Innovation in the cluster validating techniques

To detect database records containing approximate and exact duplicates because of data entry error or differences in the detailed schemas of records from multiple databases or for some other reasons is an important line of research. Yet no comprehensive comparative study has been performed to evaluate the effectiveness of Silhouette width, Calinski & Harbasz index (pseudo F-statistics) and Baker & Hubert index (γ index) algorithms for exact and approximate duplicates. In this paper, a comparative study and effectiveness of these three cluster validation techniques which involve measuring the stability of a partition in a data set in the presence of noise, in particular, approximate and exact duplicates are presented. Silhouette width, Calinski & Harbasz index and Baker & Hubert index are calculated before and after inserting the exact and approximate duplicates (deliberately) in the data set. Comprehensive experiments on glass, wine, iris and ruspini database confirms that the Baker & Hubert index is not stable in the presence of approximate duplicates. Moreover, Silhouette width, Calinski and Harbasz index and Baker & Hubert indice do not exceed the original data indice in the presence of approximate duplicates.     

β-Functionalized ethylchalcogenolate complexes of lead(II): Synthesis, structures and their conversion into lead chalcogenide nanoparticles

The reactions of Pb(OAc)₂·3H₂O with NaER yield homoleptic colorless to yellow complexes of composition, [Pb(ER)₂] (ER = SCH₂CH₂NMe₂ (1), SeCH₂CH₂NMe₂ (2) and SeCH₂CH₂COOMe (3)). These complexes were characterized by elemental analyses, UV–Vis and ¹H NMR data. Molecular structures of [Pb(ECH₂CH₂NMe₂)₂] (E = S or Se) have been established by single crystal X-ray diffraction analyses. These molecules have a distorted trigonal bipyramidal configuration around lead with the nitrogen atoms of the chelating chalcogenolate ligands occupying the axial positions. Thermal behavior of these complexes was studied by TG analysis. Pyrolysis in a furnace or in HDA (hexadecylamine) gave PbE nanoparticles which were characterized by UV–Vis, photoluminescence, XRD, EDAX, and TEM measurements.     

Structural and magnetic properties of the layered compound Ca2.375La0.125Sr0.5GaMn2O8

The brownmillerite-type layered compound Ca_2.375La_0.125Sr_0.5GaMn₂O₈ has been synthesized. The crystal and magnetic structures have been refined by the Rietveld analysis of the neutron powder diffraction patterns at 300 and 20 K. This compound crystallizes in the orthorhombic symmetry under the space group Pcm2₁ (a = 5.447(2), b = 11.359(4) and c = 5.322(2) Å). The compound is found to be antiferromagnetic at 20 K. The ordered Mn magnetic moment, aligned along the crystallographic b-direction, is derived to be 2.53(5) µ_B per Mn ion at 20 K.     

Machinability improvement in Inconel-718 by enhanced tribological and thermal environment using textured tool

Journal of Thermal Analysis and Calorimetry - Machinability of Inconel-718 superalloy in conventional approach is poor—this fact necessitates advanced technological adoption such as improved...     

Crystallinity,relaxational transitions,and free volume in high-density polyethylene

Most of the procedures employed so far in the literature for obtaining the amorphous volume of a polymer below its melting point have been based upon some kind of ad hoc assumptions. In this paper the principle of corresponding states, whose validity has been established for a number of polymers, is applied for obtaining the amorphous volume of polyethylene in the experimentally inaccessible region. The degree of crystallinity as a function of temperature is then calculated in a typical case using the actual sample volume data of Quinn and Mandelkern and the ideal crystal volume values obtained from X-ray measurements. Our results indicate the onset of a prominent relaxational transition at T₁ = 152°K. A careful analysis of the volume-temperature relationship indicates a much weaker transition at T₂ = 233°K. By making use of the isoprene volume concept, it is shown that the Simha-Boyer relation is valid in a more general form.     

Development of Raman-shifted probe laser beam for plasma diagnosis using polaro-interferometer

Optical diagnostics of laser-produced plasma requires a coherent, polarized probe beam synchronized with the pump beam. The probe beam should have energy above the background emission of plasma. Though the second harmonic probe beam satisfies most of the requirements, the plasma emission is larger at the harmonic frequencies of the pump. Hence, at high intensities we need a probe beam at non-harmonic frequencies. We have set up a Raman frequency shifted probe beam using a pressurized hydrogen cell that is pumped by the second harmonic of the Nd glass laser that operates at only one Stokes line of 673.75 nm.     

Direct Synthesis of Yttrium Aluminum Garnet Particles in an Inductively Coupled Radio-Frequency Plasma System

Advanced phosphor materials such as cerium-doped yttrium aluminum garnet (YAG) are of interest for a variety of applications, including light-emitting diodes. Previous studies have shown that it is difficult to produce the desired YAG phase without ex-situ annealing irrespective of the synthesis technique used. This study focuses on direct synthesis of YAG phosphor particles using an inductively coupled thermal plasma system with a ceramic tube inserted coaxially into the chamber. Numerical modeling indicates that the tube provides a more uniform high-temperature region, without flow recirculation. This is hypothesized to aid in size and phase control through selective particle collection and in-flight annealing. Experiments conducted with the tube-insertion setup indicate that phase and size control of the particles is possible to a certain extent, depending on the size of the tube. Characterization results of the synthesized particles showed that submicron-sized YAG particles are synthesized as the majority phase through the tube-insertion setup.     

Fluorescence quenching studies of conjugated polymer poly[2-methoxy-5-(3′,7′-dimethyloctyloxy)-1,4-phenylenevinylene in the presence of TNT

We report fluorescence quenching of the conjugated polymer poly[2-methoxy-5-(3′,7′-dimethyloctyloxy)-1,4-phenylenevinylene (MDMO-PPV) in the presence of nitrated explosives, such as, 2,4,6-trinitrotoluene (TNT). It is found that the conjugated polymer changes color from orange to brownish black when sprayed on traces of TNT within a few seconds. Fluorescence quenching of the conjugated polymer in the presence of TNT is also studied by absorption and emission spectroscopy. The conjugated polymer is highly selective for sensing TNT in daylight and ambient conditions.