惯性约束聚变装置中靶面光场特性的统计表征方法

在激光驱动的惯性约束聚变装置中,常采用多种束匀滑手段对焦斑的时空特性进行调控.光传输链路中涉及的光学元件众多、传输变换复杂,往往导致光传输模型复杂,且在运用衍射光学方法分析焦斑形态和特征时面临大量的数据处理和计算,致使出现计算量大、计算效率低等问题,亟需寻求快速而简便的新方法来描述焦斑的统计特征.本文利用光场特性的统计表征方法对靶面光场进行表征,采用圆型复数高斯随机变量直接描述靶面光场的统计特征,并基于典型焦斑评价参数对衍射光学方法和统计表征方法得到的远场焦斑进行了对比和分析.结果表明,采用衍射光学方法和统计表征方法获得的焦斑的瞬时特征基本一致,其时间积分的远场焦斑有所不同,但仍可进一步采用相关系数来表征其远场焦斑的时间变化特征.     

镧系离子(Eu3+,Tb3+)氧氟沙星配合物的合成和光谱表征

本文报道了镧系离子Eu3 + ,Tb3 + 同喹诺酮羧酸类衍生物氧氟沙星形成配合物的合成。用元素分析法和ICP确定了配合物的组成为Ln(oflo) 3 Cl3 ·8H2 O。红外光谱表明氧氟沙星配体羧基同中心离子发生螯合 ,并可能与邻位羰基形成六元环稳定结构。荧光光谱表明 ,Eu配合物具有很宽的激发谱带 (2 0 0～ 45 0nm) ,明显区别于其他羧酸类的稀土配合物 ;中心离子Eu3 + 发射谱位于 5 79 0nm(5D0 7F0 ) ,5 92 2nm(5D0 7F1) ,6 12 2nm(5D0 7F2 ) ;而Tb3 + 配合物则同时有配体和中心离子的荧光发射     

Efficient cross polarization with simultaneous adiabatic frequency sweep on the source and target channels

In this work, we propose a new and efficient heteronuclear cross polarization scheme, in which adiabatic frequency sweeps from far off-resonance toward on-resonance are applied simultaneously on both the source and target spins. This technique, which we call as Simultaneous ADIabatic Spin-locking Cross Polarization (SADIS CP), is capable of efficiently locking both the source and target spins with moderate power even in the presence of large spectral distribution and fast relaxation. It is shown that by keeping the time-dependent Hartmann-Hahn mismatch minimal throughout the mixing period, polarization transfer can be accelerated. Experiments are demonstrated in a powder sample of L-alanine.     

Pyrolysis study of poplar biomass by tunable synchrotron vacuum ultraviolet photoionization mass spectrometry

Pyrolysis is one of the most important methods to convert biomass into biofuel, which is a potential substitute for fossil fuel. The pyrolysis process of poplar biomass, a potential biofuel feedstock, has been studied with tunable synchrotron vacuum ultraviolet (SVUV) photoionization mass spectrometry (PIMS). The mass spectra at different photon energies, temperatures, and time-evolved profiles of selected species during poplar pyrolysis process were measured. Our results reveal that poplar is typical of hardwood according to its relative contents of three lignin monomeric precursors. As temperature increases from 300 to 700 °C, the overall intensities of pyrolysis products decrease due to the gas-phase cracking. Observed intensities of syringyl and guaiacyl subunits of lignin in poplar at low temperature present different trends: the intensities of syringyl subunits of lignin undergo an increase firstly and then a decrease, whereas those of guaiacyl subunits of lignin show decrease continuously. Time-dependent data demonstrate that hemicellulose pyrolysis is faster than lignin in poplar. This work reports a new application of SVUV PIMS in biomass pyrolysis, which performs very well in products analysis.     

精确Cosserat弹性杆动力学的分析力学方法

以脱氧核糖核酸和工程中的细长结构为背景, 大变形大范围运动的弹性杆动力学受到关注. 将分析力学方法运用到精确Cosserat弹性杆动力学, 旨在为前者拓展新的应用领域, 为后者提供新的研究方法. 基于平面截面假定, 在弯扭基础上再计及拉压和剪切变形形成精确Cosserat弹性杆模型. 用刚体运动的概念描述弹性杆的变形, 导出弹性杆变形和运动的几何关系; 在定义截面虚位移及其变分法则的基础上, 建立用矢量表达的d’Alembert-Lagrange原理, 在线性本构关系下化作分析力学形式, 并导出Lagrange方程和Nielsen方程, 定义正则变量后化作Hamilton正则方程; 对于只在端部受力的弹性杆静力学, 导出了将守恒量预先嵌入的Lagrange方程, 并讨论了其首次积分. 从弹性杆的d’Alembert-Lagrange原理导出积分变分原理, 在线性本构关系下化作Hamilton原理. 形成的分析力学方法使弹性杆的全部动力学方程具有统一的形式, 为弹性杆动力学的对称性和守恒量的研究及其数值计算铺平道路. 关键词： 精确Cosserat弹性杆 分析动力学方法 变分原理 Lagrange方程     

Topological nodal line semimetals predicted from first-principles calculations

Topological semimetals are newly discovered states of quantum matter, which have extended the concept of topological states from insulators to metals and attracted great research interest in recent years. In general, there are three kinds of topological semimetals, namely Dirac semimetals, Weyl semimetals, and nodal line semimetals. Nodal line semimetals can be considered as precursor states for other topological states. For example, starting from such nodal line states, the nodal line structure might evolve into Weyl points, convert into Dirac points, or become a topological insulator by introducing the spin–orbit coupling (SOC) or mass term. In this review paper, we introduce theoretical materials that show the nodal line semimetal state, including the all-carbon Mackay–Terrones crystal (MTC), anti-perovskite Cu₃PdN, pressed black phosphorus, and the CaP₃ family of materials, and we present the design principles for obtaining such novel states of matter.     

傅里叶变换中红外光谱法检测脑膜瘤的研究

采用傅里叶变换衰减全反射中红外光谱法检测了24例液氮冻存的脑膜瘤离体样品(其中良性肿瘤12例,有恶性倾向的肿瘤12例),对得到的红外光谱进行整理分析,发现不同类型脑膜瘤组织(如纤维型脑膜瘤和内皮型脑膜瘤)的红外光谱存在着差异,并且同一种类型的脑膜瘤组织,其恶性倾向的程度不同,他们的红外光谱也表现出较为明显的区别,因此,我们可以从各个特征吸收峰的峰位、峰形及峰强等信息的变化来区分脑膜瘤,并可以初步鉴别脑膜瘤的性质;研究结果发现,通过某些特征吸收峰(如1 160cm-1)峰位的变化来鉴别脑膜瘤的性质与病理诊断结果的符合率大于85%,说明傅里叶变换衰减全反射中红外光谱法有可能发展成为一种对样品无损伤、快速的脑肿瘤诊断新方法。     

Microstructural and mechanical analysis of Cu and Au interconnect on various bond pads

Effects of High Temperature Storage (HTS) and bonding toward microstructure change of intermetallic compound (IMC) at the wire bonding interface of 3 types of bond pad (Al, AlSiCu and NiPdAu) were presented in this paper. Optical and electron microscope analyses revealed that the IMC growth rate of samples under 175 and 200 °C HTS increased in the order of Al > AlSiCu > NiPdAu. Besides, higher HTS and bonding temperatures also promoted higher IMC thickness. The compositional study showed that higher HTS and bonding temperature developed rapid interdiffusion in bonding interface. In the mechanical ball shear test, a decrease of the shear force of Al and AlSiCu bond pads after 500 h HTS was believed due to poorly developed IMC at bonding interface. On the other hand, shear force degradation at 1000 h was due to excessive growth of IMC that in turn causes the formation of defects. For NiPdAu bond pad, increasing trend of shear force with HTS duration at 175 °C implied a good reliability of the Cu wire bonding. The rapid microscopic inspection on Cu wired Al bond pad under HTS 175 °C showed the IMC development from the periphery to the center of the ball bond. However, after 500 h voids started to develop until the crack was observed at 1000 h.