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21.
This work deals with the modelling and simulation of a degassing process mainly used for extruders in polymer industry. The numerical simulations are done with finite-volume method using OpenFOAM for a 2D single screw extruder. The material parameters have been all chosen for a PDMS-Pentane polymer mixture so that the results could be compared with the available experiments already performed for this mixture [1]. In addition to experiments, the numerical results will be compared with an analytical solution derived from Danckwerts' model [2][3]. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
22.
Alimi Z. Hatamjafari F. Shiroudi A. Pourshamsian K. Oliaey A. R. 《Russian Journal of Organic Chemistry》2021,57(4):631-637
Russian Journal of Organic Chemistry - A series of novel 2-(5-aryl-4H-1,2,4-triazol-3-yl)-1H-isoindole-1,3(2H)-diones were synthesized in three steps. In the first step, treatment of substituted... 相似文献
23.
Imen Aribi Sahbi Ayachi Kamel Alimi Sadok Roudesli Ayoub Haj Said 《Research on Chemical Intermediates》2017,43(1):73-89
The anodic oxidation of the 4,4′-dimethoxychalcone (DMC) was investigated by different electrochemical methods at a platinum working electrode and in acetonitrile as a solvent. The DMC exhibited a single irreversible anodic peak around 1.6 V versus Ag/AgCl. On the time scale of cyclic voltammetry experiments, the highly reactive radical cation issued from the first electron transfer underwent a second order rate-limiting reaction. The potential imposed electrolyses of DMC led to the formation of a semi-conducting oligomer with 40 % yield. Using different physico-chemicals methods, the structural study confirmed the formation of an o-phenylenevinylene oligomer. The values of the corresponding optical and electrochemical band gaps were calculated to be 3.15 and 2.86 eV, respectively. Finally, a mechanism for the DMC electro-oligomerization was proposed on the basis of the obtained results. 相似文献
24.
This study emphasizes that project scheduling and material ordering (time and quantity of an order) must be considered simultaneously to minimize the total cost, as setting the material ordering decisions after the project scheduling phase leads to non-optimal solutions. Hence, this paper mathematically formulates the model for the multi-mode resource-constrained project scheduling with material ordering (MRCPSMO) problem. In order to be more realistic, bonus and penalty policies are included for the project. The objective function of the model consists of four elements: the material holding cost, the material ordering cost, the bonus paid by the client and the cost of delay in the project completion. Since MRCPSMO is NP-hard, the paper proposes three hybrid meta-heuristic algorithms called PSO-GA, GA-GA and SA-GA to obtain near-optimal solutions. In addition, the design of experiments and Taguchi method is used to tune the algorithms’ parameters. The proposed algorithms consist of two components: an outside search, in which the algorithm searches for the best schedule and mode assignment, and the inside search, which determines the time and quantity of orders of the nonrenewable resources. First, a comparison is made for each individual component with the exact or best solutions available in the literature. Then, a set of standard PROGEN test problems is solved by the proposed hybrid algorithms under fixed CPU time. The results reveal that the PSO-GA algorithm outperforms both GA-GA and SA-GA algorithms and provides good solutions in a reasonable time. 相似文献
25.
26.
M Alimi A Allam M Selkti A Tomas P Roussel E Galardon I Artaud 《Inorganic chemistry》2012,51(17):9350-9356
Six Co(III) complexes based on unsubstituted or substituted TPA ligands (where TPA is tris(2-pyridylmethyl)amine) and acetohydroxamic acid (A), N-methyl-acetohydroxamic acid (B), or N-hydroxy-pyridinone (C) were prepared and characterized by mass spectrometry, elemental analysis, and electrochemistry: [Co(III)(TPA)(A-2H)](Cl) (1a), [Co(III)((4-Cl(2))TPA)(A-2H)](Cl) (2a), [Co(III)((6-Piva)TPA)(A-2H)](Cl) (3a), [Co(III)((4-Piva)TPA)(A-2H)](Cl) (4a) and [Co(III)(TPA)(B-H)](Cl)(2) (1b), and [Co(III)(TPA)(C-H)](Cl)(2) (1c). Complexes 1a-c and 3a were analyzed by (1)H NMR, using 2D ((1)H, (1)H) COSY and 2D ((1)H, (13)C) HMBC and HSQC, and shown to exist as a mixture of two geometric isomers based on whether the hydroxamic oxygen was trans to a pyridine nitrogen or to the tertiary amine nitrogen. Complex 3a exists as a single isomer that was crystallized. Its crystal structure revealed the presence of an H-bond between the pivaloylamide and the hydroximate oxygen. Complexes 1a, 2a, and 4a are irreversibly reduced beyond -900 mV versus SCE, while complexes 1b and 1c are reduced at less negative values of -330 and -190 mV, respectively. The H-bond in 3a increased the redox potential up to -720 mV. Reaction of complex 1a with l-cysteine methyl ester CysOMe was monitored by (1)H NMR and UV-vis at 2 mM and 0.2 mM in an aqueous buffered solution at pH 7.5. Complex 1a was successively converted into an intermediate [Co(III)(TPA)(CysOMe-H)](2+), 1d, by exchange of the hydroximate with the cysteinate ligand, and further into Co(III)(CysOMe-H)(3), 5. An authentic sample of 1d was prepared and thoroughly characterized. A detailed (1)H NMR analysis showed there was only one isomer, in which the thiolate was trans to the tertiary amine nitrogen. 相似文献
27.
Stabilizing unstable periodic orbits of a deterministic chaotic system which is perturbed by a stochastic process is studied in this paper. The stochastic chaos is modeled by exciting a deterministic chaotic system with a white noise obtained from derivative of a Wiener process which eventually generates an Ito differential equation. It is also assumed that the chaotic system being studied has some model uncertainties which are not random. The sliding mode controller with some modifications is used for stochastic chaos suppression. It is shown that the system states converge to the desired orbit in such a way that the error covariance converges to an arbitrarily small bound around zero. As some case studies, the stabilization of 1-cycle and 2-cycle orbits of chaotic Duffing and Φ6 Van der Pol systems is investigated by applying the proposed method to their corresponding stochastically perturbed systems. Simulation results show the effectiveness of the method and the accuracy of the statements proved in the paper. 相似文献
28.
Usacheva Tatiana Kabirov Dzhovidon Beregova Diana Gamov George Sharnin Valentin Biondi Marco Mayol Laura D’Aria Federica Giancola Concetta 《Journal of Thermal Analysis and Calorimetry》2019,138(1):417-424
Journal of Thermal Analysis and Calorimetry - Quercetin (QCT) is a flavonoid possessing many activities, such as neuro-/cardioprotective, anti-inflammatory and anticancer, but its pharmacological... 相似文献
29.
Michael Aalinejad Nader Noroozi Pesyan Nosrat Heidari Hana Batmani Aria Danandeh Asl 《应用有机金属化学》2019,33(6)
Ni@diaza crown ether complex supported on magnetic nanoparticle was provided by grafting technique. The catalytic activity of Fe3O4@diaza crown ether@Ni was explored through one‐pot synthesis of 2,3‐dihydroquinazolin‐4(1H)‐ones and it was used as an efficient and recoverably constant nanocatalyst. FT‐IR, SEM, TEM, XRD, BET, ICP, EDS, and TGA techniques were employed to specify the nanocatalyst. This heterogeneous catalyst demonstrated acceptable recyclability and could be used again several times with no considerable loss of its catalytic activity. 相似文献
30.