Host–Guest Chemistry Within Cellulose Nanocrystal Gel Receptors

Cellulose nanocrystals (CNCs) spontaneously assemble into gels when mixed with a polyionic organic or inorganic salt. Here, we have used this ion-induced gelation strategy to create functional CNC gels with a rigid tetracationic macrocycle, cyclobis(paraquat-p-phenylene) ( CBPQT ⁴⁺). Addition of [ CBPQT ]Cl₄ to CNCs causes gelation and embeds an active host inside the material. The fabricated CNC gels can reversibly absorb guest molecules from solution then undergo molecular recognition processes that create colorful host–guest complexes. These materials have been implemented in gel chromatography (for guest exchange and separation), and as elements to encode 2- and 3-dimensional patterns. We anticipate that this concept might be extended to design a set of responsive and selective gel-like materials functioning as, for instance, water-pollutant scavengers, substrates for chiral separations, or molecular flasks.     

Statistics of branched flow in a weak correlated random potential

Recent images of electron flow through a two-dimensional electron gas device show branching behavior that is reproduced in numerical simulations of motion in a correlated random potential [M. A. Topinka, Nature 410, 183 (2001)]]. We show how such branching arises from caustics in the classical flow and find a simple scaling behavior of the branching under variation of the random potential strength. Analytic results describing statistical properties of the branching are confirmed by classical and quantum numerical tests.     

A Bohr Phenomenon For Elliptic Equations

In 1914 Bohr proved that there is an r (0,1) such that if apower series converges in the unit disk and its sum has modulusless than 1 then, for |z| < r, the sum of absolute valuesof its terms is again less than 1. Recently, analogous resultshave been obtained for functions of several variables. The aimof this paper is to place the theorem of Bohr in the contextof solutions to second-order elliptic equations satisfying themaximum principle. 2000 Mathematics Subject Classification: 35J15, 32A05, 46A35.     

Percolation Thresholds in Ternary Polymer Melt Blends with Separate Dispersions of the Inner Phases: Mathematical Model

A mathematical model based on a straightforward geometrical background is developed which enables predictions of a transition of one dispersed phase to a cocontinuous one (i.e., the percolation threshold) on addition of another dispersed phase during melt mixing in ternary polymer blends. The present work concerns only ternary blends with two separate dispersions of the inner phases in which no encapsulation takes place. In addition, in order to simplify the model, one of the inner phases was represented by hard, nondeformable microspheres The expression developed describes well an experimental relationship between the percolation threshold, the concentration above which the former dispersed phase transforms to a continuous one, and concentrations of both inner phases. The results agree well with the experimental data obtained in a previous work.     

Revenue in contests with many participants

We show that in a contest with a single prize, the expected effort made by the k$k$th highest valuation participant bounds the sum of the expected efforts made by all of the participants with valuations less than the k$k$th highest valuations. We also show that in the limit case of a contest with m$m$ prizes, the expected effort made by the k$k$th highest valuation participant when the bidders are risk-neutral is greater than the expected effort in the risk-averse case.     

The Reality in Bohmian Quantum Mechanics or Can You Kill with an Empty Wave Bullet?

Several situations, in which an empty wave causes an observable effect, are reviewed. They include an experiment showing surrealistic trajectories proposed by Englert et al. and protective measurement of the density of the quantum state. Conditions for observable effects due to empty waves are derived. The possibility (in spite of the existence of these examples) of minimalistic interpretation of Bohmian quantum mechanics in which only Bohmian positions supervene on our experience is discussed.     

Information and Distinguishability of Ensembles of Identical Quantum States

We consider a fixed quantum measurement performed over n identical copies of quantum states. Using a rigorous notion of distinguishability based on Shannon’s 12th theorem, we show that in the case of a single qubit, the number of distinguishable states is , where (α₁,α₂) is the angle interval from which the states are chosen. In the general case of an N-dimensional Hilbert space and an area Ω of the domain on the unit sphere from which the states are chosen, the number of distinguishable states is . The optimal distribution is uniform over the domain in Cartesian coordinates.     

Optimal corrective maintenance contract planning for aging multi‐state system

This paper considers an aging multi‐state system, where the system failure rate varies with time. After any failure, maintenance is performed by an external repair team. Repair rate and cost of each repair are determined by a corresponding corrective maintenance contract with a repair team. The service market can provide different kinds of maintenance contracts to the system owner, which also can be changed after each specified time period. The owner of the system would like to determine a series of repair contracts during the system life cycle in order to minimize the total expected cost while satisfying the system availability. Operating cost, repair cost and penalty cost for system failures should be taken into account. The paper proposes a method for determining such optimal series of maintenance contracts. The method is based on the piecewise constant approximation for an increasing failure rate function in order to assess lower and upper bounds of the total expected cost and system availability by using Markov models. The genetic algorithm is used as the optimization technique. Numerical example is presented to illustrate the approach. Copyright © 2009 John Wiley & Sons, Ltd.