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171.
The process of formation of nanoparticles obtained by mixing two micellized, aqueous solutions has been simulated using the Monte Carlo technique. The model includes the phenomena of finite reaction, nucleation, and growth via intermicellar exchange. This exploratory study examines the characteristic particle size distributions (PSDs) that result from using combinations of different initial reactant distributions (Poissonian and geometric) and different types of intermicellar exchange protocols (random, cooperative, and binomial). It is observed that the PSDs obtained using an initial Poissonian distribution of reactants and random exchange rules are similar to reported experimental results for CdS nanoparticles. The effect of exchange efficiency and reaction rate has also been studied. It is seen that a high exchange efficiency leads to relatively larger particle sizes. Also, a slow reaction rate has been shown to lead to the formation of larger nanoparticles. 相似文献
172.
Cho BK Jain A Mahajan S Ow H Gruner SM Wiesner U 《Journal of the American Chemical Society》2004,126(13):4070-4071
A novel extended amphiphilic dendrimer with linear poly(ethylene oxide) (PEO) attached to a PEO-like dendritic core as hydrophilic fraction and eight docosyl chain branches as hydrophobic fraction has been prepared for the use as structure-directing agent for silica-type materials. The extended dendrimer exhibits a hexagonal columnar liquid crystalline phase in the melt. Organically modified inorganic precursors and the extended dendrimer co-assemble into nanostructured hybrids. Hybrids with 0.44 weight fraction (fw) of aluminosilicate show a lamellar morphology, while hybrids with 0.21 fw exhibit a cylindrical structure. Nanostructures were characterized by a combination of small-angle X-ray scattering (SAXS), transmission electron microscopy (TEM), and atomic force microscopy (AFM). The results suggest that dendrimer-based amphiphiles may provide an exciting platform for the formation of multifunctional organic-inorganic nanostructured hybrid materials with unique structural characteristics. 相似文献
173.
The paper presents structural, electronic and optical properties of boron-group V hexagonal nanowires (h-NW) within the framework of density functional theory. The h-NW of boron-group V compounds with an analogous diameter of 12 Å have been designed in (1 1 1) plane. Stability analysis performed through formation energies reveal that, the stability of these structures decreases with increasing atomic number of the group V element. The band nature predicts that these nanowires are good electrical conductors. Optical behaviour of the nanowires has been analysed through absorption coefficient, reflectivity, refractive index, optical conductivity and electron energy loss spectrum (EELS), that are computed from the frequency-dependent complex dielectric function. The analysis reveals high reactivity of BP and BAs h-NWs to the incident light especially in the IR and visible ranges, and the optical transparency of BN h-NW in the visible and UV ranges. 相似文献
174.
Lyle N. Long Anurag Agarwal 《International Journal of Computational Fluid Dynamics》2013,27(6):493-502
This paper discusses parallel computing applied to computational aeroacoustics problems. Computer hardware, software and algorithms are also described. A short history of parallel computers is given, along with some discussion of future prospects. We have reviewed much of the literature, but this review is not exhaustive. Finite difference, finite volume, and finite element methods are briefly discussed. There is also a discussion of how aeroacoustic problems scale, and how that relates to computational requirements. 相似文献
175.
Many metastable complex fluids, when subjected to oscillatory shear flow of increasing strain amplitude at constant frequency, are known to show a characteristic nonlinear rheological response which consists of a monotonic decrease in the elastic modulus and a nonmonotonic change in the loss modulus. In particular, the loss modulus increases from its low strain value, crosses the elastic modulus, and then decreases with further increase in the strain amplitude. Miyazaki et al. (Europhys Lett 75:915–921, 2006) proposed a qualitative argument to explain the origin of the nonmonotonic nature of the loss modulus and suggested that in fact this response could be universal to all complex fluids if they are probed in a certain frequency window in which the fluid is dominantly elastic in the small strain limit. In this letter, we confirm their hypothesis by showing that a wide variety of complex fluids, irrespective of their thermodynamic state under quiescent conditions, indeed show the aforementioned characteristic nonlinear response. We also show that the maximum relative dissipation during yielding occurs when the imposed frequency resonates with the characteristic beta relaxation frequency of the fluid. 相似文献
176.
In a recent paper (Gupta and Markenscoff in C. R., Méc. 336:126?C131, 2008) we interpreted configurational forces as necessary and sufficient dissipative mechanisms such that the corresponding Euler-Lagrange equations are satisfied. We now extend this argument for a dynamic elastic medium, and show that the energy flux obtained from the dynamic J integral ensures that the equations of motion hold throughout the body. 相似文献
177.
Theory of electroosmotic flow,retention and separation efficiency in capillary electrochromatography
Rathore AS 《Electrophoresis》2002,23(22-23):3827-3846
This article reviews recent progress that has taken place in the past decade (1992-2002) in the areas of understanding of flow of ions, buffers, as well as neutral and charged sample components through open channels and porous media. Though, primarily dealing with open capillaries and packed columns that are often used in capillary electrochromatography (CEC), these fundamental concepts are applicable to the evolving area of separations on a microchip. 相似文献
178.
Anurag K. Singh 《Transactions of the American Mathematical Society》2003,355(3):1009-1024
We examine some recent work of Phillip Griffith on étale covers and fibered products from the point of view of tight closure theory. While it is known that cyclic covers of Gorenstein rings with rational singularities are Cohen-Macaulay, we show this is not true in general in the absence of the Gorenstein hypothesis. Specifically, we show that the canonical cover of a -Gorenstein ring with rational singularities need not be Cohen-Macaulay.
179.
180.
In this paper, we are concerned with an interval-valued programming problem. Sufficient optimality conditions are established under generalized convex functions for a feasible solution to be an efficient solution. Appropriate duality theorems for Mond-Weir and Wolfe type duals are discussed in order to relate the efficient solutions of primal and dual programs. 相似文献