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111.
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For more than 25 years production has helped to sharpen our understanding of QCD. In proton induced reaction some observations are rather well understood while others are still unclear. The current status of the theory of production will be sketched, paying special attention to the issues of formation time and re-interaction in a nuclear medium.  相似文献   
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During the course of our investigation of the electron transfer properties of some redox species through highly hydrophobic long chain alkanethiol molecules on gold in aqueous and non-aqueous solvents, we obtained some intriguing results such as unusually low interfacial capacitance, very high values of impedance and film resistance, all of which pointed to the possible existence of a nanometer size interfacial gap between the hydrophobic monolayer and aqueous electrolyte. We explain this phenomenon by a model for the alkanethiol monolayer—aqueous electrolyte interface, in which the extremely hydrophobic alkanethiol film repels water molecules adjacent to it and in the process creates a shield between the monolayer film and water. This effectively increases the overall thickness of the dielectric layer that is manifested as an abnormally low value of interfacial capacitance. This behaviour is very much akin to the ‘drying transition’ proposed by Lum, Chandler and Weeks in their theory of length scale dependent hydrophobicity. For small hydrophobic units consisting of apolar solutes, the water molecules can reorganize around them without sacrificing their hydrogen bonds. Since for an extended hydrophobic unit, the existence of hydrogen bonded water structure close to it is geometrically unfavourable, there is a net depletion of water molecules in the vicinity leading to the possible creation of a hydrophobic interfacial gap.  相似文献   
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Zusammenfassung Es wird eine Methode angegeben, welche auf Grund von Flockungsversuchen lyophober Sole die numerische Festlegung der lyotropen Reihe erm?glicht. Vorl?ufige Mitteilung: Büchner, Voet und Bruins, Proc. Acad. Sci. Amsterdam35, 563 (1932).  相似文献   
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Small and large-amplitude elastic deformations of the armchair structure of single-walled carbon nanotubes are investigated with emphasis on the cylindrical geometry. As starting model, we consider a discrete one-dimensional lattice of atoms interacting via a Lennard-Jones type two-body potential. In an expansion scheme using cylindrical coordinates where radial displacements are assumed negligible compared to the angular motions, a sine-lattice Hamiltonian is derived. In the limit of small-amplitude angular displacements, the dispersion spectrum of acoustic phonons is derived and the associate characteristic frequency is given as a function of parameters of the model. In the large-amplitude regime, lattice vibrations give rise to kink-type deformations which move undergoing lattice dispersion and lattice discreteness effects. The dispersion law of the kink motion is obtained and shown to lower the effect of lattice discreteness, giving rise to a vanishing Peierls stress for kink sizes of the order of a few lattice spacings. Implications of the coupling of two armchair structures on the stability of vibrational modes of an individual armchair nanotube are also discussed. A gap of forbidden modes is predicted in the phonon spectrum while the energy needed to create a kink deformation in individual nanotubes is shifted in the presence of a wall-to-wall interaction.Received: 2 August 2004, Published online: 14 December 2004PACS: 81.07.De Nanotubes - 62.30. + d Mechanical and elastic waves-vibrations - 63.22. + m Phonons in low-dimensional nanoscale materials - 63.20.Ry Anharmonic lattices modes  相似文献   
119.
Basic ideas and results which characterize quantum diffusion of defects in quantum crystals like solid helium as a new phenomenon are presented. Quantum effects in such media lead to a delocalization of point defects (vacancies, impurities etc.) and they turn into quasiparticles of a new type—defectons, which are characterized not by their position in the crystal lattice but by their quasimomentum and dispersion law. Defecton-defecton and defecton-phonon scattering are considered and an interpolation formula for the diffusion coefficient valid in all interesting temperature and concentration regions is presented. A comparison with the experimental data is made. Some alternative points of view are discussed in detail and the inconsistency of the Kisvarsanyi-Sullivan theory is shown.  相似文献   
120.
This paper describes a compulsorily phase locked differential interferometer using an orthogonally polarized light source of a modulated LD with high extinction ratio to reduce non-linearity of the interferometer caused by polarization cross-talk. The current modulated LD is used as a light source to make the interferometer compact and for the scanning phase of the interferometer. The interferometer is operated compulsorily at the maximum inclination point of the fringe intensity curve by fringe scanning and an electric system. A Wollaston prism of high extinction ratio (50 dB) is used to combine the polarizing beams and to make the polarization cross-talk very small. In one light source the polarized output beams are on the same propagation axis; in the other they have a small crossing angle (2.5 mrad ∼ 10 mrad) to completely exclude non-linearity of the interferometer causded by polarization cross-talk. Using jets of a gas mixture of nitrogen and ethylene, this interferometer was demonstrated to be useful in detecting the photothermal effect of a photothermal velocimeter under phase fluctuation in a turbulent flow.  相似文献   
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