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131.
Roy Nilsson Ralf Nyholm Anders Berndtsson Jan Hedman Carl Nordling 《Journal of Electron Spectroscopy and Related Phenomena》1976,9(4):337-353
A new source for producing YMξ radiation in an ESCA spectrometer is described. The system makes use of continuous evaporation of yttrium on a rotating anode. It is demonstrated that this scheme allows YMξ-excited electron spectra to be recorded without gradual loss of resolution and intensity due to anode oxidation. Electron spectra of Ar, Hg and N2 excited by YMξ radiation are studied. Relative photoelectric cross-sections of the 5d, 5d and 6s orbitals in Hg and the four valence orbitals in N2 are measured. The valence electron shake-up spectrum of N2 is discussed. 相似文献
132.
133.
134.
B. Anders U. Berghaus H. Brückmann P. Lara C. Pegel H. Salehi A. Schütte K. Sinram K. Wick 《Physics letters. [Part B]》1979,87(4):346-348
At the Hamburger Isochronous Cyclotron the formation of the particle unstable ground state of has been investigated in the reaction α + d → α + p + n at Eα = 28.3 MeV. The neutrons were detected in two liquid scintillation counters, while a large Si (Li) detector was used to observe the α-particles. In a first analysis, the tensor polarization parameters of the five-nucleon system 5Li are determined from the experimental data. The results are in quite good agreement with theoretical predictions of Hackenbroich et al. 相似文献
135.
A controlled temperature controlled atmosphere atomization system is described. The sample is placed on a tungsten wire provided with temperature-controlled heating. After thermal pretreatment of the sample the wire is inserted into a hot quartz tube and rapid vaporization is accomplished by separate electrothermal heating. The pyrolysis products formed are mixed with a gas buffer and are passed through two equilibrium zones. The residence time of the analyte in the system is of the order of seconds so that the probability of attaining a state close to equilibrium is high for high temperatures. A third zone is placed perpendicularly to the others and constitutes the atomic absorption measuring cell. The usefulness of the system is illustrated for the determination of lead, bismuth, cadmium and zinc. The system provides unique possibilities in controlling interference effects in complex matrices. Examples are given for lead in concentrated chloride and sulphate solutions. Good agreement between the experimental results and high-temperature equilibrium calculations was obtained for a large variation in the composition of the gas phase. 相似文献
136.
Anders Rygh Swensen 《Stochastic Processes and their Applications》1983,15(2):181-191
In this note some problems of asymptotic inference in a class of non-stationary stochastic processes are considered. In particular, it is shown that no criterion based on the existence of uniformly most powerful tests over a local neighborhood can be used in this situation. 相似文献
137.
138.
A. Niemann W. H. Mennicke H. Meyer H. Reif E. Müller K. Jeney R. H. Sterzel H. Rüssel U. Anders A. E. Bühler F. Kreuzig W. Czysz R. Kaliszan R. Wennig F. Knorr U. Gerhardt und C. Martin 《Fresenius' Journal of Analytical Chemistry》1978,290(4):347-352
Ohne Zusammenfassung 相似文献
139.
Anders O. Lindberg 《Analytica chimica acta》1978,96(2):319-325
A system for automatic coulometric titrations with photometric end-point detection is described. To compensate for errors caused by gas bubbles and turbidity, the beam is split after passing the titration cell. The intensities of the respective light beams are registered by means of two photodiodes operating in the current mode. The currents are converted to voltages and the logarithm of the quotient is taken. The measured absorbance is only slightly dependent on the variation in the intensity of the incident light. A diminution of one absorbance unit causes a relative error of less than 5%. The deviations due to carbon particles (37–75 μm) were less than 0.002 absorbance units per mg of carbon present in 10 ml of solution. The improvement with respect to errors caused by gas bubbles is illustrated. The fundamental advantage of a one-lamp system over a twolamp system is shown. 相似文献
140.
Nour-Mohhamadi F Nguyen SD Boschloo G Hagfeldt A Lund T 《The journal of physical chemistry. B》2005,109(47):22413-22419
The oxidative degradation rate, kdeg, of the solar cell dye (Bu4N+)2[Ru(dcbpyH)2(NCS)2]2-, referred to as N719 or [RuL2(NCS)2], was obtained by applying a simple model system. Colloidal solutions of N719-dyed TiO2 particles in acetonitrile were irradiated with 532-nm monochromatic light, and the sum of the quantum yields for the oxidative degradation products [RuL2(CN)2], [RuL2(NCS)(CN)], and [RuL2(NCS)(ACN)], Phideg, was obtained at eight different light intensities in the range of 0.1-16.30 mW/cm2 by LC-UV-MS. The Phideg values decreased from 3.3 x 10-3 to 2.0 x 10-4 in the applied intensity range. By using the relation kdeg = Phidegkback and back electron-transfer reaction rates, kback, obtained with photoinduced absorption spectroscopy, it was possible to calculate an average value for the oxidative degradation rate of N719 dye attached to TiO2 particles, kdeg = 4.0 x 10-2 s-1. The stability of N719 dye during solar cell operation was discussed based on this number, and on values of the electron-transfer rate between [Ru(III)L2(NCS)2] and iodide ion that are available in the literature. 相似文献