全文获取类型
收费全文 | 839篇 |
免费 | 21篇 |
国内免费 | 14篇 |
专业分类
化学 | 497篇 |
晶体学 | 14篇 |
力学 | 43篇 |
数学 | 124篇 |
物理学 | 196篇 |
出版年
2023年 | 6篇 |
2022年 | 17篇 |
2021年 | 16篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 22篇 |
2017年 | 16篇 |
2016年 | 20篇 |
2015年 | 17篇 |
2014年 | 30篇 |
2013年 | 50篇 |
2012年 | 67篇 |
2011年 | 56篇 |
2010年 | 40篇 |
2009年 | 29篇 |
2008年 | 46篇 |
2007年 | 47篇 |
2006年 | 52篇 |
2005年 | 39篇 |
2004年 | 24篇 |
2003年 | 36篇 |
2002年 | 23篇 |
2001年 | 12篇 |
2000年 | 5篇 |
1999年 | 8篇 |
1998年 | 7篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1994年 | 8篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 3篇 |
1990年 | 11篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1974年 | 3篇 |
1973年 | 4篇 |
1970年 | 3篇 |
1969年 | 3篇 |
1968年 | 5篇 |
1961年 | 4篇 |
1960年 | 4篇 |
1958年 | 3篇 |
1948年 | 3篇 |
排序方式: 共有874条查询结果,搜索用时 0 毫秒
771.
A fractal analysis is presented for analyte-receptor binding kinetics for different types of biosensor applications. Data
taken from the literature may be modeled using a single-fractal analysis, a single- and a dual-fractal analysis, or a dual-fractal
analysis. The latter two methods represent a change in the binding mechanism as the reaction progresses on the surface. Predictive
relationships developed for the binding rate coefficient as a function of the analyte concentration are of particular value
since they provide a means by which the binding rate coefficients may be manipulated. Relationships are presented for the
binding rate coefficients as a function of the fractal dimension D
f
or the degree of heterogeneity that exists on the surface. When analyte-receptor binding is involved, an increase in the
heterogeneity on the surface (increase in D
f
) leads to an increase in the binding rate coefficient. It is suggested that an increase in the degree of heterogeneity on
the surface leads to an increase in the turbulence on the surface owing to the irregularities on the surface. This turbulence
promotes mixing, minimizes diffusional limitations, and leads subsequently to an increase in the binding rate coefficient.
The binding rate coefficient is rather sensitive to the degree of heterogeneity, D
f
, that exists on the biosensor surface. For example, the order of dependence on D
f1
is 7.25 for the binding rate coefficient k
1 for the binding of a Fab fragment of an antiparaquat monoclonal antibody in solution to an antigen in the form of a paraquat
analog immobilized on a sensor surface. The predictive relationships presented for the binding rate coefficient and the fractal
dimension as a function of the analyte concentration in solution provide further physical insights into the binding reactions
on the surface, and should assist in enhancing biosensor performance. In general, the technique is applicable to other reactions
occurring on different types of surfaces, such as cell-surface reactions. 相似文献
772.
773.
774.
B. R. Reddy S. Acharya S. Anand R. P. Das 《Journal of Thermal Analysis and Calorimetry》1991,37(5):945-951
Weathered Kimberlite tailings of Panna Diamond Mines were characterised by DTA and XRD techniques. The XRD pattern shows the presence of serpentine, quartz, calcite, hematite, magnetite and anatase phases. DTA curve indicates first endothermic peak at 125C due to dehydration of the mineral and second endo peak at 670C due to dehydroxylation of serpentine closely followed by an exothermic peak at 810C associated with the formation of forsterite. XRD and DTA studies of sulphuric acid leach residue of the Kimberlite shows the disappearance of serpentine phase with the appearance of CaSO4·2H2O phase. The product MgSO4·7H2O obtained after purification and crystallisation. From the optical emission spectroscopic analysis, the product was found to contain Ca, Fe and SiO2 as trace impurities.
Zusammenfassung Mittels DTA und Röntgendiffraktion wurden verwitterte Kimberlit-AbgÄnge aus Diamantbergwerken in Panna charakterisiert. Das Röntgendiagramm zeigt die Gegenwart von Serpentin-, Quarz-, Kalzit-, HÄmatit-, Magnetit- und Anatas-Phasen. Die DTA-Kurve zeigt einen ersten endothermen Peak bei 125C (Dehydratation des Minerales) und einen zweiten endothermen Peak bei 670C (Dehydroxylierung von Serpentin), eng gefolgt von einem exothermen Peak bei 810C (Bildung von Forsterit). Röntgendiffraktionsund DTA-Untersuchungen an einem schwefelsauren Extraktionsauszug von Kimberlit zeigen das Verschwinden der Serpentin-Phase, aber das zusÄtzliche Auftreten einer CaSO4·2H2O-Phase. Nach Reinigung und Kristallisation wurde MgSO4·7H2O als Produkt erhalten, dessen optische emissionsspektroskopische Untersuchung in Spuren Verunreinigungen mit Ca, Fe und SiO2 zeigten.相似文献
775.
776.
G.C.M. Kondaiah K. Srihari Babu K.G. Huge P. Pratap Reddy R. Vijaya Anand 《Tetrahedron letters》2008,49(1):106-109
An efficient and environmentally benign boric acid catalyzed protocol for the transesterification of ethyl acetoacetate with a variety of primary and secondary alcohols in good to excellent yields is described. The versatility of this transformation is demonstrated with problematic substrates such as propargyl alcohol and allyl alcohol, which are known to undergo Carroll rearrangement during transesterification. 相似文献
777.
Most studies of project time estimation assume that (a) activity times are mutually independent random variables; many also assume that (b) path completion times are mutually independent. In this paper, we subject the impact of both these assumptions to close scrutiny. Using tools from multivariate analysis, we make a theoretical study of the direction of the error in the classical PERT method of estimating mean project completion time when correlation is ignored. We also investigate the effect of activity dependence on the normality of path length via simulation. 相似文献
778.
Xiang Yu Abhishek Roy Stuart Dunn Anand S. Badami Juan Yang Alec S. Good James E. McGrath 《Journal of polymer science. Part A, Polymer chemistry》2009,47(4):1038-1051
Hydrophilic/hydrophobic block copolymers as proton exchange membranes (PEMs) has become an emerging area of research in recent years. These copolymers were obtained through moderate temperature (~ 100 °C) coupling reactions, which minimize the ether‐ether interchanges between hydrophobic and hydrophilic telechelic oligomers via a nucleophilic aromatic substitution mechanism. The hydrophilic blocks were based on the nucleophilic step polymerization of 3,3′‐disulfonated, 4,4′‐dichlorodiphenyl sulfone with an excess 4,4′‐biphenol to afford phenoxide endgroups. The hydrophobic (fluorinated) blocks were largely based on decafluoro biphenyl (excess) and various bisphenols. The copolymers were obtained in high molecular weights and were solvent cast into tough membranes, which had nanophase separated hydrophilic and hydrophobic regions. The performance and structure‐property relationships of these materials were studied and compared to random copolymer systems. NMR results supported that the multiblock sequence had been achieved. They displayed superior proton conductivity, due to the ionic proton conducting channels formed through the self‐assembly of the sulfonated blocks. The nano‐phase separated morphologies of the copolymer membranes were studied and confirmed by atomic force microscopy. Through control of a variety of parameters, including ion exchange capacity and sequence lengths, performances as high, or even higher than those of the state‐of‐the‐art PEM, Nafion, were achieved. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1038–1051, 2009 相似文献
779.
K. Anand T. Galla 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,68(4):587-600
The theory of complex networks and of disordered systems is used to study the stability and dynamical properties of a simple model of material flow networks defined on random graphs. In particular we address instabilities that are characteristic of flow networks in economic, ecological and biological systems. Based on results from random matrix theory, we work out the phase diagram of such systems defined on extensively connected random graphs, and study in detail how the choice of control policies and the network structure affects stability. We also present results for more complex topologies of the underlying graph, focussing on finitely connected Erdös-Réyni graphs, Small-World Networks and Barabási-Albert scale-free networks. Results indicate that variability of input-output matrix elements, and random structures of the underlying graph tend to make the system less stable, while fast price dynamics or strong responsiveness to stock accumulation promote stability. 相似文献
780.
Steven Buechler Anand Pillay Frank Wagner 《Journal of the American Mathematical Society》2001,14(1):109-124
We prove elimination of hyperimaginaries in supersimple theories. This means that if an equivalence relation on the set of realisations of a complete type (in a supersimple theory) is defined by a possibly infinite conjunction of first order formulas, then it is the intersection of definable equivalence relations.