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991.
992.
Baosić R Radojević A Radulović M Miletić S Natić M Tesić Z 《Biomedical chromatography : BMC》2008,22(4):379-386
The lipophilicity of a series of Schiff base ligands and their complexes with nickel(II) and copper(II) has been determined by reversed-phase thin-layer chromatography using binary dioxane-water mobile phase. Chelate ligands were prepared by condensation of diamine and the corresponding beta-diketone. Copper(II) and nickel(II) complexes with chelate ligands containing ethane-1,2-diamine or propane-1,2-diamine as the amine part and pentane-2,4-dione and/or 1-phenylbutane-1,3-dione, pentane-2,4-dione and/or 1,1,1-trifluoropentane-2,4-dione, or 1,1,1-trifluoropentane-2,4-dione and/or 1-phenylbutane-1,3-dione as the beta-diketone part were synthesized. Some of investigated compounds were screened for their in vitro antifungal activity against Sacharomyces cerevisiae and antibacterial activity against Escherichia coli. Chromatographically obtained lipophilicity parameters were correlated both with calculated n-octanol-water partition coefficient C log P and antimicrobial activities. Satisfactory correlations were obtained. Chromatographic data proved to be reliable parameters for describing the lipophilic properties of the investigated compounds. Additionally, the principal components analysis was performed on the data chromatographically obtained. This statistical method was useful for distinguishing compounds and objective comparison of their lipophilicity parameters. 相似文献
993.
Snia P.M. Ventura Jrme Pauly Jean L. Daridon J.A. Lopes da Silva Isabel M. Marrucho Ana. M.A. Dias Joo A.P. Coutinho 《The Journal of chemical thermodynamics》2008,40(8):1187-1192
Ionic liquids are attracting great attention nowadays due to their interesting properties which make them useful in a broad range of applications including reaction media or separation/capture of environmentally hazardous gases such as carbon dioxide. In many cases, for practical and/or economical reasons, the use of aqueous solutions of ILs would be preferable to their use as pure compounds.In this work, high pressure equilibrium data for the {carbon dioxide (CO2) + tri-iso-butyl(methyl)phosphonium tosylate [iBu3MeP][TOS] + water system were measured at temperatures ranging from (276 to 370) K and pressures up to 100 MPa. Measurements were performed using a high-pressure cell with a sapphire window that allows direct observation of the liquid–vapour transition. Mixtures with different IL concentrations were studied in order to check the influence of the amount of IL on the solubility of CO2 in the aqueous mixture.The results show that the presence of IL enhances the solubility of CO2 in the (IL + water) system revealing a salting-in effect of the IL on the solubility of CO2. The appearance of a three phase region was observed for IL concentrations higher than 4 mol% of IL in water when working at pressures between 4 and 8 MPa and temperatures between (280 and 305) K. In this range, the upper limit of the VLE region observed is shown to increase with the temperature being almost independent of the IL initial concentration in the mixture. 相似文献
994.
995.
Silva JR de Souza NC Fernandes VC Homem-de-Mello P Oliveira ON 《Journal of colloid and interface science》2008,327(1):31-35
Langmuir-Blodgett (LB) films from diazobenzene Sudan III have been investigated using surface potential measurements as a function of number of layers and deposition pressures, with the surface potential data being related to molecular dipole moments obtained from theoretical electronic structure calculations. The surface potential increased with the number of layers for SIII LB films, and then tended to saturate. Results from density functional theory (DFT) and UV-vis spectroscopy indicated that the increase is due to addition of layers with oriented molecular dipoles, with the saturation tendency being attributed to a decrease in the amount of material deposited in each layer. The surface potential increased with the surface pressure used for deposition, probably owing to a higher contribution from the vertical component of the dipole moment as a closer molecular packing, which is associated with decreasing conformational entropy, was reached. 相似文献
996.
Valente AJ Burrows HD Cruz SM Pereira RF Ribeiro AC Lobo VM 《Journal of colloid and interface science》2008,323(1):141-145
Aggregation properties of sodium dodecyl sulfate (SDS) in the presence of cerium(III) chloride, at various temperatures (298.15-323.15 K) have been measured by the electrical conductance technique. The experimental data on aqueous solutions as a function of SDS concentration show the presence of two inflexion points indicating the presence of two distinct interaction mechanisms: the first, occurring at SDS concentrations below the critical micelle concentration of the pure surfactant, which can be explained by the formation of aggregates between dodecyl sulfate (DS-) and Ce(III), while the second one, at SDS concentrations around the critical micelle concentration (cmc) of the pure surfactant which is due to the SDS micellization. The aggregation between DS- and Ce(III) was confirmed by static light scattering. The binding ratio of DS-/Ce(III) changes from 6 to 4, shows a slight dependence on the Ce(III) concentration and is independent of the temperature. The thermodynamic micellization parameters, Gibbs energy, enthalpy and entropy of micellization were calculated on the basis of the experimental data for the aggregation concentration, and the degree of counterion dissociation of the micelles. The SDS micellization is energetically favoured by increasing either the concentration of CeCl3 or the temperature. Such behaviour is clearly dominated by a decrease of the micellization (exothermic) enthalpy. The entropy of micellization approaches zero as the cerium(III) chloride concentration and temperature increase. 相似文献
997.
Gómez-Caravaca AM Verardo V Segura-Carretero A Caboni MF Fernández-Gutiérrez A 《Journal of chromatography. A》2008,1209(1-2):238-245
The aim of this work was to develop a capillary electrophoresis-mass spectrometry (CE-MS) method to identify and quantify phenolic and other related polar compounds in walnut samples. The extraction capacity of several solvent mixtures of phenolic compounds from walnut by conventional solid-liquid extractions was tested, and CE and electrospray ionization MS parameters were optimized. The finalized procedure is able to determine many well-known phenolic compounds present in walnuts and provide relevant information about the presence of minor polar compounds. A new compound in walnut ((2E,4E)-8-hydroxy-2,7-dimethyl-2,4-decadiene-1,10-dioic acid 6-O-beta-d-glucopiranosyl ester, [M-H](-) 403.161m/z) with a structure similar to glansreginins was also identified. Phenolic compounds correspond to 14-28% of total polar compounds quantified. Aglycone and glycosylated ellagic acid represent the principal components and account for 64-75% of total phenols in walnuts. However, the sum of glansreginins A, B and (2E,4E)-8-hydroxy-2,7-dimethyl-2,4-decadiene-1,10-dioic acid 6'-O-beta-d-glucopiranosyl ester was in the range of 72-86% of total quantified compounds. In addition, this is the first time that separation by CE with detection by electrospray ionization time-of-flight MS has been applied to the analysis of phenolic and other polar compounds in walnut samples, providing results in less than 15min. 相似文献
998.
René A. Clará Ana C. Gómez Marigliano Horacio N. Sólimo 《The Journal of chemical thermodynamics》2008,40(2):292-297
Density, viscosity, refractive index, and heat of mixing measurements for {x1 1-butanol + (1 ? x1) 2-butanone} at T = 303 K were made over the whole concentration range. Data of the binary mixture were further used to calculate the viscosity and refractive index deviations, and excess molar enthalpy. The excess or deviation properties were fitted with the Redlich–Kister polynomial relation to obtain their coefficients and standard deviations. The construction of an adiabatic calorimeter useful in the neighbourhood of room temperature is described. Its performance was checked by measuring the heat of mixing for {x1 benzene + (1 ? x1) cyclohexane} over the whole concentration range at T = 298 K. Experimental results are within a standard deviation of 9 J · mol?1 of the accepted literature values. 相似文献
999.
1000.
Luisa Alonso Alberto Arce María Francisco Ana Soto 《The Journal of chemical thermodynamics》2008,40(6):966-972
In the last years, new strict environmental regulations to reduce sulfur content in liquid fuels have been established. Thiophene derivates can be considered as the key substances to be separated from liquid fuel oils. This paper reports the ability of the ionic liquid 1-methyl-3-octylimidazolium tetrafluoroborate to act as solvent in the (liquid + liquid) extraction of thiophene from aliphatic hydrocarbons. Tie-line data have been determined for ternary systems containing the ionic liquid, thiophene, and some n-alkanes at T = 298.15 K. Extraction process has been analyzed by means of thiophene distribution ratio and selectivity. The solute distribution coefficient decreases and the selectivity increases as the chain length of n-alkane increases. The use of 1-methyl-3-octylimidazolium tetrafluoroborate as potential solvent for separation of thiophene from n-alkanes is feasible using the necessary quantity of solvent. A correlation of the equilibrium data reported here has also been made, using the NRTL activity coefficient model, in order to facilitate their use in simulation and design processes. 相似文献