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Reynaldo C. Castells Eleuterio L. Arancibia Angel M. Nardillo 《Journal of solution chemistry》1993,22(1):85-94
The retention behavior of eight halomethanes and four saturated hydrocarbons was measured in gas chromatographic stationary phases consisting in tri-n-octylamine (TOA), squalane (SQ) and six TOA+SQ mixtures, at 55.0, 58.5, 62.5 and 65.0°C. Equlibrium constants for complex formation were extracted from experimental data by using a lattice model developed by Martire. The results may be interpreted in terms of the formation of weak hydrogen-bonded complexes, with sociation constants of about 0.13 L-mol–1 for haloforms and 0.07 L-mol–1 for dihalomethanes at 60°C. 相似文献
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In this paper we continue to study the spectral norms and their completions ([4]) in the case of the algebraic closure $ \overline {\mathbb Q} $ of ? in ?. Let $ \widetilde{\overline{\mathbb{Q}}} $ be the completion of $ \overline {\mathbb Q} $ relative to the spectral norm. We prove that $ \widetilde{\overline{\mathbb{Q}}} $ can be identified with the R‐subalgebra of all symmetric functions of C(G), where C(G) denotes the ?‐Banach algebra of all continuous functions defined on the absolute Galois group G = Gal$ {\overline {\mathbb Q}} / {\mathbb Q} $. We prove that any compact, closed to conjugation subset of ? is the pseudo‐orbit of a suitable element of $ \widetilde{\overline{\mathbb{Q}}} $. We also prove that the topological closure of any algebraic number field in $ \widetilde{\overline{\mathbb{Q}}} $ is of the form $\widetilde{\mathbb{Q}[x]}$ with x in $ \widetilde{\overline{\mathbb{Q}}} $. 相似文献
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We introduce the notion of n-nuanced MV-algebra by performing a Łukasiewicz–Moisil nuancing construction on top of MV-algebras. These structures extend both MV-algebras and Łukasiewicz–Moisil algebras, thus unifying two important types of structures in the algebra of logic. On a logical level, n-nuanced MV-algebras amalgamate two distinct approaches to many valuedness: that of the infinitely valued Łukasiewicz logic, more related in spirit to the fuzzy approach, and that of Moisil n-nuanced logic, which is more concerned with nuances of truth rather than truth degree. We study n-nuanced MV-algebras mainly from the algebraic and categorical points of view, and also consider some basic model-theoretic aspects. The relationship with a suitable notion of n-nuanced ordered group via an extension of the Γ construction is also analyzed. 相似文献
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A noncooperative game governed by a distributed-parameter predator-prey system is considered, assuming that two players control
initial conditions for predator and prey, respectively. Existence of a Nash equilibrium is shown under the condition that
the desired population profiles and the environmental carrying capacity for the prey are sufficiently small. A conceptual
approximation algorithm is proposed and analyzed. Finally, numerical simulations are performed, too. 相似文献
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We consider a single machine scheduling problem with two min-sum objective functions: the sum of completion times and the sum of weighted completion times. We propose a simple polynomial time (1+(1/γ),1+γ)-approximation algorithm, and show that for γ>1, there is no (x,y)-approximation with 1<x<1+(1/γ) and 1<y<1+(γ-1)/(2+γ). 相似文献
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Summary A separated filtered ring has a maximally complete immediate extension. This is an analogue of Krull Theorem from valuation
ring theory in the frame of filtered rings.
Riassunto Un anello separato filtrato ha una immediata estensione massimale completa. Questo risultato è un analogo del teorema di Krull della teoria degli anelli di valutazione nell’ambito degli anelli filtrati.相似文献
9.
Parking Capacity and Pricing in Park'n Ride Trips: A Continuous Equilibrium Network Design Problem 总被引:2,自引:0,他引:2
In this paper we consider the problem of designing parking facilities for park'n ride trips. We present a new continuous equilibrium network design problem to decide the capacity and fare of these parking lots at a tactical level. We assume that the parking facilities have already been located and other topological decisions have already been taken.The modeling approach proposed is mathematical programming with equilibrium constraints. In the outer optimization problem, a central Authority evaluates the performance of the transport network for each network design decision. In the inner problem a multimodal traffic assignment with combined modes, formulated as a variational inequality problem, generates the share demand for modes of transportation, and for parking facilities as a function of the design variables of the parking lots. The objective is to make optimal parking investment and pricing decisions in order to minimize the total travel cost in a subnetwork of the multimodal transportation system.We present a new development in model formulation based on the use of generalized parking link cost as a design variable.The bilevel model is solved by a simulated annealing algorithm applied to the continuous and non-negative design decision variables. Numerical tests are reported in order to illustrate the use of the model, and the ability of the approach to solve applications of moderate size. 相似文献
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Push-pull dithiafulvenes with reduced bond length alternation (BLA) and high optical nonlinearities have been prepared. The interplay between the proaromaticity of the donor and the structural and optical properties of these merocyanines is discussed. The donor ability of dithiafulvenes can reach that of ferrocene or dialkylaminophenyl groups. 相似文献