A test of a model t-matrix for direct reaction inelastic scattering

Differential cross sections and analyzing powers from the inelastic scattering of 65 MeV protons leading to the 1⁺T=0 (12.71 MeV) and 1⁺T = 1 (15.11 MeV) states in ¹²C have been analysed as tests of a model two-nucleon t-matrix.     

Surface and aggregation behavior of aqueous solutions of Ru(II) metallosurfactants. 3. Effect of chain number and orientation on the structure of adsorbed films of [Ru(bipy)2(bipy')]Cl2 complexes

The surface behavior of a range of surfactant [Ru(bipy)(2)(p,p'-dialkyl-2,2'-bipy)]Cl(2) complexes, which we express as Ru(q)(p)C(n) where n is the alkyl chain length, p refers to the substitution position on the bipyridine ligand (=4 or 5), and q (=1 or 2) is the number of substituted alkyl chains, has been examined using neutron reflectometry. The adsorption of the single-chain Ru(1)(4)C(19) and Ru(1)(5)C(19) surfactants is strongly time-dependent, taking in excess of 10 h to form an equilibrium film. It is suggested that the slow adsorption rate is related to the alkyl chain length rather than the low monomer concentration present in the solutions. At concentrations below the critical micelle concentration (cmc) of Ru(1)(4)C(19), the film of Ru(1)(5)C(19) is denser than that of Ru(1)(4)C(19) at comparable concentration, consistent with the mass densities of the bulk solids, whereas at concentrations close to and greater than this cmc the converse pertains. Close to the cmc, the adsorbed films possess an average area per molecule significantly less than the nominal headgroup area of the surfactants (approximately 30 angstroms(2) compared with approximately 100 angstroms(2)). This fact together with consideration of the thickness and density of the adsorbed films leads to the conjecture that surface aggregates may be the adsorbing units. The adsorption of the double-chain surfactant Ru(1)(p)C(19), in contrast to the behavior of the Ru(1)(p)C(19) surfactants, is weak and independent of time. This behavior is attributed to the alkyl chain orientation. The adsorption behavior of a racemic mixture of the Delta and Lambda isomers of Ru(2)(4)C(19) has been compared with that of the Delta isomer. It is found that the film of racemic material is more closely packed than that of the resolved complex.     

Giant multipole resonance effects in27Al(p n)27Si

A set of ten differential cross sections between 10 and 40 MeV for this charge exchange reaction have been analysed. In the analyses, amplitudes associated with the virtual excitation of the giant dipole and quadrupole reasonances in²⁸Si complement those associated with the direct reaction mechanism. Such resonance effects are essential to explain the rapid energy variation of the data.     

Author index to volume 75

Møller-Plesset perturbation theory is used to find the second- and third-order correlation corrections to some oneelectron properties of HC1 and CO. An estimate of the fourth-order correction is made. It is shown that the perturbed wavefunctions can be constructed efficiently using the techniques of the direct CI methods. The results are comparable in accuracy with those obtained from large-scale CI calculations, but require considerably less computation.     

Complementary control by additives of the kinetics of amorphous CaCO3 mineralization at an organic interface: in-situ synchrotron x-ray observations

The kinetics of biomimetic mineralization at a fatty acid monolayer interface have been measured in situ by synchrotron x-ray reflectivity. The formation of biologically relevant amorphous calcium carbonate films is affected by soluble macromolecules, supersaturation rate of change, and Mg cations. We find that these solution conditions influence mineral film formation in a complementary fashion. Poly(sodium acrylate) extends the lifetime of metastable amorphous calcium carbonate, solution saturation controls the mineral film growth rate, and Mg cations create a longer induction time. This is the first quantification of potentially competitive biomineralization mechanisms that addresses nucleation and growth of the amorphous mineral phases, which are important in biomineralization.     

Relativistic treatment of the spin-zero particles subject to the second Poschl-Teller-like potential

The three-dimensional Klein-Gordon equation is solved for the case of equal vector and scalar second Poschl-Teller potential by proper approximation of the centrifugal term within the framework of the asymptotic iteration method. Energy eigenvalues and the corresponding wave function are obtained analytically. Eigenvalues are computed numerically for some values of n and It is found that the results are in good agreement with the findings of other methods for short-range potential.     

Sonic booms and diffusion wakes generated by a heavy quark in thermal gauge-string duality

We evaluate the Poynting vector generated by a heavy quark moving through a thermal state of N=4 gauge theory using the gauge-string duality. A significant diffusion wake is observed as well as a Mach cone. We discuss the ratio of the energy going into sound modes to the energy coming in from the wake.     

Moments of partitions and derivatives of higher order

Journal of Algebraic Combinatorics - We define moments of partitions of integers, and show that they appear in higher-order derivatives of certain combinations of functions.