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271.
272.
We show that when polystyrene is exposed (for 15–60 sec) to a UV laser light beam (λ = 248 nm), its absorption and luminescent
properties change significantly. In the irradiated polymer, optical centers are formed with absorption bands in the 280–460
nm region and fluorescence bands in the 330–520 nm region. We have established the chemical structure of the optical centers
for fluorescence of polystyrene.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 1, pp. 54–58, January–February, 2006. 相似文献
273.
274.
A method for deriving one-dimensional wave propagation equations in thin inhomogeneous anisotropic bars based on the mathematical homogenization theory for periodic media is used to obtain equations governing the longitudinal and transverse vibrations of a homogeneous circular bar. The equations are derived up to O(ε8) terms and take into account variable body forces and surface loads. Here, ε is the ratio of the bar’s typical thickness to the typical wavelength. 相似文献
275.
R. U. Khafizov N. Severijns O. Zimmer H. -F. Wirth D. Rich S. V. Tolokonnikov V. A. Solovei M. R. Kolhidashvili 《JETP Letters》2006,83(1):5-9
The aim of this work is the experimental observation of and research into a rare neutron mode, the radiative beta decay, where
a new particle, the radiative gamma quantum, is formed along with the expected decay products: a beta electron, a recoil proton,
and an antineutrino. The discovery of this rare neutron decay mode was conducted through identification of triple-coincidence
events: simultaneous registration of a beta electron, a proton, and a radiative gamma quantum. The ordinary neutron decay
was registered by double coincidences of a beta electron and a recoil proton. The statistics collected allow one to deduce
the branching ratio (BR) BR = (3.2 ± 1.6) × 10−3 (90% C.L.) in the gamma energy region greater than 35 keV. This value of BR is consistent with standard electroweak theory.
The text was submitted by the authors in English.
An erratum to this article is available at . 相似文献
276.
Photoisomerization of provitamin D 3 (7-dehydrocholesterol) in a nematic liquid crystal (ZLI-1695, Merck) is investigated in detail by UV absorption spectroscopy. It is found that dissolution of chiral molecules of provitamin D 3 induces the cholesteric phase in a nematic. The spectral kinetics of photoisomerization in this phase changes significantly from that in an ethanol solution. A sharp nonmonotonic dependence of the increase in accumulation of trans isomer tachysterol in a liquid crystal matrix with a decrease in the induced cholesteric pitch from 2200 to 25 μm is revealed. 相似文献
277.
Evstafyeva I. T. Bozhenkov G. V. Aizina Ya. A. Rozenzveig I. B. Ermakova T. G. Levkovskaya G. G. Mirskova A. N. 《Russian Journal of Organic Chemistry》2002,38(8):1178-1182
1H-Pyrazoles, triazoles, and imidazoles in reaction with ethoxycarbonylimine and arylsulfonylimines of chloral yield addition products, corresponding 1-(1-amidotrichloroethyl)azoles. Derivatives of 1-alkylpyrazoles and pyrazolones react with chloral 4-chlorophenylsulfonylimine to furnish products of C-amidotrichloroethylation into position 4 of the azole ring. 相似文献
278.
The effect of hydrogen on the photoluminescence and planar conductivity of GaAs/InGaAs quantum-well heterostructures with an island Pd layer at the anodically oxidized surface was studied. Unlike continuous deposited Pd layers, island layers do not cause the formation of defects in the GaAs surface region and yet the Pd layer maintains high catalytic activity with respect to hydrogen. It is found that the thermal treatment of such a structure in a hydrogen atmosphere causes atomic-hydrogen passivation of the defects in quantum wells. Studies of the characteristics of planar photoresistors with an island Pd layer acting as hydrogen sensors show that their hydrogen detectivity is approximately two orders of magnitude higher than that of diode structures with continuous Pd layers. 相似文献
279.
The injection of positrons into crystalline adamantane results in the formation of positronium (Ps). At temperatures T> 400 K the mean lifetime of the long-lived ortho-positronium exhibits a sigmoidal increase with temperature characteristic of the trapping of this species in thermally created defects. The variation is well described by the trapping model usually applied to the trapping of positrons in defects in metals. The formation energy of the defects which trap ortho-Ps is estimated at Efv = 70 ± 10 kJ mol-1 (0.73 ± 0.1 eV). This value is in good agreement with estimates of the formation energy of lattice vacancies in adamantane derived from self-diffusion studies. 相似文献
280.
E. A. Bailov N. Temirgaliev 《Computational Mathematics and Mathematical Physics》2006,46(9):1515-1525
Sharp estimates (in the power scale) are obtained for the discretization error in the solutions to Poisson’s equation whose right-hand side belongs to a Korobov class. Compared to the well-known Korobov estimate, the order is almost doubled and has an ultimate value in the power scale. 相似文献