection with chemometric analysis were used as a fast and direct approach to classify spray dried honey powder compositions in terms of honey content, the type of diluent (water or skim milk), and carrier (maltodextrin or skim milk powder) used for the preparation of feed solutions before spray drying. Eleven variants of honey powders containing different amounts of honey, the type of carrier, and the diluent were investigated and compared to pure honey and carrier materials. Chemometric discrimination of samples was achieved by principal component analysis (PCA), hierarchical clustering analysis (HCA), linear discriminant analysis (LDA), and partial least squares-discriminant analysis (PLS-DA) modelling procedures performed on the FTIR preprocessed spectral data for the fingerprint region (1800–750 cm−1) and the extended region (3600–750 cm−1). As a result, it was noticed that the type of carrier is a significant factor during the classification of different samples of powdered multifloral honey. PCA divided the samples based on the type of carrier, and additionally among maltodextrin-honey powders it was possible to distinguish the type of diluent. The result obtained by PCA-LDA and PLS-DA scores yielded a clear separation between four classes of samples and showed a very good discrimination between the different honey powder with a 100.0% correct overall classification rate of the samples. 相似文献
152.
Arkadiusz Mandowski 《Macromolecular Symposia》2004,212(1):257-262
A new analytical model is proposed to describe the kinetics of trapping and recombination of charge carriers in complex systems with an arbitrary spatial distribution of traps and recombination centres. The structural properties of a material are described by two functions Γm and Γn irrespective of the thermal history of the sample. A simple method is proposed to determine the function Γm from simultaneous thermoluminescence (TL) and thermally stimulated conductivity (TSC) measurements. 相似文献
153.
Marek K. Wcawski Irena Deperasiska Marzena Banasiewicz David C. Young Arkadiusz Leniak Daniel T. Gryko 《化学:亚洲杂志》2019,14(10):1763-1770
The double Knoevenagel condensation of 1,4‐dibenzoyloxyanthraquinone with methyl esters of arylacetic acids affords a series of compounds based upon a previously unknown 1,8‐dioxa‐benzo[e]pyrene‐2,7‐dione heterocyclic core. The aryl groups incorporated in the 3‐ and 6‐positions can be oxidatively coupled to the π‐expanded backbone to produce a further new heterocyclic core: 1,10‐dioxa‐dibenzo[dj]coronene‐2,9‐dione. The intriguing optical properties of these π‐expanded coumarin derivatives are discussed and rationalized through quantum chemical calculations. The broad absorption bands of 1,8‐dioxa‐benzo[e]pyrene‐2,7‐dione‐based dyes are attributed to both HOMO?1→LUMO and HOMO→LUMO transitions, which have a similar energy. Weakly coupled electron‐donating aryl substituents result in a moderate bathochromic shift of both the absorption and emission by 30–60 nm in toluene. The emissive properties of these compounds are in part determined by the oscillator strength of the main transition, lifetimes of the excited state, and by the energy match of the excited state with a triplet state of a similar energy. The 1,10‐dioxa‐dibenzo[dj]coronene‐2,9‐dione displays a much smaller Stokes shift, yet a markedly increased fluorescence quantum yield of 90 % owing to the increased rigidity compared with the 1,8‐dioxa‐benzo[e]pyrene‐2,7‐dione core. 相似文献
154.
Ewa esawska Robert Zakrzewski Arkadiusz Nowicki Izabela Korona-Gowniak Antonín Ly
ka Agnieszka Kania Krzysztof Kazimierz Zborowski Piotr Suder Agnieszka Skrska-Stania Waldemar Tejchman 《Molecules (Basel, Switzerland)》2022,27(13)
The constant increase in the resistance of pathogenic bacteria to the commonly used drugs so far makes it necessary to search for new substances with antibacterial activity. Taking up this challenge, we obtained a series of rhodanine-3-carboxyalkyl acid derivatives containing 2- or 3- or 4-pyridinyl moiety at the C-5 position. These compounds were tested for their antibacterial and antifungal activities. They showed activity against Gram-positive bacteria while they were inactive against Gram-negative bacteria and yeast. In order to explain the relationship between the activity of the compounds and their structure, for selected derivatives crystal structures were determined using the X-ray diffraction method. Modeling of the isosurface of electron density was also performed. For all tested compounds their lipophilicity was determined by the RP-TLC method and by calculation methods. On the basis of the carried-out research, it was found that the derivatives with 1.5 N···S electrostatics interactions between the nitrogen atom in the pyridine moiety and the sulfur atom in the rhodanine system showed the highest biological activity. 相似文献
155.
Szeleszczuk Łukasz Gubica Tomasz Szmeja Sebastian Ciesielski Arkadiusz Cyrański Michał K. Pisklak Dariusz M. 《Structural chemistry》2021,32(1):297-307
Structural Chemistry - A reliable method for molecular structure determination, excluding single-crystal X-ray diffraction (SCXRD), has been applied to six methyl glycoside tetrabenzoates. The... 相似文献
156.
Ewa Mandowska Wojciech Mazela Piotr Czub Arkadiusz Mandowski Jan Pielichowski Józef Świątek 《Macromolecular Symposia》2004,212(1):269-274
Luminescence properties of a new material - epoxy resin with added 9-(2,3-epoxypropyl)carbazole (REPK) were studied. Absorption and photoluminescence (PL) spectra of REPK are compared with those of poly(N-vinylcarbazole) (PVK). PL in REPK is shifted to shorter wavelengths. Its intensity is higher than in PVK. REPK emits light in the range from 330 nm to 470 nm. PL spectrum of REPK could be well deconvoluted for four emission bands. 相似文献
157.
Arkadiusz P. Trawiński 《Few-Body Systems》2016,57(6):449-453
An approximate light-cone wave function for the pion effective quark-antiquark Fock sector corresponding to a small value of the renormalization group parameter is presented. The approximate wave function is motivated by the LF-holography and the quadratic confinement potential in the front form of Hamiltonian dynamics, which is in harmony with the linear confining potential in the instant form. The pion radius, decay constant and form-factor are also presented. 相似文献
158.
Arkadiusz Matwijczuk Andrzej Górecki Marcin Makowski Katarzyna Pustuła Alicja Skrzypek Joanna Waś Andrzej Niewiadomy Mariusz Gagoś 《Journal of fluorescence》2018,28(1):65-77
The article presents the results of fluorescence analyses of 2-methylamino-5-(2,4-dihydroxyphenyl)-1,3,4-thiadiazole (MDFT) in an aqueous environment. MDFT dissolved in aqueous solutions with a pH value in the range from 1 to 4.5 yielded an interesting effect of two clearly separated fluorescence emissions. In turn, a single fluorescence was observed in MDFT dissolved in water solutions with a pH value from 4.5 to 12. As it was suggested in the previous investigations of other 1,3,4-thiadiazole compounds, these effects may be associated with conformational changes in the structure of the analysed molecule accompanied by aggregation effects. Crystallographic data showed that the effect of the two separated fluorescence emissions occurred in a conformation with the –OH group in the resorcyl ring bound on the side of the sulphur atom from the 1,3,4-thiadiazole ring. The hypothesis of aggregation as the mechanism involved in the change in the spectral properties at low pH is supported by the results of (Time-Dependent) Density Functional Theory calculations. The possibility of rapid analysis of conformational changes with the fluorescence spectroscopy technique may be rather important outcome obtained from the spectroscopic studies presented in this article. Additionally, the presented results seem to be highly important as they can be easily observed in solutions and biologically important samples. 相似文献
159.
Syta Arkadiusz Bernardini Davide Litak Grzegorz Savi Marcelo A. Jonak Kamil 《Meccanica》2020,55(6):1295-1308
Meccanica - It is well known that dynamical systems that include devices based on shape memory alloys (SMA) can exhibit a wide spectrum of responses: periodic, quasi-periodic and chaotic motions.... 相似文献
160.
Barbara Bobrowska-Korczak Agnieszka Stawarska Arkadiusz Szterk Karol Ofiara Magorzata Czerwonka Joanna Giebutowicz 《Molecules (Basel, Switzerland)》2021,26(5)
The present study aimed to assess the levels of 98 multi-class pharmaceuticals including cardiovascular drugs, antidepressants, hypnotics, antibiotics, and sulfonamides occurring in the muscle tissue of fish caught in the Baltic Sea. The following fish species were collected: perch (Perca fluviatilis); flounder (Platichthys flesus); turbot (Scophthalmus maximus); plaice (Pleuronectes platessa); cod (Gadus morhua callarias); bream (Abramis brama); crucian (Carassius carassius). Additionally, in the examined fish muscle the levels of heavy metals and trace elements were determined (As; Ag; Au; Ba; Cd; Co; Cr; Cu; Hg; Li; Mo; Ni; Pb; Sb; Se; Sn; Tl; V) as well as the levels of cholesterol and its 5 derivatives (7-ketocholesterol; 7α-hydroxycholesterol; 7β-hydroxycholesterol; 5β,6β-epoxy-cholesterol; 5α,6α-epoxycholesterol). In the performed studies 11 out of 98 examined pharmaceuticals were detected in fish muscle. The levels of pharmaceuticals in fish muscle varied depending on the species. In the tissues of bream and crucian, no pharmaceuticals were found. Mercury, lead and arsenic were detected in the muscles of all examined fish. Based on the hazard factor for Hg, Pb, Cd, Ni (target hazard quotient, THQ < 1), it was found that the consumption of the studied fish does not constitute a health risk. However, the THQ for As remained >1 indicated possible risk from those metals. In the examined fish muscle the total cholesterol oxidation products (COPs) level of oxysterols were, respectively: 6.90 (cod) μg/g–4.18 μg/g (perch), which corresponded to 0.7–1.5% of cholesterol. The main COPs evaluated were 7-ketocholesterol (0.78 ± 0.14–1.79 ± 0.06 μg/g), 7β-hydroxycholesterol (0.50 ± 0.04–3.20 ± 2.95 μg/g) and 5β,6β-epoxycholesterol (0.66 ± 0.03–1.53 ± 0.66 μg/g). The assessment of health hazards due to contaminations is necessary, which may help to introduce national legislation and global standards aimed at reducing or even eliminating the exposure to contaminants. 相似文献