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101.
Apostolos Avgeropoulos Sofia Rangou Vahik Krikorian Edwin L. Thomas 《Macromolecular Symposia》2008,267(1):16-20
Synthesis of 2nd generation dendritic polymeric materials via anionic polymerization procedures in combination with chlorosilane chemistry, consisting either from one polydienic segment (homopolymers) or from two chemically different polydienic components (copolymers), is described. The polydienes used were poly(butadiene) (PB) with ∼90% 1,4-isomerism and poly(isoprene) (PI) with increased 3,4-isomerism (∼60%). Molecular characterization of intermediate products and the final dendritic materials was made with Gel Permeation Chromatography (GPC), Membrane and Vapour Pressure Osmometry (MO and VPO respectively), Gas Chromatography –Mass Spectroscopy (GC-MS) and 1H-Nuclear Magnetic Resonance (1H-NMR) Spectroscopy, leading to the conclusion that they can be considered model polymers. Morphological studies solely with Transmission Electron Microscopy (TEM) have been conducted on two of the four synthesized copolymer samples exhibiting microphase separation between the two polydiene segments. 相似文献
102.
103.
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献
104.
Using the Navier-Stokes equations in conjunction with the k-? model of turbulence, the characteristics of flow in the region downstream of a conical diffuser with 5° angle of inclination are calculated. Two representative stations 1D2 and 10D2 after the diffuser exit are selected for comparison against experimental results. The calculations indicate an underestimation of mean velocity and turbulence kinetic energy at the first station, while satisfactory agreement is obtained for the mean velocity at the second station. The use of a modified k-? model sensitive to adverse pressure conditions improves the predictions considerably. The effect of inlet properties and Reynolds number on the flow characteristics at the above stations is studied using various inlet profiles and a range of Reynolds numbers based on the inlet diameter from 50 000 to 280 000. 相似文献
105.
106.
The ground state of the linear BNB molecule has been examined with multireference-based ab initio methods coupled with quantitative basis sets. Previous computational studies on BNB, even those using highly correlated single reference-based methods, e.g., the CCSD(T) and BDT methods, suggested that the two BN bond lengths were unequal. In this paper, the BN(X 3Pi) + B(2Pu) potential energy curve is constructed using a state-averaged multireference-based correlated method (SA-CASSCF+PT2). The four lowest states of BN were included in the state averaging procedure. These calculations reveal no symmetry breaking along the antisymmetric stretching mode of the molecule. 相似文献
107.
Apostolos Gerasoulis 《BIT Numerical Mathematics》1981,21(3):377-380
It is shown that the direct Gauss-Chebyshev method used for the numerical solution of singular integral equations of Cauchy-type possesses a unique solution for sufficiently largen. 相似文献
108.
Apostolos Hadjidimos Theodore S. Papatheodorou Yiannis G. Saridikis 《Linear algebra and its applications》1983
The problem of determining fast iterative solutions of certain large, sparse, and nonsymmetric linear systems, arising in applications, is addressed here. Several iterative schemes, from the accelerated overrelaxation family, are considered. Different geometrical algorithms are used for the explicit determination of the optimal factors. Direct comparisons of the spectral radii of the resulting optimal schemes reveal that the optimal extrapolated accelerated Gauss-Seidel (EAGS) is always asymptotically faster than the optimal successive overrelaxation, while the optimal EAGS and extrapolated Gauss-Seidel strongly compete. Application of the collocation method on simple boundary-value problems is used to demonstrate our results numerically. 相似文献
109.
Konstantinos Adamopoulos Dimitrios Koutsouris Apostolos Zaravinos George I. Lambrou 《Molecules (Basel, Switzerland)》2021,26(9)
Gravity constituted the only constant environmental parameter, during the evolutionary period of living matter on Earth. However, whether gravity has affected the evolution of species, and its impact is still ongoing. The topic has not been investigated in depth, as this would require frequent and long-term experimentations in space or an environment of altered gravity. In addition, each organism should be studied throughout numerous generations to determine the profound biological changes in evolution. Here, we review the significant abnormalities presented in the cardiovascular, immune, vestibular and musculoskeletal systems, due to altered gravity conditions. We also review the impact that gravity played in the anatomy of snakes and amphibians, during their evolution. Overall, it appears that gravity does not only curve the space–time continuum but the biological continuum, as well. 相似文献
110.
Protons on water molecules are strongly affected by paramagnetic ions. Since the acid-base properties of water facilitate rapid proton exchange, a single proton nuclear magnetic resonance (NMR) signal is seen in aqueous solutions of paramagnetic ions. Proton relaxation times are significantly affected by paramagnetic species and the readily detectable single signal serves as a powerful amplifier of the information contained concerning the protons in the paramagnetic environment. Where water molecules coordinated to free paramagnetic ions and to metal complexes of ligands that form non-labile (on the NMR time scale) complexes, the effects on water in the two environments can be distinguished. This can provide information on the nature of the ligand binding sites. The example of Cu2+ bound to the Laurentian humic acid mixture reported here using convenient low field NMR relaxometers shows that the information can enrich our understanding of complexation and speciation in the presence of complex mixture ligands characteristic of natural water systems. In this case, the data underline the role of aggregation and conformation in defining the complexation sites. 相似文献