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91.
López-Martín J Anam EM Boira H Sanz MJ Blázquez MA 《Chemical & pharmaceutical bulletin》2002,50(12):1613-1615
Dennettine, a new 2,6-dimethoxychromone and three known phenanthrene alkaloids (uvariopsine, stephenanthrine and argentinine) in addition to the phenolic and known compound vanillin were isolated from the roots of Dennettia tripetala. Their structures were determined by physical and spectroscopical one dimensional (1D) and 2D-NMR analysis, including heteronuclear multiple bond correlation and nuclear Overhauser enhancement spectroscopy. 相似文献
92.
Delgado J Espinós A Jiménez MC Miranda MA 《Chemical communications (Cambridge, England)》2002,(22):2636-2637
Formation of an o-quinone methide via C-C fragmentation of a zwitterion formed by intramolecular excited state proton transfer from an o-allylphenol derivative is reported for the first time. 相似文献
93.
Barluenga J Aznar F Gutiérrez I García-Granda S Llorca-Baragaño MA 《Organic letters》2002,4(24):4273-4276
[reaction: see text] The first cyclopropanation reaction of olefins with Fischer dialkylaminocarbene complexes is presented. The reaction yields 1-aminocyclopropanecarboxylic acid derivatives in a single step, usually with high diastereoselectivity. An approach to the asymmetric version of this reaction is also presented. The synthetic utility of the procedure is exemplified by the synthesis of both cycles of metanoproline in a single step. In addition, the synthesis of the first Fischer carbene containing a halocarbonyl group is reported. 相似文献
94.
Dang van Ba 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1969,20(4):599-602
Résumé On essaie de trouver l'équation du mouvement de la barre de contrôle d'un réacteur en théorie ponctuelle à un groupe de neutrons retardés à partir des principes stochastiques. 相似文献
95.
J. Baštecká 《Czechoslovak Journal of Physics》1965,15(8):595-601
The stress components based on anisotropic elasticity are found for edge and screw dislocations in α-Fe. The method of Eshelby, Read and Shockley is used. 相似文献
96.
We report experimental measurements of the phase behavior of mixtures of thin (charged semiflexible fd virus) and thick (fd-PEG, fd virus covalently coated with polyethylene glycol) rods with diameter ratio varying from 3.7 to 1.1. The phase diagrams of the rod mixtures reveal isotropic-nematic, isotropic-nematic-nematic, and nematic-nematic coexisting phases with increasing concentration. In stark contrast to predictions from earlier theoretical work, we observe a nematic-nematic coexistence region bound by a lower critical point. Moreover, we show that a rescaled Onsager-type theory for binary hard-rod mixtures qualitatively describes the observed phase behavior. 相似文献
97.
The mathematics of Lorentz transformations, called the Lorentz group, continues to play an important role in optical sciences. It is the basic mathematical language for coherent and squeezed states. It is noted that the six-parameter Lorentz group can be represented by two-by-two matrices. Since the beam transfer matrices in ray optics are largely based on two-by-two matrices or ABCD matrices, the Lorentz group is bound to be the basic language for ray optics, including polarization optics, interferometers, lens optics, multilayer optics, and the Poincaré sphere. Because the group of Lorentz transformations and ray optics are based on the same two-by-two matrix formalism, ray optics can perform mathematical operations that correspond to transformations in special relativity. It is shown, in particular, that one-lens optics provides a mathematical basis for unifying the internal space-time symmetries of massive and massless particles in the Lorentz-covariant world. 相似文献
98.
Pomerantz AE Ausfelder F Zare RN Juanes-Marcos JC Althorpe SC Sáez Rábanos V Aoiz FJ Bañares L Castillo JF 《The Journal of chemical physics》2004,121(14):6587-6590
Experimental measurements of rovibrational product state distributions for the inelastic scattering process H + D2(nu=0,j)-->H + D2(nu' = 1,2,j') are presented and compared with the results of quasiclassical and quantum mechanical calculations. Agreement between theory and experiment is almost quantitative. Two subtle trends are found: the relative amount of energy in product rotational excitation decreases slightly with increasing collision energy and increases slightly with increasing product vibrational excitation. These trends are the reverse of what has been found for reactive scattering in which the opposite trends are much more pronounced. 相似文献
99.
López C Caubet A Pérez S Solans X Font-Bardía M 《Chemical communications (Cambridge, England)》2004,(5):540-541
The synthesis of the first examples of diastereomerically pure platinacycles having simultaneously a chiral carbon and a sigma[Pt-C(sp(2), ferrocene)] bond is described. 相似文献
100.
Cao Thi Vi Ba Ha Huy Bang Dang Van Soa 《International Journal of Theoretical Physics》2003,42(8):1781-1786
We propose commutation relations for a single mode -deformed para-Bose oscillator. In this new deformation of para-Bose statistics the distribution function has the same form as in the para-Bose statistics. Furthermore, we show analogies between the coherent states of -deformed and q-deformed para-Bose statistics. 相似文献