全文获取类型
收费全文 | 313篇 |
免费 | 17篇 |
国内免费 | 1篇 |
专业分类
化学 | 246篇 |
力学 | 11篇 |
数学 | 23篇 |
物理学 | 51篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 11篇 |
2021年 | 26篇 |
2020年 | 11篇 |
2019年 | 26篇 |
2018年 | 11篇 |
2017年 | 13篇 |
2016年 | 23篇 |
2015年 | 9篇 |
2014年 | 11篇 |
2013年 | 21篇 |
2012年 | 10篇 |
2011年 | 11篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 15篇 |
2007年 | 14篇 |
2006年 | 8篇 |
2005年 | 4篇 |
2004年 | 4篇 |
2003年 | 8篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1971年 | 1篇 |
1967年 | 4篇 |
排序方式: 共有331条查询结果,搜索用时 109 毫秒
41.
Anuraj Singh Abdelalim A. Elsadany Amr Elsonbaty 《Mathematical Methods in the Applied Sciences》2019,42(11):3992-4007
A proposed discretized form of fractional‐order prey‐predator model is investigated. A sufficient condition for the solution of the discrete system to exist and to be unique is determined. Jury stability test is applied for studying stability of equilibrium points of the discretized system. Then, the effects of varying fractional order and other parameters of the systems on its dynamics are examined. The system undergoes Neimark‐Sacker and flip bifurcation under certain conditions. We observe that the model exhibits chaotic dynamics following stable states as the memory parameter α decreases and step size h increases. Theoretical results illustrate the rich dynamics and complexity of the model. Numerical simulation validates theoretical results and demonstrates the presence of rich dynamical behaviors include S‐asymptotically bounded periodic orbits, quasi‐periodicity, and chaos. The system exhibits a wide range of dynamical behaviors for fractional‐order α key parameter. 相似文献
42.
Aequationes mathematicae - Given two functions $$f,g:I\rightarrow \mathbb {R}$$ and a probability measure $$\mu $$ on the Borel subsets of [0, 1], the two-variable mean $$M_{f,g;\mu... 相似文献
43.
Si nanograins embedded in silica matrix were obtained by magnetron cosputtering of both Si and SiO2 at different substrate temperature (200–700°C) and thermal annealing at 1100°C. The samples were characterized by ellipsometric spectroscopy, high-resolution electron microscopy observations and photoluminescence. The highest excess of Si atoms was found to be incorporated for deposition temperature near 400–500°C, giving rise to a maximum PL and a shift of the peak position towards lower energy. These features might be interpreted in terms of quantum size effects and of density of grains, even though the interface states seem to be involved in the improvement of the photoluminescence efficiency. 相似文献
44.
A newly developed, semi-elliptic computational algorithm is employed to predict the transonic flow inside an axisymmetric, convergent-divergent nozzle featuring small wall radius of curvature at the throat. The predictions obtained are compared against flow measurements for this nozzle, which have been reported elsewhere. Good agreement between the corresponding measurements and predictions is revealed, thus validating the computational algorithm and demonstrating its value as a design tool. 相似文献
45.
46.
Sameh A. Rizk Salwa S. Abdelwahab Eman Elrazaz 《Journal of heterocyclic chemistry》2019,56(2):443-449
2,3‐Diaryloxirane‐2,3‐dicarbonitriles have employed in heterocyclic synthesis in many organic reactions. Authors highlight its use as intermediate in the synthesis of various organic compounds through the reaction with different nitrogen nucleophiles as methyl hydrazine, thiourea, thiosemicarbazide, methylglycinate, and others to furnish new heterocyclic derivatives. They are also used as key starting materials to construct some important heterocycles. Structures of all newly synthesized products are substantiated by studying their micro analytical and spectral data. Some of newly synthesized compounds were evaluated for their in vitro cytotoxic effects against a panel of three human tumor cell lines, namely, Hep‐G2, Hela, and MCF‐7. Most of the newly synthesized compounds ( 1a , 2a , 2d , 3 , 4 , 5 , 6a , 6c , 6d , 7a , and 7b ) inhibited cell proliferation with IC50 values in range of 0.52–5.21 μΜ. For activity against HepG2 cell line, compounds 5 , 6a , 6d , and 7b emerged as the most active members. The Hela cell line showed highest sensitivity toward compounds 2a , 2d , and 6c whereas compounds 2d and 6c showed the highest inhibitory activity against MCF‐7 cell line. 相似文献
47.
Amr A. A. Attia Alexandru Lupan R. Bruce King 《International journal of quantum chemistry》2019,119(15):e25934
The structures and energetics of the tetracarbindanes C4Inn−4Men (n = 6-14) have been determined by density functional theory. In contrast to their aluminum and gallium analogs, the lowest energy tetracarbindanes typically have all four carbon atoms segregated into a single C4 unit. Thus, linear C4 units resembling butadiene are found in the lowest energy C4Inn−4Men structures. In addition, some higher energy tetracarbindane structures have a structural feature not found in any of the corresponding tetracarbalanes and tetracarbagallanes, namely closed trapezoidal C4 units resembling cyclobutene. Such trapezoidal C4 units bind to the Inn−4 subcluster with the CC edge bonding to a single indium atoms as an olefin-metal or 3-center 2-electron bond. These differences may be attributed to the larger size of indium atoms (1.42 Å covalent radius) relative to gallium atoms (1.22 Å covalent radius). 相似文献
48.
Fateme Banihashemi Amr F. M. Ibrahim Ali Akbar Babaluo Jerry Y. S. Lin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(8):2541-2545
Highly b‐oriented, closely packed, MFI zeolite films are prepared on seeded stainless‐steel plates using organic template‐free, secondary growth solutions, containing aluminum sulfate as a crystallization agent. The number of a‐oriented twin crystals is significantly reduced, and even eliminated, simply by restricting the pH value of the secondary growth solution to the narrow range of 11.1–11.3. Values of pH can be adjusted through the controlled addition of (NH4)2SO4 or H2SO4 to secondary growth solutions of the composition (1 SiO2:0.57 NaOH:137.5 H2O:0.0050 (Al2(SO4)3?18 H2O)) or by simply decreasing the molar composition of NaOH with no extra additives. 相似文献
49.
Khalifa N. M. Amr A. E. G. Al-Omar M. A. Nossier E. S. 《Russian Journal of General Chemistry》2016,86(12):2785-2790
Russian Journal of General Chemistry - A new group of chiral linear 7-methyl-4-oxo-1,8-naphthyridine-3-carboxamides with incorporated peptide linkage have been synthesized via condensation of... 相似文献
50.
The behavior of composite coated Al electrodes fabricated by surface mechanical alloying ‘SMA’ was studied. The work was accomplished using Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) techniques in alkaline media were done at room temperature. Results show hydroxyl ions accumulate on the surface due to Al deformation micro cavities filling with until full charge blockage reached. A barrier cover layer development causing an increase of both resistance and capacitance as it becomes more stable and thinner with exposure time increase. Migrating hydroxyl ion inside micro cavity changed its composition from Al2O3 to stable tetrahedral aluminate ions. Therefore future benefits could be reached by developing such surfaces having charge accumulation that enables environmental interaction. 相似文献