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11.
Daniel C. Cohen Peter Orlik 《Transactions of the American Mathematical Society》2005,357(8):3031-3050
We study the Gauss-Manin connection for the moduli space of an arrangement of complex hyperplanes in the cohomology of a complex rank one local system. We define formal Gauss-Manin connection matrices in the Aomoto complex and prove that, for all arrangements and all local systems, these formal connection matrices specialize to Gauss-Manin connection matrices.
12.
E.Ann Hallinan Clifford R. DornWilliam M. Moore Gina M. JeromePamela T. Manning Barnett S. Pitzele 《Tetrahedron letters》2003,44(39):7345-7347
Described is a method of introducing trifluoroalkyl groups at C-6 of lysine. This chemistry has the potential to introduce a variety of functionality at C-6 of lysine. 相似文献
13.
Vishal Sipani Ann Kirsch Alec B. Scranton 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):4409-4416
The effective propagation rate constant (kp; averaged over all the propagating active centers) was characterized for solvent‐free cationic photopolymerizations of phenyl glycidyl ether over the entire range of conversions, including the high conversion regime in which mass transfer limitations become important. The profile for the kp as a function of conversion was found to exhibit a constant plateau value at low to intermediate conversions, followed by a monotonic increase above a threshold value of conversion. To explain this trend, it is proposed that at high conversion the diffusional mobility of the photoinitiator counterion is reduced whereas the mobility of the cationic active center remains high because of reactive diffusion. Therefore, with increasing conversion, the average distance between the active centers and counterions may increase, resulting in an increase in the propagation rate constant. The profiles for the kp values were investigated as a function of the temperature, photoinitiator anion, and photoinitiator concentration. As the photoinitiator concentration was increased, the plateau value of the effective propagation rate constant decreased whereas the threshold conversion increased. All of the experimental trends are consistent with the proposed increase in ion separation at high conversions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4409–4416, 2004 相似文献
14.
In the nineteenth century, field theory brilliantly resolveda number of questions that had taxed mathematicians for centuries;for example, The circle cannot be squared by straightedge and compass, and solving polynomial equations by radicalsis not always possible. These successes have continued to beheld up as superb examples of the power of mathematical thought,and are demonstrated at an undergraduate level. The purposeof this article is to provide another such natural example whichleads to a concrete realisation of the free group on 2 generators. 相似文献
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16.
M. C. Fornaciari Iljadica J. C. Furnari I. M. Cohen 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(1):273-275
Summary The evolution of education in Argentina at the university level is described. The detailed search of the educational offer
shows that less than half of the universities (35 out of 92) include chemistry and chemistry related undergraduate programmes
in their curriculum. The revision of the position of radiochemistry in these programmes reveals that only seven courses on
radiochemistry are currently offered. Radiochemistry is included only in few programmes in chemistry and biochemistry. With
respect to the programmes in chemical engineering the situation is worse. This offer is strongly concentrated in Buenos Aires
and its surroundings. 相似文献
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18.
Let X be a locally self-similar stochastic process of index 0<H<1 whose sample paths are a.s. CH?ε for all ε>0. Then the Hausdorff dimension of the graph of X is a.s. 2?H. To cite this article: A. Benassi et al., C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
19.
The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ± 0.3) × 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experimental data and calculations. Several possible reaction channels are discussed, and although products were not monitored, it seems probable, on the basis of other work and theoretical estimates, that the primary mechanism (?75%) for the removal of OH by CH3 at these conditions is their combination to form CH3OH. Rate coefficients of (5.3 ± 0.8) × 1012 and (9.0 ± 1.4) × 1012 cm3/mol-s were measured for the reactions of OH with acetone and ethane, respectively, at the same temperature and pressure. 相似文献
20.