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81.
[reaction: see text]. N-Benzhydryl aziridines-2-carboxylates can be readily obtained from the catalytic asymmetric aziridination reaction from N-benzhydrylimines and ethyl diazoacetate. Cleavage of the benzhydryl group by hydrogenolysis leads to ring opening when R = aryl. Surprisingly, ozone will selectively oxidize the benhydryl group in these aziridines even when R is an aryl group. This allows for a new deprotection strategy for these aziridines whose generality is explored. 相似文献
82.
Transfer of data in linear quantum registers can be significantly simplified with preengineered but not dynamically controlled interqubit couplings. We show how to implement a mirror inversion of the state of the register in each excitation subspace with respect to the center of the register. Our construction is especially appealing as it requires no dynamical control over individual interqubit interactions. If, however, individual control of the interactions is available then the mirror inversion operation can be performed on any substring of qubits in the register. In this case, a sequence of mirror inversions can generate any permutation of a quantum state of the involved qubits. 相似文献
83.
For the antiferromagnetic, highly anisotropic XZ and XXZ quantum spin chains, we impose periodic boundary conditions on chains
with an odd number of sites to force an interface (or kink) into the chain. We prove that the energy of the interface depends
on the momentum of the state. This shows that at zero temperature the interface in such chains is not stable. This is in contrast
to the ferromagnetic XXZ chain for which the existence of localized interface ground states has been proven for any amount
of anisotropy in the Ising-like regime.
Received: 15 August 2002 / Accepted: 8 January 2003
Published online: 14 April 2003
RID="⋆"
ID="⋆" ? Copyright rests with the authors. Reproduction of the entire article for non-commercial purposes is permitted.
Communicated by M. Aizenman 相似文献
84.
Wen J Chowdhury P Fulton DB Datta A Das K Andreotti AH Petrich JW 《Photochemistry and photobiology》2003,77(1):5-9
Nuclear magnetic resonance measurements indicate that hypericin exists in the same "normal" tautomeric form irrespective of whether the solvent is dimethyl sulfoxide or tetrahydrofuran. This result is discussed in the context of previous experimental and theoretical work. It is concluded that solvent perturbations cannot induce tautomerization in hypericin. 相似文献
85.
Cavity cluster approach for quantification of cavitational intensity in sonochemical reactors 总被引:2,自引:0,他引:2
The mechanism involved in the spectacular effects from cavitation phenomenon is very complex and there have been several proposed theories to explain the observed results. The experimental as well as the visual observations indicate that a single collapsing cavity is also influenced by the dynamics of the surrounding cavities, which are very near to the collapsing cavity. The observed effects and erosion patterns cannot be explained properly on the basis of a single cavity collapse and hence in this study a cavity cluster (group of cavities) has been considered to understand the mechanism of cavitational effects. The effect of intensity, frequency of ultrasound, initial size of the cluster and the fraction of energy transferred from the collapsing cavities to the surrounding cavities on the cavitational intensity quantified in terms of the pressure pulse generated at the collapse of cavities as well as the active zone of cavitation has been investigated using bubble/cavity dynamics equations, numerically. On the basis of the trends obtained, empirical correlations estimating the collapse pressure and active volume of cavitation, have been developed. 相似文献
86.
In an R-parity nonconserving supersymmetric theory, the lighter stop can dominantly decay into b&mgr; and btau if R-parity breaking has to explain the neutrino mass and mixing pattern suggested by the data on atmospheric muon neutrinos. This should give rise to dilepton + dijet and single - lepton + jets, signals identical with those of the top quark at the Fermilab Tevatron. One can thus constrain the stop parameter space using the current top search data and can similarly look for the first signals of supersymmetry at the upgraded runs of the Tevatron. 相似文献
87.
A. Saha A. Ray S. Mukhopadhyay P.K. Datta P.K. Dutta S.M. Saltiel 《Applied physics. B, Lasers and optics》2007,87(3):431-436
An all-solid-state, side diode array pulse pumped Nd:YAG laser tunable for six wavelengths ranging from 1318.8 nm to 1356.0 nm
is developed. The tunability is obtained by using a grating in Littrow mode that also serves as an output coupler. The configuration
ensures a line width as low as 0.04 nm. Thermal effects limit the maximum average power to 250 mW for an average absorbed
pump power of 8.0 W in the free-running condition. An acousto-optic Q-switching of the laser provides pulses of width 251 ns
with peak power of 733 W for an average pump power of 11.5 W. The laser may find application in microsurgery and dermatology.
PACS 42.55.Xi; 42.60.-v; 42.60.Fc; 42.60.Gd; 42.62.Be 相似文献
88.
P. Pardhasaradhi D. Madhavi Latha P. V. Datta Prasad G. Padmaja Rani P. R. Alapati V. G. K. M. Pisipati 《Journal of Thermal Analysis and Calorimetry》2013,111(2):1483-1490
As a part of the systematic studies on symmetric liquid crystal dimer homologous series, α,ω-bis-(4-n-alkylaniline benzylidene-4′-oxy) alkanes, (referred to as m.OnO.m with m = 3, 4, and 5; and n = 8, 9, and 10), we present in this article the nature of phase transitions across isotropic–nematic and nematic–smectic-A (N–SmA) phases exhibited by the just mentioned compounds. The methods employed are differential scanning calorimetry and dilatometry. The compounds studied were 3.O8O.3, 4.O8O.4, and 5.O8O.5; and 3.O9.03, 5.O9O.5, 3.O10O.3, 4.O10O.4, and 5.O10O.5. Different from the case of their corresponding monomers, all these compounds exhibit a nematic phase only with the exception of 5.O8O.5 which exhibits a SA phase in addition to the nematic phase. The phase transitions viz., isotropic–nematic transitions studied in all these compounds were confirmed to be of first-order nature, whereas the N–SmA transition exhibited by the compound 5.O8O.5 only was found to be of second-order nature. We also report in this article the calculated density jumps, thermal expansion coefficient maxima, and pressure dependence of transition temperatures which are analyzed in the light of the available literature data. 相似文献
89.
Coefficients of characteristic polynomials (CP) of linear polyacenes (LP) have been shown to be obtainable from Pascal’s triangle
by using a graph factorisation and squaring technique. Strong subspectrality existing among the members of the linear polyacene
series has been shown from the derivation of the CP’s. Thus it has been shown that the entire eigenspectrum of ann-ring LP is included in that of (2n + 1)-ring LP. Correspondence between the eigenspectra of linear chains and LP’s is brought
out by a recently developed vertex-alternation and squaring algorithm. 相似文献
90.
Anwar Usman Ibrahim Abdul Razak Suchada Chantrapromma Hoong-Kun Fun Jayanta Kumar Ray Sujit Das Adhikari Bishnu Pada Datta 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(12):1441-1442
In the title compound, C20H20FNO5S, the pyrrolidine ring adopts an envelope conformation. The fluorophenyl and thiophene rings are individually planar. The molecular and crystal structures are stabilized by intra- and intermolecular C—H⋯O interactions. 相似文献