全文获取类型
收费全文 | 10556篇 |
免费 | 377篇 |
国内免费 | 62篇 |
专业分类
化学 | 7935篇 |
晶体学 | 84篇 |
力学 | 236篇 |
数学 | 1315篇 |
物理学 | 1425篇 |
出版年
2023年 | 72篇 |
2022年 | 89篇 |
2021年 | 126篇 |
2020年 | 206篇 |
2019年 | 168篇 |
2018年 | 130篇 |
2017年 | 117篇 |
2016年 | 270篇 |
2015年 | 255篇 |
2014年 | 284篇 |
2013年 | 520篇 |
2012年 | 755篇 |
2011年 | 922篇 |
2010年 | 437篇 |
2009年 | 284篇 |
2008年 | 675篇 |
2007年 | 733篇 |
2006年 | 770篇 |
2005年 | 752篇 |
2004年 | 598篇 |
2003年 | 505篇 |
2002年 | 439篇 |
2001年 | 119篇 |
2000年 | 106篇 |
1999年 | 103篇 |
1998年 | 94篇 |
1997年 | 100篇 |
1996年 | 121篇 |
1995年 | 85篇 |
1994年 | 90篇 |
1993年 | 77篇 |
1992年 | 70篇 |
1991年 | 68篇 |
1990年 | 50篇 |
1989年 | 39篇 |
1988年 | 46篇 |
1987年 | 35篇 |
1986年 | 24篇 |
1985年 | 86篇 |
1984年 | 52篇 |
1983年 | 33篇 |
1982年 | 60篇 |
1981年 | 57篇 |
1980年 | 48篇 |
1979年 | 47篇 |
1978年 | 44篇 |
1977年 | 39篇 |
1976年 | 31篇 |
1975年 | 36篇 |
1974年 | 23篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
The 2D Ising model is well-formulated to address problems in adsorption thermodynamics. It is particularly well-suited to describing the adsorption isotherms predicting the surface enantiomeric excess, , observed during competitive co-adsorption of enantiomers onto achiral surfaces. Herein, we make the direct one-to-one correspondence between the 2D Ising model Hamiltonian and the Hamiltonian used to describe competitive enantiomer adsorption on achiral surfaces. We then demonstrate that adsorption from racemic mixtures of enantiomers and adsorption of prochiral molecules are directly analogous to the Ising model with no applied magnetic field, i.e., the enantiomeric excess on chiral surfaces can be predicted using Onsager’s solution to the 2D Ising model. The implication is that enantiomeric purity on the surface can be achieved during equilibrium exposure of prochiral compounds or racemic mixtures of enantiomers to achiral surfaces. 相似文献
102.
Quantum energy coherences represent a thermodynamic resource, which can be exploited to extract energy from a thermal reservoir and deliver that energy as work. We argue that there exists a closely analogous classical thermodynamic resource, namely, energy-shell inhomogeneities in the phase space distribution of a system’s initial state. We compare the amount of work that can be obtained from quantum coherences with the amount that can be obtained from classical inhomogeneities, and find them to be equal in the semiclassical limit. We thus conclude that coherences do not provide a unique thermodynamic advantage of quantum systems over classical systems, in situations where a well-defined semiclassical correspondence exists. 相似文献
103.
104.
Julia J. Chang Andrew Martin Chuanshen Du Alana M. Pauls Martin Thuo 《Angewandte Chemie (International ed. in English)》2020,59(38):16346-16351
Fabrication of bio‐templated metallic structures is limited by differences in properties, processing conditions, packing, and material state(s). Herein, by using undercooled metal particles, differences in modulus and processing temperatures can be overcome. Adoption of autonomous processes such as self‐filtration, capillary pressure, and evaporative concentration leads to enhanced packing, stabilization (jamming) and point sintering with phase change to create solid metal replicas of complex bio‐based features. Differentiation of subtle differences between cultivars of the rose flower with reproduction over large areas shows that this biomimetic metal patterning (BIOMAP) is a versatile method to replicate biological features either as positive or negative reliefs irrespective of the substrate. Using rose petal patterns, we illustrate the versatility of bio‐templated mapping with undercooled metal particles at ambient conditions, and with unprecedented efficiency for metal structures. 相似文献
105.
Christoph R. Müller Daniel J. Holland James R. Third Andrew J. Sederman John S. Dennis Lynn F. Gladden 《Particuology》2011,9(4):330-341
This short review describes the capabilities of magnetic resonance (MR) to image opaque single- and two-phase granular systems, such as rotating cylinders and gas-fluidized beds operated in different fluidization regimes. The unique capability of MR to not only image the solids’ distribution (voidage) but also the velocity of the particulate phase is clearly shown. It is demonstrated that MR can provide measurements over different length and time scales. With the MR equipment used for the studies summarized here, temporal and spatial scales range from sub-millisecond to hours and from a few hundred micrometres to a few centimetres, respectively. Besides providing crucial data required for an improved understanding of the underlying physics of granular flows, multi-scale MR measurements were also used to validate numerical simulations of granular systems. It is shown that predictions of time-averaged properties, such as voidage and velocity of the particulate phase, made using the Discrete Element Model agree very well with MR measurements. 相似文献
106.
Philip A. Baker Andrew F. Coffey Roger Epton Tony Johnson Edward J. Mole 《Macromolecular Symposia》1988,19(1):79-91
2, 4-Dinitrophenyl-L-phenylalanine has been coupled to L-, D-, and DL-amino acid phenyl esters pendant upon a polymer matrix. The esters had been prepared by di-isopropylcarbodiimide-mediated condensation, catalyzed by 4-dimethylaminopyridine. Reverse phase high pressure liquid chromatography (HPLC), using elution solvents consisting of 10 vol.-% trifluoroacetic acid in water/acetonitrile mixtures, has been used to investigate the 2,4-dinitrophenyl L-L and L-D dipeptide mixtures obtained on hydrazinolysis of each of the dipeptide-matrix assemblies. ‘Hydrazinolysis-HPLC’ has been used also to determine intermediate peptide homogeneity in ultra-high load solid (gel) phase synthesis with Boc amino acids. Cross-linked poly(N-[2-(4-hydroxyphenyl)ethyl]acrylamide) and two derived polymers incorporating spacer groups have been used as supports. The spacer groups made possible peptide C-terminal attachment by either HF-labile benzyl ester or HF-labile cyclohexyl ester bonds, while still incorporating the phenolic ester linkage susceptible to rapid hydrazinolytic scission. 相似文献
107.
Herman Bachelard Peter Morris Andrew Taylor Nicola Thatcher 《Magnetic resonance imaging》1995,13(8):1223-1226
We are applying multi-nuclear high-field (500 MHz) MR spectroscopy of metabolising whole tissue preparations of the mammalian brain to studies on individual components of convulsions, which include prolonged depolarization, metabolic deprivation, and the effects of excitotoxins. The responses of glial cells and neurones can be partially distinguished by following labelling patterns of metabolic intermediates from 13C-labelled glucose or acetate (which enters only glial cells). This approach clearly confirmed our earlier indications that the metabolic response to depolarization (40 mM extracellular K+) occurs essentially in glial cells. Some evidence for metabolic shuttling between glia and neurones was obtained from the changes in C3/C4 ratios of glutamate and glutamine, and the C2/C3 of GABA. Mechanisms for metabolic support of neurones by glia may be of importance in neuronal protection under such metabolic stress as occurs in epilepsy. Changes in free intracellular divalent cations ([Ca2+]i and [Zn2+]i) were monitored using the 19F-MRS indicator, 5FBAPTA. Large increases in [Ca2+]i and decreases in PCr were produced by excitotoxins (glutamate and NMDA), depolarization or ischaemia, but intracellular Zn2+ appeared only after exposure to the excitotoxins. The NMDA receptor blocker, MK801, removed all of the responses to NMDA, but only prevented the appearance of Zn2+ observed with glutamate. These results indicate that the damage caused to neurones by such insults as convulsions is not due simply to the presence of excessive excitotoxic glutamate. 相似文献
108.
Young-Gui Yoon Bernd G. Pfrommer Steven G. Louie Andrew Canning 《Solid State Communications》2004,131(1):15-19
We present calculations of NMR chemical shifts in crystalline phases of some representative amino acids such as glycine, alanine, and alanyl-alanine. We explore the effects of environment on the chemical shifts in selected glycine geometries ranging from the crystalline phase to completely isolated molecules. In the crystalline and dilute molecular limits, the calculated distinct NMR chemical shifts are attributed to intermolecular hydrogen-bonds and dipole electric field effects, respectively. 相似文献
109.
A kicked quantum nondemolition measurement is introduced, where a qubit is weakly measured by pumping current. Measurement statistics are derived for weak measurements combined with single-qubit unitary operations. These results are applied to violate a generalization of the Leggett-Garg inequality. The violation is related to the failure of the noninvasive detector assumption, and may be interpreted as either intrinsic detector backaction, or the qubit entangling the microscopic detector excitations. The results are discussed in terms of a quantum point contact kicked by a pulse generator, measuring a double quantum dot. 相似文献
110.
Andrew Glenn 《Acta Physica Hungarica A》2006,25(2-4):381-388
Understanding normal nuclear medium effects present in heavy ion collisions is essential for understanding the following dynamics of the high density matter produced in the collision. Asymmetric collisions, such as deuteron + gold, provide a key tool for studying these effects since particles produced in the forward and backward directions may be subject to different phenomena. Particle production has been studied in d+Au collisions for various kinematic regions at the RHIC facility. PHENIX has measured charged hadron production as a function of pT for different centrality classes using the PHENIX muon spectrometers for d+Au collisions at $\sqrt {s_{NN} } = 200$ GeV. The PHENIX muon spectrometers have coverage in both forward and backward directions in the rapidity range 1.2 |η| < 2.4. The R cp measurement, the ratio of central to peripheral production, is presented and discussed. Comparisons are also made with some relevant theoretical calculations. 相似文献