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101.
In this study the electron beam (e-beam) radiation synthesis in “paste-like condition” and characterization of the network structure of acrylic acid (AA) sodium salt/xanthan gum (XG)/carboxymethylcellulose (CMC) superabsorbent hydrogels incorporating graphene oxide (GO) was investigated. The effects of the AA concentration on gel fraction, sol-gel analysis, swelling degree and network parameters, as well as the relationship between these parameters and radiation dose was also established.Gel fraction exceeds 90%, and the p0/q0 ratio shows a moderate degradation process. The swelling kinetic data were used to determine, first the swelling degree, second the diffusion characteristics, and third the average molecular weight between crosslinks (Mc), as well as. The diffusion data revealed a Fickian mechanism transport, for each hydrogel compositions. The network parameters (Mc and ξ) increased with absorbed dose, while cross-linking density and the radiation-chemical yields were decreased. 相似文献
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103.
Anca Silvestru 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):617-620
Abstract. Solid state monomeric structures with monometallic biconnective (bidentate) diphenylphosphinodithioato groups were found in Ph2Te(S2PPh2)2 (1) or [Ph3Te][S2PPh2] (2), while in the polymeric associations [Te2(S2PPh2)2]n (3) and [PhTeS(S)PPh2]n (4) bimetallic biconnective (bridging) and monodentate biconnective (bridging) patterns were established by X-ray diffractometry. [Te(S2PPh2)3]2 (5) exhibits an unusual dimeric structure, with both monometallic biconnective and bimetallic triconnective ligand units. 相似文献
104.
Anca Paun Irina Zarafu Miron T. Caproiu Constantin Draghici Maria Maganu Ani I. Cotar Mariana C. Chifiriuc Petre Ionita 《Comptes Rendus Chimie》2013,16(7):665-671
Starting from benzocaine, a well-known anaesthetic, ten derivatives were synthesized and characterized by UV–vis, IR, NMR, and elemental analysis. Most of the compounds contain residues with recognized biological activity, like nicotinic acid (vitamin B3 or PP), biotin (vitamin B7 or H), lipoic acid (thioctic acid), adamantine, as well as other residues of crown-ether type, benzofurazane, naphtylurea, di- and tri-nitrobenzene, and a nitroxide radical. The biological evaluation of the obtained compounds included hydrophobicity (lipophobicity) assay, total antioxidant and microbiological activity tests. 相似文献
105.
Anca Zanfirescu Anca Ungurianu Dragos Paul Mihai Denise Radulescu George Mihai Nitulescu 《Molecules (Basel, Switzerland)》2021,26(18)
Neurological and neurodegenerative diseases are debilitating conditions, and frequently lack an effective treatment. Monoacylglycerol lipase (MAGL) is a key enzyme involved in the metabolism of 2-AG (2-arachidonoylglycerol), a neuroprotective endocannabinoid intimately linked to the generation of pro- and anti-inflammatory molecules. Consequently, synthesizing selective MAGL inhibitors has become a focus point in drug design and development. The purpose of this review was to summarize the diverse synthetic scaffolds of MAGL inhibitors concerning their potency, mechanisms of action and potential therapeutic applications, focusing on the results of studies published in the past five years. The main irreversible inhibitors identified were derivatives of hexafluoroisopropyl alcohol carbamates, glycol carbamates, azetidone triazole ureas and benzisothiazolinone, whereas the most promising reversible inhibitors were derivatives of salicylketoxime, piperidine, pyrrolidone and azetidinyl amides. We reviewed the results of in-depth chemical, mechanistic and computational studies on MAGL inhibitors, in addition to the results of in vitro findings concerning selectivity and potency of inhibitors, using the half maximal inhibitory concentration (IC50) as an indicator of their effect on MAGL. Further, for highlighting the potential usefulness of highly selective and effective inhibitors, we examined the preclinical in vivo reports regarding the promising therapeutic applications of MAGL pharmacological inhibition. 相似文献
106.
Elena Ceausescu R. Bordeianu Anca Ion E. Buzdugan Rodica Stancu Irina Cerchez 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(11):1555-1570
An approximate analytical solution of the set of differential equations modeling the anionic polymerization of styrene is presented. By using this solution, a new method for calculating the initiation rate constant for this polymerization process was developed. 相似文献
107.
Daniela Babusca Larisa Popescu Liviu Sacarescu Dana Ortansa Dorohoi Dorina Creanga Lacramioara Anca Oprica 《Molecular Crystals and Liquid Crystals》2020,698(1):56-64
AbstractWe have designed an experimental study dedicated to silver nanotoxicity using a suspension of citrate-silver nanoparticles, obtained by photochemical reduction. Fine granularity of generally symmetrical shape nanoparticles were evidenced by tansmission electron microscopy. The localized surface plasmon resonance spectral band revealed the intensification of silver nanoparticle formation under UV exposure. The nanotoxicity of silver nanoparticles was tested on cereal sprouts by measuring the concentrations of chlorophylls and carotenes in the green tissue. The differences between control samples, supplied with distilled water and test samples, loaded with different volumes of silver nanoparticles suspension were analyzed statistically, and compared with literature reports. 相似文献
108.
Anca Gabriela Bejenariu Henrik Koblitz Rasmussen Anne Ladegaard Skov Ole Hassager Sarah Maria Frankaer 《Rheologica Acta》2010,49(8):807-814
Using a filament stretching rheometer surrounded by a thermostatic chamber and equipped with a micrometric laser, it is possible
to measure large amplitude oscillatory elongation (LAOE) on elastomeric based networks with no base flow as in the LAOE method
for polymer melts. Poly(dimethylsiloxane)-based networks, considered as a model system for studying the development of soft
elasticity, are mechanically characterised through reversed LAOE deformation, applying oscillatory measurements with several
amplitudes and frequencies. 相似文献
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